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Influence of Outer-Sphere Anions on the Photoluminescence from Samarium(II) Crown Complexes

Journal Article · · Inorganic Chemistry

Not provided.

Research Organization:
Florida State Univ., Tallahassee, FL (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0010677
OSTI ID:
1977862
Journal Information:
Inorganic Chemistry, Vol. 60, Issue 20; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (69)

Synthesis, spectroscopic properties and applications of divalent lanthanides apart from Eu2+ June 2019
Magnetism of Lanthanides in Molecular Materials with Transition-Metal Ions and Organic Radicals June 2002
Magnetic Anisotropy in Divalent Lanthanide Compounds May 2020
Aqueous Lanthanide Chemistry in Asymmetric Catalysis and Magnetic Resonance Imaging February 2016
Complex formation of the lanthanides and actinides in lower oxidation states June 1991
Messungen an zwei- und vierwertigen Verbindungen der seltenen. Erden. I. Beiträge zur Kenntnis der Samariumhalogenide November 1928
Messungen an zwei- und vierwertigen Verbindungen der seltenen Erden. VII. Über die Struktur einiger Dihalogenide May 1939
Electronic Structure and Properties of Berkelium Iodates September 2017
Spectroscopic Properties of Rare Earths September 1965
Structural, Spectroscopic, and Theoretical Comparison of Traditional vs Recently Discovered Ln 2+ Ions in the [K(2.2.2-cryptand)][(C 5 H 4 SiMe 3 ) 3 Ln] Complexes: The Variable Nature of Dy 2+ and Nd 2+ December 2014
Solid-State Optical Maser Using Divalent Samarium in Calcium Fluoride [Letter to the Editor] January 1961
Magnetic Moment and Hyperfine Structure Coupling of the First 2+ State in Gd 154 March 1961
Divalent Rare Earth Spectra Selection Rules and Spectroscopy of Sr Cl 2 : Sm 2 + May 1963
Fluorescence Spectrum and the Energy Levels of the Sm 2+ Ion January 1962
Divalent lanthanide derivatives in organic synthesis. 1. Mild preparation of samarium iodide and ytterbium iodide and their use as reducing or coupling agents April 1980
Large Scale Synthesis of Dysprosium and Neodymium Diiodides May 2003
Fluorescence from Samarium(II) Iodide and Its Electron Transfer Quenching:  Dynamics of the Reaction of Benzyl Radicals with Sm(II) January 1996
Luminescence study of reduced samarium in barium lithium nonaborate and barium sodium nonaborate May 2020
Luminescence and vacuum ultraviolet excitation spectroscopy of samarium doped SrB4O7 June 2020
Pentagonal-bipyramidal acetonitrile complexes of the lanthanide(II) iodides April 2020
Quantification of the Interaction of SmI 2 with Substrates and Ligands April 2020
7-Siloxy-Substituted Hexahydronaphthalene Derivatives: Samarium Diiodide Promoted Synthesis and Typical Reactions June 2020
Samarium(II)-Iodide-Mediated Cyclizations in Natural Product Synthesis May 2004
Switching between Novel Samarium(II)-Mediated Cyclizations by a Simple Change in Alcohol Cosolvent November 2003
Synthesis and Structure of New Soluble Organosamarium(II) Reagents: (indenyl)2Sm(THF) and (fluorenyl)2Sm(THF)2 April 1994
Utility of Organosamarium(II) Reagents in the Formation of Polyatomic Group 16 Element Anions: Synthesis and Structure of [(C5Me5)2Sm]2(E3)(THF), [(C5Me5)2Sm(THF)]2(E), and Related Species (E = S, Se, Te) June 1994
The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides October 1992
On the existence of divalent californium in aqueous solution May 1968
Oxidatively Stable, Aqueous Europium(II) Complexes through Steric and Electronic Manipulation of Cryptand Coordination Chemistry October 2010
Synthesis of Ln II ‐in‐Cryptand Complexes by Chemical Reduction of Ln III ‐in‐Cryptand Precursors: Isolation of a Nd II ‐in‐Cryptand Complex June 2020
Electrochemical Studies of Selected Lanthanide and Californium Cryptates July 2019
Europium(II) complexes with unsubstituted crown ethers January 2003
The luminescent properties of divalent europium complexes of crown ethers and cryptands March 1998
Two complexes of Sm( ii ) with crown ethers—electrochemical synthesis, structure and spectroscopy January 2004
Molecular and Electronic Structure, and Hydrolytic Reactivity of a Samarium(II) Crown Ether Complex February 2019
