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Energy Landscape for the Electrocatalytic Oxidation of Water by a Single-Site Oxomanganese(V) Porphyrin

Journal Article · · Inorganic Chemistry
 [1];  [1]
  1. Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States

Not provided.

Research Organization:
Univ. of Virginia, Charlottesville, VA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0001298
OSTI ID:
1977897
Journal Information:
Inorganic Chemistry, Vol. 61, Issue 35; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (66)

Manganese Compounds as Water-Oxidizing Catalysts: From the Natural Water-Oxidizing Complex to Nanosized Manganese Oxide Structures journal January 2016
Mn 4 Ca Cluster in Photosynthesis: Where and How Water is Oxidized to Dioxygen journal March 2014
Is Deprotonation of the Oxygen-Evolving Complex of Photosystem II during the S 1 → S 2 Transition Suppressed by Proton Quantum Delocalization? journal May 2021
Missing Pieces in the Puzzle of Biological Water Oxidation journal September 2018
An oxyl/oxo mechanism for oxygen-oxygen coupling in PSII revealed by an x-ray free-electron laser journal October 2019
Structure of photosystem II and substrate binding at room temperature journal November 2016
Transition metal-mediated O–O bond formation and activation in chemistry and biology journal January 2021
Water oxidation with transition metal catalysts with non-innocent ligands and its mechanisms journal July 2021
Photochemical Water Oxidation Using a Doubly N-Confused Hexaphyrin Dinuclear Cobalt Complex journal December 2020
Oxygen evolution reaction over catalytic single-site Co in a well-defined brookite TiO2 nanorod surface journal December 2020
Electrocatalytic Water Oxidation by a Trinuclear Copper(II) Complex journal June 2021
Artificial photosynthesis: opportunities and challenges of molecular catalysts journal January 2019
Design of molecular water oxidation catalysts with earth-abundant metal ions journal January 2021
Electrocatalytic Water Oxidation by a Phosphorus–Nitrogen O═PN 3 -Pincer Cobalt Complex journal November 2020
Cobalt Corroles as Electrocatalysts for Water Oxidation: Strong Effect of Substituents on Catalytic Activity journal November 2020
Redox Metal–Ligand Cooperativity Enables Robust and Efficient Water Oxidation Catalysis at Neutral pH with Macrocyclic Copper Complexes journal September 2020
Design of an inherently-stable water oxidation catalyst journal November 2018
Electrochemically Driven Water-Oxidation Catalysis Beginning with Six Exemplary Cobalt Polyoxometalates: Is It Molecular, Homogeneous Catalysis or Electrode-Bound, Heterogeneous CoO x Catalysis? journal September 2018
Water-Nucleophilic Attack Mechanism for the Cu II (pyalk) 2 Water-Oxidation Catalyst journal July 2018
Frontiers of water oxidation: the quest for true catalysts journal January 2017
Polyoxometalate‐Based Compounds for Photo‐ and Electrocatalytic Applications journal August 2020
Polyoxometalate-Supported Bis(2,2′-bipyridine)mono(aqua)nickel(II) Coordination Complex: an Efficient Electrocatalyst for Water Oxidation journal May 2018
Speciation and Dynamics in the [Co 4 V 2 W 18 O 68 ] 10– /Co(II) aq /CoO x Catalytic Water Oxidation System journal November 2018
Multi-Tasking POM Systems journal August 2018
Homogeneous electrocatalytic water oxidation at neutral pH by a robust trinuclear copper(ii)-substituted polyoxometalate journal January 2018
Molecular Catalysts for Water Oxidation journal July 2015
Water oxidation using earth-abundant transition metal catalysts: opportunities and challenges journal January 2016
Covalent bonds immobilization of cofacial Mn porphyrin dimers on an ITO electrode for efficient water oxidation in aqueous solutions journal August 2017
Mimicking the Catalytic Center for the Water-Splitting Reaction in Photosystem II journal February 2020
S = 3 Ground State for a Tetranuclear Mn IV 4 O 4 Complex Mimicking the S 3 State of the Oxygen-Evolving Complex journal February 2020
CaMn 3 IV O 4 Cubane Models of the Oxygen‐Evolving Complex: Spin Ground States S <9/2 and the Effect of Oxo Protonation journal July 2021
The Role of the −OH Groups within Mn 12 Clusters in Electrocatalytic Water Oxidation journal March 2021
