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Observation and Characterization of Dicarbonyls on a RhCu Single-Atom Alloy

Journal Article · · Journal of Physical Chemistry Letters
 [1];  [2];  [1];  [1];  [1];  [3];  [4];  [1]
  1. Department of Chemistry, Tufts University, Medford, Massachusetts 02155, United States
  2. Department of Chemical Engineering, University College London, London WC1E 7JE, U.K.; Yusuf Hamied Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, U.K.; Department of Physics and Astronomy, University College London, London WC1E 6BT, U.K.
  3. Department of Chemical Engineering, University College London, London WC1E 7JE, U.K.
  4. Yusuf Hamied Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, U.K.; Department of Physics and Astronomy, University College London, London WC1E 6BT, U.K.

Not provided.

Research Organization:
Tufts Univ., Medford, MA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0004738
OSTI ID:
1978116
Journal Information:
Journal of Physical Chemistry Letters, Vol. 13, Issue 27; ISSN 1948-7185
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (40)

Infrared spectra of chemisorbed CO on Rh journal February 1979
New advances in the use of infrared absorption spectroscopy for the characterization of heterogeneous catalytic reactions journal January 2014
Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts journal September 2015
Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst journal August 2011
Atomically dispersed supported metal catalysts: perspectives and suggestions for future research journal January 2017
Catalyst Architecture for Stable Single Atom Dispersion Enables Site-Specific Spectroscopic and Reactivity Measurements of CO Adsorbed to Pt Atoms, Oxidized Pt Clusters, and Metallic Pt Clusters on TiO 2 journal September 2017
Single-atom catalysis of CO oxidation using Pt1/FeOx journal July 2011
Breaking the scaling relationship via thermally stable Pt/Cu single atom alloys for catalytic dehydrogenation journal October 2018
First-principles design of a single-atom–alloy propane dehydrogenation catalyst journal June 2021
Free-atom-like d states in single-atom alloy catalysts journal August 2018
An atomic-scale view of single-site Pt catalysis for low-temperature CO oxidation journal March 2018
Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit journal October 2015
Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations journal March 2012
Single-Atom Alloy Catalysis journal June 2020
Facet engineering accelerates spillover hydrogenation on highly diluted metal nanocatalysts journal August 2020
Mechanistic and Electronic Insights into a Working NiAu Single-Atom Alloy Ethanol Dehydrogenation Catalyst journal December 2021
Combining STM, RAIRS and TPD to Decipher the Dispersion and Interactions Between Active Sites in RhCu Single‐Atom Alloys journal November 2019
Atomic-Scale Surface Structure and CO Tolerance of NiCu Single-Atom Alloys journal October 2019
Structure of rhodium in an ultradispersed rhodium/alumina catalyst as studied by EXAFS and other techniques journal May 1985
Structure and Bonding of a Site-Isolated Transition Metal Complex:  Rhodium Dicarbonyl in Highly Dealuminated Zeolite Y journal August 2000
Strong Metal–Support Interactions between Pt Single Atoms and TiO 2 journal May 2020
Quantum Mechanical Screening of Single-Atom Bimetallic Alloys for the Selective Reduction of CO 2 to C 1 Hydrocarbons journal October 2016
Selective Activation of Methane on Single-Atom Catalyst of Rhodium Dispersed on Zirconia for Direct Conversion journal November 2017
Support functionalization as an approach for modifying activation entropies of catalytic reactions on atomically dispersed metal sites journal December 2021
Isolated Metal Active Site Concentration and Stability Control Catalytic CO 2 Reduction Selectivity journal February 2015
Site distribution studies of Rh supported on Al 2 O 3 —An infrared study of chemisorbed CO journal April 1981
Infrared spectroscopic study of activated surface processes: CO chemisorption on supported Rh journal November 1979
Tracking Rh Atoms in Zeolite HY: First Steps of Metal Cluster Formation and Influence of Metal Nuclearity on Catalysis of Ethylene Hydrogenation and Ethylene Dimerization journal June 2016
Surface facet dependence of competing alloying mechanisms journal December 2020
Carbon Monoxide Poisoning Resistance and Structural Stability of Single Atom Alloys journal January 2018
CO-Induced Aggregation and Segregation of Highly Dilute Alloys: A Density Functional Theory Study journal March 2019
Roughening of Copper (100) at Elevated CO Pressure: Cu Adatom and Cluster Formation Enable CO Dissociation journal October 2018
Structural Evolution of Ga–Cu Model Catalysts for CO2 Hydrogenation Reactions journal January 2021
Microscopic View of the Active Sites for Selective Dehydrogenation of Formic Acid on Cu(111) journal November 2015
Adsorbate−Adsorbate Interactions and Chemisorption at Different Coverages Studied by Accurate ab initio Calculations:  CO on Transition Metal Surfaces journal March 2006
On the effect of coverage-dependent adsorbate–adsorbate interactions for CO methanation on transition metal surfaces journal November 2013
Adsorption of CO to Characterize the Structure of a Pd/Ag(111) Single-Atom Alloy Surface journal June 2020
Vibrational spectroscopy of CO adsorbed on supported ultra-small transition metal particles and single metal atoms journal May 2000
Single-Bond Formation and Characterization with a Scanning Tunneling Microscope journal November 1999
Tackling CO Poisoning with Single-Atom Alloy Catalysts journal May 2016