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Water Dynamics in Aqueous Poly- N -Isopropylacrylamide Below and Through the Lower Critical Solution Temperature

Journal Article · · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry

Not provided.

Research Organization:
Stanford Univ., CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG03-84ER13251
OSTI ID:
1978001
Journal Information:
Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry, Vol. 126, Issue 36; ISSN 1520-6106
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (63)

Hydrogel: Preparation, characterization, and applications: A review journal March 2015
Hydrogel Based Sensors for Biomedical Applications: An Updated Review journal August 2017
Hydraulically amplified self-healing electrostatic actuators with muscle-like performance journal January 2018
Bioactuators based on stimulus-responsive hydrogels and their emerging biomedical applications journal November 2019
Stimulus-responsive hydrogels: Theory, modern advances, and applications journal July 2015
Solution Properties of Poly(N-isopropylacrylamide) journal December 1968
Solution Properties and Thermal Behavior of Poly(N-n-propylacrylamide) in Water journal December 1997
Poly(N-isopropylacrylamide) and Copolymers: A Review on Recent Progresses in Biomedical Applications journal October 2017
Thermoresponsive polymers and their biomedical application in tissue engineering – a review journal January 2020
Role of Solvation Dynamics and Local Ordering of Water in Inducing Conformational Transitions in Poly( N -isopropylacrylamide) Oligomers through the LCST
  • Deshmukh, Sanket A.; Sankaranarayanan, Subramanian K. R. S.; Suthar, Kamlesh
  • The Journal of Physical Chemistry B, Vol. 116, Issue 9 https://doi.org/10.1021/jp210788u
journal February 2012
Change in Hydration State during the Coil−Globule Transition of Aqueous Solutions of Poly( N -isopropylacrylamide) as Evidenced by FTIR Spectroscopy journal September 2000
Phase Behavior of N-(Isopropyl)propionamide in Aqueous Solution and Changes in Hydration Observed by FTIR Spectroscopy journal March 2008
A infrared spectroscopic study on the mechanism of temperature-induced phase transition of concentrated aqueous solutions of poly(N-isopropylacrylamide) and N-isopropylpropionamide journal March 2010
The Role of Backbone Hydration of Poly(N-isopropyl acrylamide) Across the Volume Phase Transition Compared to its Monomer journal December 2017
UV Resonance Raman Determination of Molecular Mechanism of Poly( N -isopropylacrylamide) Volume Phase Transition journal April 2009
Hydration and Hydrogen Bond Network of Water during the Coil-to-Globule Transition in Poly( N -isopropylacrylamide) Aqueous Solution at Cloud Point Temperature journal April 2015
Single Chain Structure of a Poly( N -isopropylacrylamide) Surfactant in Water journal February 2015
Dynamics of Linear Poly( N -isopropylacrylamide) in Water around the Phase Transition Investigated by Dielectric Relaxation Spectroscopy journal March 2014
Dynamics of the Poly(N-Isopropylacrylamide) Microgel Aqueous Suspension Investigated by Dielectric Relaxation Spectroscopy journal February 2022
Solvent relaxation of swelling PNIPAM microgels by NMR journal December 2005
Characterization of free, restricted, and entrapped water environments in poly( N -isopropyl acrylamide) hydrogels via 1 H HRMAS PFG NMR spectroscopy journal September 2014
NMR studies of water dynamics during sol-to-gel transition of poly (N-isopropylacrylamide) in concentrated aqueous solution journal January 2017
From Molecular Dehydration to Excess Volumes of Phase-Separating PNIPAM Solutions journal April 2014
Water Dynamics in a Concentrated Poly( N -isopropylacrylamide) Solution at Variable Pressure journal February 2019
Hydrogen bond dynamics in aqueous NaBr solutions journal October 2007
Structural Dynamics of Aqueous Salt Solutions journal April 2008