Coordination Geometry and Oxidation State Requirements of Corner-Sharing MnO 6 Octahedra for Water Oxidation Catalysis: An Investigation of Manganite (γ-MnOOH) journal February 2016
Efficient Homogeneous Electrocatalytic Water Oxidation by a Manganese Cluster with an Overpotential of Only 74 mV journal January 2019
Cerium(IV)-Driven Water Oxidation Catalyzed by a Manganese(V)-Nitrido Complex journal February 2015
Spectroscopic and electrochemical studies of high-valent water soluble manganese porphyrine. Electrocatalytic water oxidation journal July 2014
Water oxidation on a mononuclear manganese heterogeneous catalyst journal October 2018
Mechanism of Water Oxidation Catalyzed by a Mononuclear Manganese Complex journal February 2017
Characterization of a Dinuclear MnVO Complex and Its Efficient Evolution of O2 in the Presence of Water journal January 2004
Identifying Intermediates in Electrocatalytic Water Oxidation with a Manganese Corrole Complex journal September 2021
Nucleophilic Attack of Hydroxide on a Mn V Oxo Complex: A Model of the O−O Bond Formation in the Oxygen Evolving Complex of Photosystem II journal July 2009
Reversible O−O Bond Cleavage and Formation between Mn(IV)-Peroxo and Mn(V)-Oxo Corroles journal October 2010
Dioxygen Activation and O–O Bond Formation Reactions by Manganese Corroles journal October 2017
A High-Valent Metal-Oxo Species Produced by Photoinduced One-Electron, Two-Proton Transfer Reactivity journal December 2017
Electrocatalytic Water Oxidation by a Copper(II) Complex of an Oxidation-Resistant Ligand journal April 2017
Trans-dioxo Manganese(V) Porphyrins journal October 2007
Modeling the haloperoxidases: Reversible oxygen atom transfer between bromide ion and an oxo-Mn(V) porphyrin journal November 2007
Dissection of the Mechanism of Manganese Porphyrin-Catalyzed Chlorine Dioxide Generation journal October 2011
A “Push−Pull” Mechanism for Heterolytic O−O Bond Cleavage in Hydroperoxo Manganese Porphyrins journal December 2010
Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base journal September 2013
Concerted O atom-proton transfer in the O--O bond forming step in water oxidation journal April 2010
Foot of the Wave Analysis for Mechanistic Elucidation and Benchmarking Applications in Molecular Water Oxidation Catalysis journal November 2016
An Anionic N-Donor Ligand Promotes Manganese-Catalyzed Water Oxidation journal June 2013
Characterization of the O 2 -Evolving Reaction Catalyzed by [(terpy)(H 2 O)Mn III (O) 2 Mn IV (OH 2 )(terpy)](NO 3 ) 3 (terpy = 2,2‘:6,2‘ ‘-Terpyridine) journal January 2001
Sustained Water Oxidation by [Mn4O4]7+ Core Complexes Inspired by Oxygenic Photosynthesis journal August 2009
Oxygen evolving reactions catalysed by synthetic manganese complexes: A systematic screening journal January 2007
On the Homogeneity of a Cobalt-Based Water Oxidation Catalyst journal April 2022
Quantitative Correlation of Relative Rates. Comparison of Hydroxide Ion with Other Nucleophilic Reagents toward Alkyl Halides, Esters, Epoxides and Acyl Halides 1 journal January 1953
Rapid, Reversible Oxygen Atom Transfer between an Oxomanganese(V) Porphyrin and Bromide: A Haloperoxidase Mimic with Enzymatic Rates journal November 2000
Mutation of Lysine 317 in the D2 Subunit of Photosystem II Alters Chloride Binding and Proton Transport journal July 2013
Characterization of ammonia binding to the second coordination shell of the oxygen-evolving complex of photosystem II journal January 2017
Chloride Maintains a Protonated Internal Water Network in the Photosynthetic Oxygen Evolving Complex journal November 2017
Location of chloride and its possible functions in oxygen-evolving photosystem II revealed by X-ray crystallography journal May 2009
Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å journal April 2011
Identification of a Na+-Binding Site near the Oxygen-Evolving Complex of Spinach Photosystem II journal July 2020
Location and function of the high-affinity chloride in the oxygen-evolving complex – Implications from comparing studies on Cl−/Br−/I−-substituted photosystem II prepared using two different methods journal September 2014