Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Experimental Tests of a Theoretically Predicted Noncausal Correlation between Dynamics and Thermodynamics in Glass-forming Polymer Melts

Journal Article · · Macromolecules
 [1];  [1];  [2]
  1. Department of Materials Science, University of Illinois, Urbana, Illinois 61801, United States; Material Research Laboratory, University of Illinois, Urbana, Illinois 61801, United States
  2. Department of Materials Science, University of Illinois, Urbana, Illinois 61801, United States; Department of Chemistry, University of Illinois, Urbana, Illinois 61801, United States; Department of Chemical and Biomolecular Engineering, University of Illinois, Urbana, Illinois 61801, United States; Material Research Laboratory, University of Illinois, Urbana, Illinois 61801, United States

Not provided.

Research Organization:
Univ. of Illinois at Urbana-Champaign, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0020858
OSTI ID:
1978142
Journal Information:
Macromolecules, Vol. 54, Issue 21; ISSN 0024-9297
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (63)

Relaxation in glassforming liquids and amorphous solids journal September 2000
Little evidence for dynamic divergences in ultraviscous molecular liquids journal July 2008
In search of a theory of supercooled liquids journal November 2008
Molecular Theories of Segmental Dynamics and Mechanical Response in Deeply Supercooled Polymer Melts and Glasses journal August 2010
Perspective: Supercooled liquids and glasses journal August 2012
Perspective: The glass transition journal March 2013
Glass Transition Thermodynamics and Kinetics journal April 2013
Growing Length Scales and Their Relation to Timescales in Glass-Forming Liquids journal March 2014
On the Free‐Volume Model of the Liquid‐Glass Transition journal March 1970
How Free Volume Does Influence the Dynamics of Glass Forming Liquids journal April 2017
Perspective: Excess-entropy scaling journal December 2018
On the Temperature Dependence of Cooperative Relaxation Properties in Glass‐Forming Liquids journal July 1965
Theory of Structural Glasses and Supercooled Liquids journal May 2007
Separating the configurational and vibrational entropy contributions in metallic glasses journal May 2017
Polymer Glass Formation: Role of Activation Free Energy, Configurational Entropy, and Collective Motion journal February 2021
A Quantitative Model of Super-Arrhenian Behavior in Glass-Forming Polymers journal February 2019
A structural signature of liquid fragility journal August 2014
Correlation between dynamical and structural heterogeneities in colloidal hard-sphere suspensions journal March 2016
A structural approach to relaxation in glassy liquids journal February 2016
Correlation between temperature variations of static and dynamic properties in glass-forming liquids journal December 2016
Local structure in deeply supercooled liquids exhibits growing lengthscales and dynamical correlations journal August 2018
Structure determines where crystallization occurs in a soft colloidal glass journal September 2020
Elastic models for the non-Arrhenius viscosity of glass-forming liquids journal November 2006
Elastic Signature of Flow Events in Supercooled Liquids Under Shear journal August 2013
Irreversible reorganization in a supercooled liquid originates from localized soft modes journal July 2008
String model for the dynamics of glass-forming liquids journal May 2014
Two-step relaxation and the breakdown of the Stokes-Einstein relation in glass-forming liquids journal November 2019
Dynamics on the Way to Forming Glass: Bubbles in Space-Time journal March 2010
Entropic barriers, activated hopping, and the glass transition in colloidal suspensions journal July 2003
Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. I. General formulation and application to hard sphere fluids journal May 2014
Thermodynamics–Structure–Dynamics Correlations and Nonuniversal Effects in the Elastically Collective Activated Hopping Theory of Glass-Forming Liquids journal July 2020
Unified Theory of Activated Relaxation in Liquids over 14 Decades in Time journal October 2013
Elastically cooperative activated barrier hopping theory of relaxation in viscous fluids. II. Thermal liquids journal May 2014
Dynamical Theory of Segmental Relaxation and Emergent Elasticity in Supercooled Polymer Melts journal March 2015
Nonuniversal Coupling of Cage Scale Hopping and Collective Elastic Distortion as the Origin of Dynamic Fragility Diversity in Glass-Forming Polymer Liquids journal December 2016
Integral equation theory of thermodynamics, pair structure, and growing static length scale in metastable hard sphere and Weeks-Chandler-Andersen fluids journal April 2020
Experimental test of a predicted dynamics–structure–thermodynamics connection in molecularly complex glass-forming liquids journal April 2021
Derivation of a microscopic theory of barriers and activated hopping transport in glassy liquids and suspensions journal December 2005
Integral equation theory of polymer melts: density fluctuations, static structure factor, and comparison with incompressible and continuum limit models journal October 1988
Solution of a new integral equation for pair correlation functions in molecular liquids journal December 1973
Correlation between dynamic fragility and glass transition temperature for different classes of glass forming liquids journal August 2006
The application of the energy landscape model to polymers journal September 1999
Temperature Dependence of the Segmental Relaxation Time of Polymers Revisited journal April 2015
Theory of dynamic barriers, activated hopping, and the glass transition in polymer melts journal July 2004
Progress towards a phenomenological picture and theoretical understanding of glassy dynamics and vitrification near interfaces and under nanoconfinement journal December 2019
Dynamics near Free Surfaces and the Glass Transition in Thin Polymer Films: A View to the Future journal November 2013
Nature of dynamic gradients, glass formation, and collective effects in ultrathin freestanding films journal July 2021
Viscosity in disordered media journal October 2005
Role of Chemical Structure in Fragility of Polymers: A Qualitative Picture journal October 2008
Why many polymers are so fragile journal April 2007
Temperature Dependence of Segmental and Terminal Relaxation in Atactic Polypropylene Melts journal August 2001
Molecular Weight Dependence of Glassy Dynamics in Linear Polymers Revisited journal December 2008
Correlation of polymer segmental chain dynamics with temperature-dependent time-scale shifts journal September 1991
Supercooled dynamics of glass-forming liquids and polymers under hydrostatic pressure journal May 2005
Dielectric investigation of the glass relaxation in poly(vinyl acetate) and poly(vinyl chloride) under high hydrostatic pressure journal November 1985
Dynamic fragility in polymers: A comparison in isobaric and isochoric conditions journal March 2002
Predicting the density-scaling exponent of a glass-forming liquid from Prigogine–Defay ratio measurements journal July 2011
Explaining why simple liquids are quasi-universal journal November 2014
Simple liquids’ quasiuniversality and the hard-sphere paradigm journal June 2016
Evidence of a one-dimensional thermodynamic phase diagram for simple glass-formers journal February 2018
Equation of State and Entropy Theory Approach to Thermodynamic Scaling in Polymeric Glass-Forming Liquids journal March 2021
Activated penetrant dynamics in glass forming liquids: size effects, decoupling, slaving, collective elasticity and correlation with matrix compressibility journal January 2021
Theory of the effect of external stress on the activated dynamics and transport of dilute penetrants in supercooled liquids and glasses journal August 2021

Similar Records

Experimental test of a predicted dynamics–structure–thermodynamics connection in molecularly complex glass-forming liquids
Journal Article · 2021 · Proceedings of the National Academy of Sciences of the United States of America · OSTI ID:1780534

Long Wavelength Thermal Density Fluctuations in Molecular and Polymer Glass-Forming Liquids: Experimental and Theoretical Analysis under Isobaric Conditions
Journal Article · 2021 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry · OSTI ID:1977980

Related Subjects