Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Isolation and Characterization of a Highly Reducing Aqueous Chromium(II) Complex

Journal Article · · Inorganic Chemistry
 [1];  [2];  [1];  [3];  [1]
  1. Department of Chemistry, University of Colorado Boulder, Boulder, Colorado 80309, United States
  2. Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, Colorado 80309, United States
  3. Joint Center for Energy Storage Research, Raytheon Technologies Research Center, 411 Silver Lane, East Hartford, Connecticut 06108, United States

Not provided.

Research Organization:
Raytheon Technologies Corp., Waltham, MA (United States)
Sponsoring Organization:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
DOE Contract Number:
AR0000994
OSTI ID:
1977885
Journal Information:
Inorganic Chemistry, Vol. 61, Issue 23; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (36)

Interrogation of 2,2′-Bipyrimidines as Low-Potential Two-Electron Electrolytes journal January 2021
Links between electrochemical thermodynamics and kinetics journal September 2015
Heat Evolution and Electrical Work of Batteries as a Function of Discharge Rate: Spontaneous and Reversible Processes and Maximum Work journal March 2018
4.0 V Aqueous Li-Ion Batteries journal September 2017
Cobalt and Vanadium Trimetaphosphate Polyanions: Synthesis, Characterization, and Electrochemical Evaluation for Non-aqueous Redox-Flow Battery Applications journal January 2018
Electrolyte Lifetime in Aqueous Organic Redox Flow Batteries: A Critical Review journal February 2020
Redox potentials and related thermodynamic parameters of (diaminopolycarboxylato)metal(III/II) redox couples journal September 1989
Chelated Chromium Electrolyte Enabling High-Voltage Aqueous Flow Batteries journal October 2019
Effect of Chelation on Iron–Chromium Redox Flow Batteries journal April 2020
Holistic design principles for flow batteries: Cation dependent membrane resistance and active species solubility journal February 2022
Bismuth Electrocatalyst Enabling Reversible Redox Kinetics of a Chelated Chromium Flow Battery Anolyte journal March 2022
Designer Two-Electron Storage Viologen Anolyte Materials for Neutral Aqueous Organic Redox Flow Batteries journal December 2017
A 1.51 V pH neutral redox flow battery towards scalable energy storage journal January 2019
Proton-Coupled Electron Transfer: The Engine of Energy Conversion and Storage journal January 2022
Evaluating aqueous flow battery electrolytes: a coordinated approach journal January 2020
Simple synthetic method and structural characteristics of (1,3-propanediaminetetraacetato)cobalt(II) complexes: uniform crystal packing in a series of metal(II) complexes with 1,3-propanediaminetetraacetate ligand journal August 2003
Tuning the topologies of Co(II) and Ni(II) complexes with EDTA, 1,3-PDTA and 1,4-BDTA ligands: Synthesis and spectroscopic data of [Mg(H2O)6][Co(1,4-bdta)]·3H2O and [Mg(H2O)6][Ni(1,4-bdta)]·3H2O complexes, and the X-ray structure of their chiral crystals journal October 2007
Two distinct manganese(II) complexes with hexadentate 1,3-propanediaminetetraacetate ligand: The ability of metal(II) complexes with 1,3-pdta ligand to form solid solutions journal May 2007
Crystal structures of Na[M(1,3-PDTA)]·3H2O(M = Cr, Rh; 1,3-PDTA = 1,3-propanediaminetetraacetate), and the absolute configuration of the (-)D-Isomer of the Rh complex journal March 1984
Ligand Structural Effects on the Electrochemistry of Chromium(III) Amino Carboxylate Complexes journal January 1996
Iminodiacetato, methyliminodiacetato, and 1,3-propanediaminetetraacetato complexes of chromium(III) journal November 1968
Ligand Field Stabilization and Activation Energies Revisited: Molecular Modeling of the Thermodynamic and Kinetic Properties of Divalent, First-Row Aqua Complexes journal August 2008
Minimizing Oxygen Permeation in Metal-Chelate Flow Batteries journal June 2020
The potential diagram for oxygen at pH 7 journal July 1988
Characterisation of the ferrocene/ferrocenium ion redox couple as a model chemistry for non-aqueous redox flow battery research journal September 2020
Dioxygen-decomposition of ferrocenium molecules in acetonitrile: The nature of the electrode-fouling films during ferrocene electrochemistry journal September 1998
Reactivity of ferrocenium cations with molecular oxygen in polar organic solvents: Decomposition, redox reactions and stabilization journal March 2005
Mechanistic insights of cycling stability of ferrocene catholytes in aqueous redox flow batteries journal January 2022
An interpretation of the formal potential for the ferricyanide / ferrocyanide couple as a function of solvent composition journal October 1990
Synthetic Organic Electrochemistry: Calling All Engineers journal November 2017
Catalyzing Electrosynthesis: A Homogeneous Electrocatalytic Approach to Reaction Discovery journal February 2020
Electrifying Synthesis: Recent Advances in the Methods, Materials, and Techniques for Organic Electrosynthesis journal March 2020
Studies of indirect electrochemical reductions using chromium complexes with polyaminocarboxylate ligands as mediators journal January 1992
A Practical Beginner’s Guide to Cyclic Voltammetry journal November 2017
Empirical parameters for donor and acceptor properties of solvents journal September 1976
Chemical Redox Agents for Organometallic Chemistry journal January 1996