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Polymorph Selection in Zeolite Synthesis Occurs after Nucleation

Journal Article · · Journal of Physical Chemistry Letters
 [1];  [2];  [2]
  1. Department of Chemistry, The University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850, United States; OSTI
  2. Department of Chemistry, The University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850, United States
Not provided.
Research Organization:
Univ. of California, Los Angeles, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0021201
OSTI ID:
1978102
Journal Information:
Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 4 Vol. 13; ISSN 1948-7185
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (66)

Optimization of crystal growth of hierarchical porosity ZSM‐5 zeolite based on coal fly ash “waste utilization” journal September 2020
Issues in the Synthesis of Crystalline Molecular Sieves: Towards the Crystallization of Low Framework-Density Structures journal March 2004
Structure of the Silica Phase Extracted from Silica/(TPA)OH Solutions Containing Nanoparticles journal September 2003
Guest/host relationships in zeolite synthesis: ring-substituted piperidines and the remarkable adamantane mimicry by 1-azonio spiro [5.5] undecanes journal June 1998
Coarsening and Spinodal Decomposition of Zeolite Linde Type A Precursor Gels Aged at Low Temperatures journal May 2016
Supramolecular self-assembled molecules as organic directing agent for synthesis of zeolites journal September 2004
Investigation of Silicalite-1 Crystallization Using Attenuated Total Reflection/Fourier Transform Infrared Spectroscopy journal October 2007
A new approach to the determination of atomic-architecture of amorphous zeolite precursors by high-energy X-ray diffraction technique journal January 2006
Comment on “Identification of Precursor Species in the Formation of MFI Zeolite in the TPAOH−TEOS−H 2 O System” journal February 2002
Assembly and Evolution of Amorphous Precursors in Zeolite L Crystallization journal February 2016
Local Order of Amorphous Zeolite Precursors from 29 Si{ 1 H} CPMAS and 27 Al and 23 Na MQMAS NMR and Evidence for the Nature of Medium-Range Order from Neutron Diffraction journal June 2004
Observing a Zeolite Nucleus (Subcrystal) with a Uniform Framework Structure and Its Oriented Attachment without Single‐Molecule Addition journal June 2021
A contribution to understanding the mechanism of crystallization of silicalite-1 in heterogeneous systems (hydrogels) journal July 2009
Kinetics of nucleation and growth of zeolite LTA from clear solution by in situ and ex situ XRPD journal July 2002
The hydrothermal synthesis of zeolites: Precursors, intermediates and reaction mechanism journal July 2005
Physical Basis for the Formation and Stability of Silica Nanoparticles in Basic Solutions of Monovalent Cations journal September 2005
Anomalous crystallization mechanism in the synthesis of nanocrystalline ZSM-5 journal September 2000
Possible resolution of the Kauzmann paradox in supercooled liquids journal July 2003
In situ Small-Angle and Wide-Angle X-ray Scattering Investigation on Nucleation and Crystal Growth of Nanosized Zeolite A journal April 2007
Towards the Rational Design of Efficient Organic Structure-Directing Agents for Zeolite Synthesis journal October 2013
Coarse-Grained Model for the Hydrothermal Synthesis of Zeolites journal November 2021
Zeolite and molecular sieve synthesis journal July 1992
Regulating Nonclassical Pathways of Silicalite‐1 Crystallization through Controlled Evolution of Amorphous Precursors journal September 2019
Mechanism of Transformation of Precursors into Nanoslabs in the Early Stages of MFI and MEL Zeolite Formation from TPAOH−TEOS−H 2 O and TBAOH−TEOS−H 2 O Mixtures journal June 1999
Evidence for X-ray-amorphous zeolites journal January 1981
Thermodynamic properties of silicalite SiO2 journal June 1987
A Structural Resolution Cryo-TEM Study of the Early Stages of MFI Growth journal December 2008
Characterization of siliceous MFI-type zeolites containing tetra-, tri-, and dipropylammonium fluoride species journal September 1989
Kinetic and Thermodynamic Studies of Silica Nanoparticle Dissolution journal August 2007