Trivalent scandium, yttrium and lanthanide complexes with thia-oxa and selena-oxa macrocycles and crown ether coordination January 2013
PREPARATION AND STRUCTURE OF THE [YbCl 2 ·15-CROWN-5] + CATION, AN EXAMPLE OF SEVEN-COORDINATE YTTERBIUM July 1987
Primary to secondary sphere coordination of 15-crown-5 to lanthanide(III) chlorides: structural analysis of [MCl3(15-crown-5)] (M=La, Ce) and [Er(OH2)8]Cl3·15-crown-5 August 1994
Cationic rare-earth-metal methyl complexes: a new preparative access exemplified for Y and Pr January 2010
Direct comparison of the preparation and structural features of crown ether and polyethylene glycol complexes of neodymium trichloride hexahydrate December 1991
Syntheses, structures and magnetic properties of a series of mono- and di-nuclear dysprosium( iii )-crown-ether complexes: effects of a weak ligand-field and flexible cyclic coordination modes January 2016
Placing a crown on Dy III – a dual property Ln III crown ether complex displaying optical properties and SMM behaviour January 2015
Stabilising small clusters: synthesis and characterisation of thermolabile [Gd4F7(15-crown-5)4][AsF6]5·6SO2 January 2005
Structure of the pentahydrate of the samarium(III) perchlorate complex with the crown polyether 1,4,7,10,13-pentaoxacyclopentadecane, [Sm(C10H20O5)2(H2O)4]3+.3ClO4−.H2O October 1983
Stoichiometry and Structure of the Complexes Between Lanthanide Ions and Macrocyclic Crown Ethers Containing from Four to Seven Coordinating Sites January 1984
An electrochemical investigation of the effect of macrocycle ring size on the binding of di- and trivalent lanthanide cations by 12-crown-4, 15-crown-5, 4-tert-butylbenzo-15-crown-5, and dibenzo-30-crown-10 in propylene carbonate June 1982
Effect of Crown Ethers on the Ground and Excited State Reactivity of Samarium Diiodide in Acetonitrile February 2012
Solvation-Controlled Luminescence of SmII Complexes February 2007
SHELXT – Integrated space-group and crystal-structure determination January 2015
OLEX2 : a complete structure solution, refinement and analysis program January 2009
A complete active space SCF method (CASSCF) using a density matrix formulated super-CI approach May 1980
OpenMolcas: From Source Code to Insight September 2019
Main Group Atoms and Dimers Studied with a New Relativistic ANO Basis Set December 2003
New Relativistic Atomic Natural Orbital Basis Sets for Lanthanide Atoms with Applications to the Ce Diatom and LuF 3 November 2008
Relativistic electronic-structure calculations employing a two-component no-pair formalism with external-field projection operators June 1986
Understanding the Stabilization and Tunability of Divalent Europium 2.2.2B Cryptates May 2021
Development and applications of the LFDFT: the non-empirical account of ligand field and the simulation of the f–d transitions by density functional theory January 2015
A DFT-based theoretical model for the calculation of spectral profiles of lanthanide M 4,5 -edge x-ray absorption August 2018
Perdew, Burke, and Ernzerhof Reply: January 1998
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu April 2010
Relativistic regular two‐component Hamiltonians September 1993
Effects of changing the M 2+ cation on the crystal structure and optical properties of divalent samarium-doped MAl 2 Si 2 O 8 (M = Ca, Sr, Ba) January 2015
New Insights into the Influence of the 4f 5 5d 1 State in the 4f 6 Electronic Configuration of Sm 2+ in Crystal Hosts March 2019
Optical Absorption Intensities of Rare-Earth Ions August 1962
Intensities of Crystal Spectra of Rare‐Earth Ions August 1962
Interference between Judd-Ofelt and Wybourne-Downer mechanisms in the 5 D 0 − 7 F J ( J =2,4) transitions of Sm 2 + in solids January 1996
Radial correlation effects on interconfigurational excitations at the end of the lanthanide series: A restricted active space second order perturbation study of Yb 2+ and SrCl 2 :Yb 2+ February 2013
Energy Level Structure and Multiple 4f 12 5d 1 Emission Bands for Tm 2+ in Halide Perovskites: Theory and Experiment May 2017
Relation between high-pressure spectroscopy and f n − 1 d 1 excited-state geometry: A comparison between theoretical and experimental results in Sr F 2 : Sm 2 + September 2007