Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Synthesis of Parent Acetylide and Dicarbide Complexes of Thorium and Uranium and an Examination of Their Electronic Structures

Journal Article · · Inorganic Chemistry
 [1];  [2];  [3];  [1];  [2];  [1]
  1. Department of Chemistry and Biochemistry, University of California—Santa Barbara, Santa Barbara, California 93106, United States
  2. Department of Chemistry, University at Buffalo, State University of New York, Buffalo, New York 14260, United States
  3. Organisch-Chemisches Institut, University of Münster, Corrensstraße 40, Münster 48149, Germany
+ Show Author Affiliations

Not provided.

Research Organization:
State Univ. of New York (SUNY), Albany, NY (United States); Univ. of California, Santa Barbara, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0001136; SC0001861
OSTI ID:
1977867
Journal Information:
Inorganic Chemistry, Vol. 60, Issue 20; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (52)

The Catalytic Effect in Opening an Organoactinide Metal Coordination Sphere:  Regioselective Dimerization of Terminal Alkynes and Hydrosilylation of Alkynes and Alkenes with PhSiH 3 Promoted by Me 2 SiCp‘ ‘ 2 Th n Bu 2 November 2001
Intermolecular Hydroamination of Terminal Alkynes Catalyzed by Organoactinide Complexes. Scope and Mechanistic Studies November 2001
Cross dimerization of terminal alkynes catalyzed by [(Et2N)3U][BPh4] May 2002
Organoactinides—novel catalysts for demanding chemical transformations October 2002
Towards uranium catalysts September 2008
Insertion of Carbodiimides and Organic Azides into Actinide−Carbon Bonds June 2009
Oligomerization and Cross-Oligomerization of Terminal Alkynes Catalyzed by Organoactinide Complexes April 1999
Controlling the Catalytic Oligomerization of Terminal Alkynes Promoted by Organoactinides:  A Strategy to Short Oligomers March 1999
Selective Dimerization of Terminal Alkynes Promoted by the Cationic Actinide Compound [(Et 2 N) 3 U][BPh 4 ]. Formation of the Alkyne π-Complex [(Et 2 N) 2 U(C⋮C t Bu)(η 2 -HC⋮C t Bu)][BPh 4 ] June 1999
Selective Oligomerization and [2 + 2 + 2] Cycloaddition of Terminal Alkynes from Simple Actinide Precatalysts August 2015
Thorium(IV) and Uranium(IV) trans -Calix[2]benzene[2]pyrrolide Alkyl and Alkynyl Complexes: Synthesis, Reactivity, and Electronic Structure September 2017
Experimental Evidence for Magnetic Exchange in Di- and Trinuclear Uranium(IV) Ethynylbenzene Complexes February 2010
Investigation of the Electronic Structure of Aryl-Bridged Dinuclear U(III) and U(IV) Compounds February 2019
13 C NMR Shifts as an Indicator of U–C Bond Covalency in Uranium(VI) Acetylide Complexes: An Experimental and Computational Study March 2019
Stable Uranium(VI) Methyl and Acetylide Complexes and the Elucidation of an Inverse Trans Influence Ligand Series August 2013
Use of 77 Se and 125 Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(E n ){N(SiMe 3 ) 2 } 3 ] − (E = Se, Te; n = 1, 2) and Their Oxo-Uranium(VI) Congeners January 2016
Use of 15 N NMR spectroscopy to probe covalency in a thorium nitride January 2019
Probing the Electronic Structure of a Thorium Nitride Complex by Solid-State 15 N NMR Spectroscopy June 2020
Molecular Thorium Compounds with Dichalcogenide Ligands: Synthesis, Structure, 77 Se NMR Study, and Thermolysis November 2018
A Rare Uranyl(VI)-Alkyl Ate Complex [Li(DME) 1.5 ] 2 [UO 2 (CH 2 SiMe 3 ) 4 ] and Its Comparison with a Homoleptic Uranium(VI)-Hexaalkyl February 2013
Synthesis, structure and bonding of hexaphenyl thorium( iv ): observation of a non-octahedral structure January 2016
Synthesis, Thermochemistry, Bonding, and 13 C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium April 2017
Synthesis and Characterization of Two Uranyl‐Aryl “Ate” Complexes January 2021
Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift March 2021
Phosphorano-Stabilized Carbene Complexes with Short Thorium(IV)– and Uranium(IV)–Carbon Bonds June 2018
The Crystal and Molecular Structure of Tricyclopentadienylethynyluranium(Iv) September 1976
A bimetallic uranium μ-dicarbide complex: synthesis, X-ray crystal structure, and bonding January 2010
Synthesis of an Alkyne-Bridged Decamethylhafnocene Dimer and Related Alkyne-Substituted Monomers October 1996
Insertion, protonolysis and photolysis reactivity of a thorium monoalkyl amidinate complex January 2018
The Infra‐Red Spectrum of Acetylene October 1950
Preparation of a potassium chloride bridged thorium phosphinidiide complex and its reactivity towards small organic molecules January 2019
Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination September 2017
Formation of Trivalent U–C, U–N, and U–S Bonds and Their Reactivity toward Carbon Dioxide and Acetone November 2011
Synthesis, structure, and spectroscopic properties of copper( II ) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper( II ) perchlorate January 1984
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides September 1976
Trapping of Acetylene by a Zirconocene Terminal Imido Complex May 2000
Synthesis and Structure of a New Bis[(trimethylphosphan)titanocene] Complex with a Bridging C 2 Unit October 1992
Magnetic Susceptibility of Uranium Complexes August 2014
Small molecule activation at uranium coordination complexes: control of reactivity via molecular architecture January 2006
Uranium( iv ) terminal hydrosulfido and sulfido complexes: insights into the nature of the uranium–sulfur bond January 2016
Systematic Studies of Early Actinide Complexes:  Uranium(IV) Fluoroketimides September 2007
Ferromagnetic exchange coupling in the linear, chloride-bridged cluster (cyclam)CoII[(μ-Cl)UIV(Me2Pz)4]2 September 2008
Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with U IV –E–U IV cores (E = S, Se, Te): implications for determining the presence or absence of actinide–actinide magnetic exchange January 2017
Natural bond orbital methods: Natural bond orbital methods June 2011
Homoleptic Aryl Complexes of Uranium (IV) July 2019
Homoleptic Perchlorophenyl “Ate” Complexes of Thorium(IV) and Uranium(IV) July 2021
Comparison of the Reactivity of 2-Li-C 6 H 4 CH 2 NMe 2 with MCl 4 (M=Th, U): Isolation of a Thorium Aryl Complex or a Uranium Benzyne Complex August 2013
Relativistic Density-Functional Computations of the Chemical Shift of 129 Xe in Xe@C 60 May 2003
Organometallic Complexes for Nonlinear Optics. 30. 1 Electrochromic Linear and Nonlinear Optical Properties of Alkynylbis(diphosphine)ruthenium Complexes December 2002
Group 8 metal alkynyl complexes for nonlinear optics February 2014
Iron Alkynyl Helicenes: Redox-Triggered Chiroptical Tuning in the IR and Near-IR Spectral Regions and Suitable for Telecommunications Applications May 2016
Metal Alkynyl σ Complexes: Synthesis and Materials June 2003

Similar Records

Related Subjects

Chemistry