Elucidation of Medium-Range Structure in a Dry Gel-Forming *BEA-Type Zeolite journal June 2007
Aggregative Growth of Silicalite-1 journal April 2007
Evolution of Self-Assembled Silica−Tetrapropylammonium Nanoparticles at Elevated Temperatures journal July 2005
Spontaneous Formation of Silica Nanoparticles in Basic Solutions of Small Tetraalkylammonium Cations journal July 2004
Diverse Physical States of Amorphous Precursors in Zeolite Synthesis journal June 2018
Structure-Directing Behaviors of Tetraethylammonium Cations toward Zeolite Beta Revealed by the Evolution of Aluminosilicate Species Formed during the Crystallization Process journal November 2015
The structure-controlling role of organic templates for the synthesis of porosils in the systems SiO2/template/H2O journal January 1992
Silicalite, a new hydrophobic crystalline silica molecular sieve journal February 1978
Effect of water on topological constraints in silica glass journal February 2019
Thermodynamic properties of quartz, cristobalite and amorphous SiO2: drop calorimetry measurements between 1000 and 1800 K and a review from 0 to 2000 K journal December 1982
Nucleation of open framework materials: Navigating the voids journal May 2016
Discovering Relationships between OSDAs and Zeolites through Data Mining and Generative Neural Networks journal April 2021
Identification of Precursor Species in the Formation of MFI Zeolite in the TPAOH−TEOS−H 2 O System journal June 1999
MFI Fingerprint: How Pentasil-Induced IR Bands Shift during Zeolite Nanogrowth journal May 2008
An X-ray absorption fine structure study of amorphous precursors of a gallium silicate zeolite journal August 2001
Thermodynamics of Pure-Silica Molecular Sieve Synthesis journal April 2002
Role of homogeneous nucleation in the formation of primary zeolite particles journal June 1995
Aggregation Mechanism of Nanoslabs with Zeolite MFI-Type Structure journal December 1999
UV Raman spectroscopic study on the synthesis mechanism of zeolite X journal February 2001
Capturing Ultrasmall EMT Zeolite from Template-Free Systems journal December 2011
Mechanism of Structure Direction in the Synthesis of Si-ZSM-5: An Investigation by Intermolecular 1H-29Si CP MAS NMR journal April 1994
In situ observation of silicalite nucleation and growth: A light-scattering study journal March 1994
Thermochemistry of Microporous and Mesoporous Materials journal September 2009
Amorphous microporous molecular sieves with different pore dimensions and topologies: Synthesis, characterization and catalytic activity journal February 2006
Mechanism of Structure Direction in the Synthesis of Pure-Silica Zeolites. 2. Hydrophobic Hydration and Structural Specificity journal August 1995
Zeolites upon heating: Factors governing their thermal stability and structural changes journal September 2006
A priori control of zeolite phase competition and intergrowth with high-throughput simulations journal October 2021
Tailoring the physicochemical properties of zeolite catalysts journal January 2014
Synthesis of new zeolite structures journal January 2015
Mechanistic principles of nanoparticle evolution to zeolite crystals journal April 2006
Characterization of Nanosized Material Extracted from Clear Suspensions for MFI Zeolite Synthesis
  • Ravishankar, Raman; Kirschhock, Christine E. A.; Knops-Gerrits, Peter-Paul
  • The Journal of Physical Chemistry B, Vol. 103, Issue 24 https://doi.org/10.1021/jp990296z
journal June 1999
Reaction Kinetics Regulated Formation of Short-Range Order in an Amorphous Matrix during Zeolite Crystallization journal July 2021
Nucleation Rates of Zeolite A Crystals from Clear Aluminosilicate Solutions. journal January 2003
Spontaneous nucleation and growth of pure silica zeolite-? free of connectivity defects journal January 1996
Structural Evolution of Amorphous Precursors toward Crystalline Zeolites Visualized by an in Situ X-ray Pair Distribution Function Approach journal October 2019
In situ observation of homogeneous nucleation of nanosized zeolite A journal January 2006
Formation of Crystal Nuclei in Liquid Metals journal October 1950

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