The Renaissance of Non-Aqueous Uranium Chemistry
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June 2015 |
Identification of the +2 Oxidation State for Uranium in a Crystalline Molecular Complex, [K(2.2.2-Cryptand)][(C 5 H 4 SiMe 3 ) 3 U]
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August 2013 |
Chelate-Free Synthesis of the U(II) Complex, [(C 5 H 3 (SiMe 3 ) 2 ) 3 U] 1– , Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs
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August 2018 |
Isolation of a Perfectly Linear Uranium(II) Metallocene
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February 2020 |
Synthesis and Characterization of a Uranium(II) Monoarene Complex Supported by δ Backbonding
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May 2014 |
Synthesis and Characterization of a Neutral U(II) Arene Sandwich Complex
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November 2018 |
A Uranium(II) Arene Complex That Acts as a Uranium(I) Synthon
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November 2021 |
C–H Bond Activation via U(II) in the Reduction of Heteroleptic Bis(trimethylsilyl)amide U(III) Complexes
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September 2020 |
Coordination and Redox Isomerization in the Reduction of a Uranium(III) Monoarene Complex
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July 2014 |
Delivery of a Masked Uranium(II) by an Oxide‐Bridged Diuranium(III) Complex
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December 2020 |
Multiple Syntheses of (C 5 Me 5 ) 3 U
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March 2002 |
Synthesis and properties of a new class of highly reactive trivalent actinide organometallic compounds. Derivatives of bis(pentamethylcyclopentadienyl)uranium(III)
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January 1982 |
Actinide Hydride Complexes as Multielectron Reductants: Analogous Reduction Chemistry from [(C 5 Me 5 ) 2 UH] 2 , [(C 5 Me 5 ) 2 UH 2 ] 2 , and [(C 5 Me 5 ) 2 ThH 2 ] 2
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July 2007 |
Tetravalent and Pentavalent Uranium Acetylide Complexes Prepared by Oxidative Functionalization with CuCCPh
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July 2008 |
Structural variations in cyclopentadienyl uranium(III) iodide complexes
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December 2020 |
Isolation of a [Fe(CO)4]2–-Bridged Diuranium Complex Obtained via Reduction of Fe(CO)5 with Uranium(III)
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May 2021 |
Reactivity of U 3+ Metallocene Allyl Complexes Leads to a Nanometer-Sized Uranium Carbonate, [(C 5 Me 5 ) 2 U] 6 (μ-κ 1 :κ 2 -CO 3 ) 6
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August 2013 |
Four-electron reduction chemistry using a uranium( iii ) phosphido complex
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January 2018 |
From Bent to Linear Uranium Metallocenes: Influence of Counterion, Solvent, and Metal Ion Oxidation State
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November 2006 |
Density Functional Theory and X-ray Analysis of the Structural Variability in η 5 ,η 5 ,η 1 -Tris(ring) Rare Earth/Actinide Tetramethylpyrrolyl Complexes, (C 5 Me 5 ) 2 M(NC 4 Me 4 )
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June 2012 |
An improved method for the computation of ligand steric effects based on solid angles
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January 2006 |
Mono(pentamethylcyclopentadienyl)uranium(III) Complexes: Synthesis, Properties, and X-ray Structures of (η-C 5 Me 5 )UI 2 (THF) 3 , (η-C 5 Me 5 )UI 2 (py) 3 , and (η-C 5 Me 5 )U[N(SiMe 3 ) 2 ] 2
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February 2000 |
Chemistry of sterically crowded aryloxide ligands. 4. Synthesis and structure of mixed chloro aryloxides of tantalum
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August 1984 |
Direct comparison of aryloxide and alkoxide coordination to a dimetal center. Synthesis and structure of bis[isopropoxybis(2,6-dimethylphenoxy)molybdenum(III)](Mo-Mo)
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September 1983 |
Syntheses of the Phenylchalcogenolate Complexes (.eta.5-C5Me5)2Zr(EPh)2 (E = O, S, Se, Te) and (.eta.5-C5H5)2Zr(OPh)2: Structural Comparisons within a Series of Complexes Containing Zirconium-Chalcogen Single Bonds
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November 1995 |
Solid state structure of the tantalum bis-aryl compounds Ta(OAr-2,6R2)3(C6H5)2 (R = CH3, Pri; OAr-2,6R2 = 2,6-dialkylphenoxide): Observation of a lack of correlation of MOAr distances and MOAr angles for aryloxide derivatives of niobium(V) and tantalum(V)
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January 1990 |
Are metal alkoxides linear owing to electrostatic repulsion?
