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Mechanisms of Electrochemical N 2 Splitting by a Molybdenum Pincer Complex

Journal Article · · Inorganic Chemistry
 [1];  [2];  [2];  [1]
  1. Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599-3290, United States
  2. Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903, United States
+ Show Author Affiliations

Not provided.

Research Organization:
University of North Carolina, Chapel Hill, NC (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0021173
OSTI ID:
1977879
Journal Information:
Inorganic Chemistry, Vol. 61, Issue 4; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (45)

Detonator of the population explosion journal July 1999
How a century of ammonia synthesis changed the world journal September 2008
Electrochemical Synthesis of Ammonia: A Low Pressure, Low Temperature Approach journal January 2015
Nitrogen fertilizers manufactured using wind power: greenhouse gas and energy balance of community-scale ammonia production journal November 2015
Potential Economic Feasibility of Direct Electrochemical Nitrogen Reduction as a Route to Ammonia journal May 2020
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center journal July 2003
Catalytic conversion of nitrogen molecule into ammonia using molybdenum complexes under ambient reaction conditions journal January 2021
Catalytic Reduction of N 2 to Borylamine at a Molybdenum Complex journal August 2021
Comprehensive insights into synthetic nitrogen fixation assisted by molecular catalysts under ambient or mild conditions journal January 2021
Electrosynthesis of ammonia journal October 1985
Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring p K a Effects and Demonstrating Electrocatalysis journal April 2018
Mechanism of Chemical and Electrochemical N 2 Splitting by a Rhenium Pincer Complex journal May 2018
Electrochemical Reduction of N 2 to NH 3 at Low Potential by a Molecular Aluminum Complex journal October 2018
Dinitrogen‐Molybdenum Complex Induces Dinitrogen Cleavage by One‐Electron Oxidation journal August 2019
(Electro‐)chemical Splitting of Dinitrogen with a Rhenium Pincer Complex journal January 2020
A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia journal December 2010
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center journal December 2005
Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia journal April 2014
Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand journal June 2014
Catalytic Nitrogen Fixation via Direct Cleavage of Nitrogen–Nitrogen Triple Bond of Molecular Dinitrogen under Ambient Reaction Conditions journal October 2017
Molybdenum-catalysed ammonia production with samarium diiodide and alcohols or water journal April 2019
Reaction Parameters Influencing Cobalt Hydride Formation Kinetics: Implications for Benchmarking H 2 -Evolution Catalysts journal December 2016
Elements of Molecular and Biomolecular Electrochemistry: An Electrochemical Approach to Electron Transfer Chemistry journal June 2019
Cycling between Molybdenum‐Dinitrogen and ‐Nitride Complexes to Support the Reaction Pathway for Catalytic Formation of Ammonia from Dinitrogen journal September 2020
Electron-transfer reactions in nitrogen fixation. Part 1. The electrosynthesis of dinitrogen, hydride, isocyanide, and carbonyl complexes of molybdenum: intermediates, mechanisms, and energetics journal January 1985
Technetium electrochemistry. 4. Electrochemical and spectroelectrochemical studies on the bis(tertiary phosphine or arsine (D))rhenium(III) complexes, trans-[ReD2X2]+ (X = Cl, Br). Comparison with the technetium(III) analogues journal September 1987
Electrochemical parametrization of rhenium redox couples journal May 1991
Redox-Catalyzed Binding of Dinitrogen by Molybdenum N - tert -Hydrocarbylanilide Complexes:  Implications for Dinitrogen Functionalization and Reductive Cleavage journal November 1999
A 10 6 -Fold Enhancement in N 2 -Binding Affinity of an Fe 2 (μ-H) 2 Core upon Reduction to a Mixed-Valence Fe II Fe I State journal September 2014
Bimetallic Cobalt–Dinitrogen Complexes: Impact of the Supporting Metal on N 2 Activation journal July 2015
A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench 57 Fe Mössbauer Data, and a Hydride Resting State journal January 2016
Terpyridine Molybdenum Dinitrogen Chemistry: Synthesis of Dinitrogen Complexes That Vary by Five Oxidation States journal March 2016
Dinitrogen Coupling to a Terpyridine-Molybdenum Chromophore Is Switched on by Fermi Resonance journal February 2019
Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex journal January 2013
Metal–dioxygen and metal–dinitrogen complexes: where are the electrons? journal January 2010
N2 Cleavage by Three-Coordinate Group 6 Complexes. W(III) Complexes Would Be Better Than Mo(III) Complexes journal December 1995
Dinitrogen Cleavage by Three-Coordinate Molybdenum(III) Complexes:  Mechanistic and Structural Data 1 journal January 1996
Considering Electrocatalytic Ammonia Synthesis via Bimetallic Dinitrogen Cleavage journal August 2020
Understanding Terminal versus Bridging End-on N 2 Coordination in Transition Metal Complexes journal June 2021
Simple construction of an infrared optically transparent thin-layer electrochemical cell journal November 1991
Dinitrogen Reduction to Ammonium at Rhenium Utilizing Light and Proton-Coupled Electron Transfer journal November 2019
N 2 Reduction into Silylamine at Tridentate Phosphine/Mo Center: Catalysis and Mechanistic Study journal October 2015
Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation: Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation journal September 2016
Disproportionation and ECE mechanisms—I. Theoretical analysis. Relationships for linear sweep voltammetry journal April 1968
Mediated Fuel Cells: Soluble Redox Mediators and Their Applications to Electrochemical Reduction of O 2 and Oxidation of H 2 , Alcohols, Biomass, and Complex Fuels journal March 2020

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