Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Isolation of a Side-On V(III)-(η 2 -O 2 ) through the Intermediacy of a Low-Valent V(II) in a Metal–Organic Framework

Journal Article · · Inorganic Chemistry
; ; ; ; ; ; ;

Not provided.

Research Organization:
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0016214
OSTI ID:
1977873
Journal Information:
Inorganic Chemistry, Vol. 60, Issue 23; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (37)

Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications journal January 2020
Interplay of Electronic and Steric Effects to Yield Low‐Temperature CO Oxidation at Metal Single Sites in Defect‐Engineered HKUST‐1 journal April 2020
Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites journal October 2018
Design of a Metal–Organic Framework with Enhanced Back Bonding for Separation of N 2 and CH 4 journal December 2013
Selective nitrogen adsorption via backbonding in a metal–organic framework with exposed vanadium sites journal February 2020
Synthesis and O 2 Reactivity of a Titanium(III) Metal–Organic Framework journal October 2015
Ti 3+ -, V 2+/3+ -, Cr 2+/3+ -, Mn 2+ -, and Fe 2+ -Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5 journal August 2013
Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal–Organic Framework journal July 2018
Matrix Isolation Chemistry in a Porous Metal−Organic Framework:  Photochemical Substitutions of N 2 and H 2 in Zn 4 O[(η 6 -1,4-Benzenedicarboxylate)Cr(CO) 3 ] 3 journal January 2008
Enabling Access to Reduced Open-Metal Sites in Metal-Organic Framework Materials through Choice of Anion Identity: The Case of MIL-100(Cr) journal June 2020
Investigation of Acid Sites in a Zeotypic Giant Pores Chromium(III) Carboxylate journal March 2006
Synthesis and properties of the metal-organic framework Mo3(BTC)2 (TUDMOF-1) journal January 2006
Recent advances in post-synthetic modification of metal–organic frameworks: New types and tandem reactions journal January 2019
Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption journal June 2010
Crystallographic characterization of the metal–organic framework Fe 2 (bdp) 3 upon reductive cation insertion journal January 2020
Doping activated carbon incorporated composite MIL-101 using lithium: impact on hydrogen uptake journal January 2015
Quo vadis niobium ? Divergent coordination behavior of early-transition metals towards MOF-5 journal January 2019
Low Temperature Activation of Supported Metathesis Catalysts by Organosilicon Reducing Agents journal August 2016
Salt-Free Reduction of Transition Metal Complexes by Bis(trimethylsilyl)cyclohexadiene, -dihydropyrazine, and -4,4′-bipyridinylidene Derivatives journal February 2019
1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadienes as Strong Salt-Free Reductants for Generating Low-Valent Early Transition Metals with Electron-Donating Ligands journal March 2014
Bis(imido)vanadium(V)-Catalyzed [2+2+1] Coupling of Alkynes and Azobenzenes Giving Multisubstituted Pyrroles journal February 2019
Revised Pourbaix diagrams for the vanadium – water system journal February 2019
Accelerated Synthesis of a Ni 2 Cl 2 (BTDD) Metal–Organic Framework in a Continuous Flow Reactor for Atmospheric Water Capture journal March 2021
Solvothermal Crystallization Kinetics and Control of Crystal Size Distribution of MOF-808 in a Continuous Flow Reactor journal October 2021
A continuous flow chemistry approach for the ultrafast and low-cost synthesis of MOF-808 journal January 2021
Selective Binding of O 2 over N 2 in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites journal September 2011
Selective, High-Temperature O 2 Adsorption in Chemically Reduced, Redox-Active Iron-Pyrazolate Metal–Organic Frameworks journal August 2020
Biomimetic O 2 adsorption in an iron metal–organic framework for air separation journal January 2020
Ligand Field Spectrum of Vanadium(II) Hexaquo Ions. journal January 1958
A new route for substitution of the bridging acetate on the oxo-centered triruthenium acetate cluster journal January 2009
Vanadium Analogues of Nonfunctionalized and Amino-Functionalized MOFs with MIL-101 Topology - Synthesis, Characterization, and Gas Sorption Properties journal April 2012
Photoelectron spectroscopy study of oxygen vacancy on vanadium oxides surface journal September 2004
New trinuclear, oxo-centered, basic carboxylate compounds of transition metals. 3. Syntheses and x-ray studies of the trivanadium(III,III,III) and trivanadium(II,III,III) compounds [V3(.mu.3-O)(CH3CO2)6(CH3COOH)2(THF)]+[VCl4(CH3COOH)2]- and V3(.mu.3-O)(CF3CO2)6(THF)3 with "classical" triangular structures journal September 1982
Structural, Spectroscopic, and Magnetochemical Characterization of the Trinuclear Vanadium(III) Carboxylates [V 3 O(O 2 CR) 6 L 3 ](ClO 4 ) (R = Various Groups; L = Pyridine, 4-Picoline, 3,5-Lutidine) journal January 1996
Variable character of O--O and M--O bonding in side-on ( 2) 1:1 metal complexes of O2 journal March 2003
Crystal structure of a side-on superoxo complex of cobalt and hydrogen abstraction by a reactive terminal oxo ligand journal March 1990
O 2 Activation with a Sterically Encumbered, Oxygen-Deficient Polyoxovanadate-Alkoxide Cluster journal June 2021

Similar Records

Structural Diversities in Heterometallic Mn–Ca Cluster Chemistry from the Use of Salicylhydroxamic Acid: {MnIII4Ca2}, {MnII/III6Ca2}, {MnIII/IV8Ca}, and {MnIII8Ca2} Complexes with Relevance to Both High- and Low-Valent States of the Oxygen-Evolving Complex
Journal Article · 2017 · Inorganic Chemistry · OSTI ID:1530297
+10 more
Co11Li[(OH)5O][(PO3OH)(PO4)5], a Lithium-Stabilized, Mixed-Valent Cobalt(II,III) Hydroxide Phosphate Framework
Journal Article · 2017 · Inorganic Chemistry · OSTI ID:1532262
+2 more
Cs 3 RE III Ge 3 O 9 (RE = Pr, Nd, and Sm–Yb) and Cs 8 Tb III 2 Tb IV Ge 9 O 27 : A Rare Example of a Mixed-Valent Tb(III)/Tb(IV) Oxide
Journal Article · 2019 · Inorganic Chemistry · OSTI ID:1612655
+1 more

Related Subjects

Chemistry