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September 2002 |
Lanthanide Chalcogenolate Complexes: Synthesis and Crystal Structures of the Isoleptic Series [Sm(Tp Me,Me ) 2 ER] (E = O, S, Se, Te; Tp Me,Me = t ris -3,5-Dimethylpyrazolylborate)
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May 2000 |
Synthesis of Heteroleptic Uranium (μ−η 6 :η 6 -C 6 H 6 ) 2− Sandwich Complexes via Facile Displacement of (η 5 -C 5 Me 5 ) 1− by Ligands of Lower Hapticity and Their Conversion to Heteroleptic Bis(imido) Compounds
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December 2009 |
Evidence for Alkane Coordination to an Electron-Rich Uranium Center
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December 2003 |
Uranium(III) Coordination Chemistry and Oxidation in a Flexible Small-Cavity Macrocycle
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November 2014 |
Spontaneous reduction and C–H borylation of arenes mediated by uranium(III) disproportionation
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July 2012 |
Small Molecule Activation by Uranium Tris(aryloxides): Experimental and Computational Studies of Binding of N 2 , Coupling of CO, and Deoxygenation Insertion of CO 2 under Ambient Conditions
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June 2011 |
Synthesis, Structure, and Reactivity of Organometallic .pi.-Complexes of the Rare Earths in the Oxidation State Ln3+ with Aromatic Ligands
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June 1995 |
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
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September 1976 |
Highly reactive organolanthanides. Systematic routes to and olefin chemistry of early and late bis(pentamethylcyclopentadienyl) 4f hydrocarbyl and hydride complexes
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December 1985 |
Investigation of organolanthanide-based carbon-carbon bond formation: synthesis, structure, and coupling reactivity of organolanthanide alkynide complexes, including the unusual structures of the trienediyl complex [(C5Me5)2Sm]2[.mu.-.eta.2:.eta.2-Ph(CH2)2C:C:C:C-(CH2)2Ph] and the unsolvated alkynide [(C5Me5)2Sm(C.tplbond.CCMe3)]2
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July 1993 |
Carbon Monoxide and Isocyanide Complexes of Trivalent Uranium Metallocenes
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October 1999 |
Activity of[Sm(C5Me5)3] in Ethylene Polymerization and Synthesis of[U(C5Me5)3], the First Tris(pentamethylcyclopentadienyl) 5f-Element Complex
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April 1997 |
Rare‐Earth Metal(II) Aryloxides: Structure, Synthesis, and EPR Spectroscopy of [K(2.2.2‐cryptand)][Sc(OC 6 H 2 t Bu 2 ‐2,6‐Me‐4) 3 ]
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November 2018 |
A Room-Temperature Stable Y(II) Aryloxide: Using Steric Saturation to Kinetically Stabilize Y(II) Complexes
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February 2020 |
Reactivity of (C5Me5)2Sm with cyclopentadiene and cyclopentadienide: isolation of the mixed-valence complex (C5Me5)2Sm(III)(.mu.-C5H5)Sm(II)(C5Me5)2
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July 1987 |
Cyclopentadienyl ring metathesis with bis(pentamethylcyclopentadienyl)calcium as a route to mixed ring organolanthanide complexes; the crystal structure of (C5Me5)2Nd(C5H5)
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January 1995 |
Tris(polyalkylcyclopentadienyl) Complexes: The Elusive [(η5-C5R5)2M(η1-C5R5)] Structure and Trihapto Cyclopentadienyl Coordination Involving a Methyl Substituent
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December 2010 |
Dinitrogen Reduction via Photochemical Activation of Heteroleptic Tris(cyclopentadienyl) Rare-Earth Complexes
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March 2013 |
Chemistry of Tris(pentamethylcyclopentadienyl) f-Element Complexes, (C 5 Me 5 ) 3 M
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June 2002 |
Synthesis of (C 5 Me 5 ) 2 (C 5 Me 4 H)UMe, (C 5 Me 5 ) 2 (C 5 H 5 )UMe, and (C 5 Me 5 ) 2 UMe[CH(SiMe 3 ) 2 ] from Cationic Metallocenes for the Evaluation of Sterically Induced Reduction
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November 2008 |
Reactivity of dicyclopentadienylbis(diethylamido)uranium(IV). Reactions with carboxylic and thiocarboxylic acids
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August 1981 |
Organosamarium-Mediated Transformations of CO 2 and COS: Monoinsertion and Disproportionation Reactions and the Reductive Coupling of CO 2 to [O 2 CCO 2 ] 2-
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February 1998 |
Facile Insertion of CO 2 into Tetra- and Pentamethylcyclopentadienyl Lanthanide Moieties To Form (C 5 Me 4 RCO 2 ) - Carboxylate Ligands (R = H, Me)
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September 2007 |
Expanding the chemistry of U3+ reducing agents
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April 2006 |
Trends in Electronic Structure and Redox Energetics for Early-Actinide Pentamethylcyclopentadienyl Complexes
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October 2004 |
The Electronic Influence of Ring Substituents and Ansa Bridges in Zirconocene Complexes as Probed by Infrared Spectroscopic, Electrochemical, and Computational Studies
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August 2002 |
Expanding the Chemistry of Molecular U 2+ Complexes: Synthesis, Characterization, and Reactivity of the {[C 5 H 3 (SiMe 3 ) 2 ] 3 U} − Anion
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December 2015 |
Structure of K+(cryptand[2.2.2J) electride and evidence for trapped electron pairs
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February 1988 |
Tetramethylcyclopentadienyl Ligands Allow Isolation of Ln(II) Ions across the Lanthanide Series in [K(2.2.2-cryptand)][(C 5 Me 4 H) 3 Ln] Complexes
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October 2018 |
Synthesis of a Heteroleptic Pentamethylcyclopentadienyl Yttrium(II) Complex, [K(2.2.2-Cryptand)]{(C5Me5)2YII[N(SiMe3)2]}, and Its C–H Bond Activated Y(III) Derivative
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November 2021 |
Comparative assessment of a new nonempirical density functional: Molecules and hydrogen-bonded complexes
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December 2003 |
COSMO Implementation in TURBOMOLE: Extension of an efficient quantum chemical code towards liquid systems
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January 2000 |
Harnessing the meta-generalized gradient approximation for time-dependent density functional theory
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October 2012 |
Synthesis, Structure, and Magnetism of Tris(amide) [Ln{N(SiMe 3 ) 2 } 3 ] 1− Complexes of the Non-traditional +2 Lanthanide Ions
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May 2018 |
TURBOMOLE: Modular program suite for ab initio quantum-chemical and condensed-matter simulations
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May 2020 |
Density Functional Theory Analysis of the Importance of Coordination Geometry for 5f 3 6d 1 versus 5f 4 Electron Configurations in U(II) Complexes
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October 2021 |