Water Dynamics in Divalent and Monovalent Concentrated Salt Solutions journal November 2012
Water Dynamics and Structure of Highly Concentrated LiCl Solutions Investigated Using Ultrafast Infrared Spectroscopy journal February 2022
Effect of urea on the structural dynamics of water journal December 2006
Water Dynamics in Water/DMSO Binary Mixtures journal April 2012
Water dynamics in large and small reverse micelles: From two ensembles to collective behavior journal July 2009
Water dynamics at neutral and ionic interfaces journal August 2009
Geometry and Nanolength Scales versus Interface Interactions: Water Dynamics in AOT Lamellar Structures and Reverse Micelles journal June 2009
Water Dynamics and Interactions in Water−Polyether Binary Mixtures journal March 2009
Bulk-like and Interfacial Water Dynamics in Nafion Fuel Cell Membranes Investigated with Ultrafast Nonlinear IR Spectroscopy journal October 2019
Water Dynamics in Polyacrylamide Hydrogels journal July 2018
Identical Water Dynamics in Acrylamide Hydrogels, Polymers, and Monomers in Solution: Ultrafast IR Spectroscopy and Molecular Dynamics Simulations journal September 2021
Water Dynamics in Nanoporous Silica: Ultrafast Vibrational Spectroscopy and Molecular Dynamics Simulations journal January 2019
Molecular-Sieve Chromatography of Proteins on Granulated Polyacrylamide Gels journal January 1966
The spaces in a uniform random suspension of fibres journal January 1958
Thermal Response of Narrow-Disperse Poly( N -isopropylacrylamide) Prepared by Atom Transfer Radical Polymerization journal July 2005
Combined electronic structure/molecular dynamics approach for ultrafast infrared spectroscopy of dilute HOD in liquid H2O and D2O journal May 2004
Resonant intermolecular transfer of vibrational energy in liquid water journal December 1999
Water dynamics in small reverse micelles in two solvents: Two-dimensional infrared vibrational echoes with two-dimensional background subtraction journal February 2011
Watching Hydrogen Bonds Break:  A Transient Absorption Study of Water journal December 2004
On the orientational relaxation of HDO in liquid water journal September 2005
Water Dynamics at the Interface in AOT Reverse Micelles journal June 2009
Water Dynamics in Nafion Fuel Cell Membranes:  The Effects of Confinement and Structural Changes on the Hydrogen Bond Network journal June 2007
Infrared and Raman Line Shapes of Dilute HOD in Liquid H 2 O and D 2 O from 10 to 90 °C journal July 2005
Water inertial reorientation: Hydrogen bond strength and the angular potential journal April 2008
Strong temperature dependence of water reorientation in hydrophobic hydration shells journal June 2009
Collective Hydrogen Bond Reorganization in Water Studied with Temperature-Dependent Ultrafast Infrared Spectroscopy journal May 2011
Solvation dynamics of N -substituted acrylamide polymers and the importance for phase transition behavior journal January 2020
The combined effect of cations and anions on the dynamics of water journal January 2012
A femtosecond mid-infrared study of the dynamics of water in aqueous sugar solutions journal January 2015
A theory of fluorescence polarization decay in membranes journal December 1977
Effect of librational motion on fluorescence depolarization and nuclear magnetic resonance relaxation in macromolecules and membranes journal June 1980
Orientational dynamics of water confined on a nanometer length scale in reverse micelles journal May 2005
A Molecular Jump Mechanism of Water Reorientation journal February 2006
Why Water Reorientation Slows without Iceberg Formation around Hydrophobic Solutes journal February 2009
Water Hydrogen-Bond Dynamics around Amino Acids: The Key Role of Hydrophilic Hydrogen-Bond Acceptor Groups journal February 2010
Water Dynamics in the Hydration Shells of Biomolecules journal March 2017
On the molecular origin of the cooperative coil-to-globule transition of poly( N -isopropylacrylamide) in water journal January 2018