Ultrathin MnO 2 -Coated FeOOH Catalyst for Indoor Formaldehyde Oxidation at Ambient Temperature: New Insight into Surface Reactive Oxygen Species and In-Field Testing in an Air Cleaner

Wang, Can; Han, Zhengyan; Zou, Xuehua; Liu, Haibo; Wang, Hanlin; Shu, Daobing; Chen, Tianhu; Suib, Steven L.

doi:10.1021/acs.est.2c02663

Ultrathin MnO ₂ -Coated FeOOH Catalyst for Indoor Formaldehyde Oxidation at Ambient Temperature: New Insight into Surface Reactive Oxygen Species and In-Field Testing in an Air Cleaner

Journal Article · 15 July 2022 · Environmental Science and Technology

DOI:https://doi.org/10.1021/acs.est.2c02663· OSTI ID:1977841

Wang, Can ^[1]; Han, Zhengyan ^[2]; Zou, Xuehua ^[3]; ^[2]; Wang, Hanlin ^[2]; Shu, Daobing ^[2]; ^[2]; ^[4]

School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, China; Key Laboratory of Nano-minerals and Pollution Control of Anhui Higher Education Institutes, Hefei University of Technology, Hefei 230009, China; OSTI
School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, China; Key Laboratory of Nano-minerals and Pollution Control of Anhui Higher Education Institutes, Hefei University of Technology, Hefei 230009, China
School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, China; Key Laboratory of Nano-minerals and Pollution Control of Anhui Higher Education Institutes, Hefei University of Technology, Hefei 230009, China; Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States
Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States

Not provided.

Research Organization:: Univ. of Connecticut, Storrs, CT (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-86ER13622

OSTI ID:: 1977841

Journal Information:: Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 15 Vol. 56; ISSN 0013-936X

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (42)

Potassium associated manganese vacancy in birnessite-type manganese dioxide for airborne formaldehyde oxidation Rong, Shaopeng; Li, Kezhi; Zhang, Pengyi Catalysis Science & Technology, Vol. 8, Issue 7 https://doi.org/10.1039/C7CY02121F	journal	January 2018
Defective domain control of TiO2 support in Pt/TiO2 for room temperature formaldehyde (HCHO) remediation Ahmad, Waleed; Park, Eunseuk; Lee, Heehyeon Applied Surface Science, Vol. 538 https://doi.org/10.1016/j.apsusc.2020.147504	journal	February 2021
Formaldehyde sources, formaldehyde concentrations and air exchange rates in European housings Salthammer, Tunga Building and Environment, Vol. 150 https://doi.org/10.1016/j.buildenv.2018.12.042	journal	March 2019
Corrosion Motivated ROS Generation Helps Endow Titanium with Broad‐Spectrum Antibacterial Abilities Wang, Donghui; Li, Qianwen; Qiu, Jiajun Advanced Materials Interfaces, Vol. 6, Issue 17 https://doi.org/10.1002/admi.201900514	journal	July 2019
Advances on transition metal oxides catalysts for formaldehyde oxidation: A review Yusuf, Abubakar; Snape, Colin; He, Jun Catalysis Reviews, Vol. 59, Issue 3 https://doi.org/10.1080/01614940.2017.1342476	journal	July 2017
Biomimetic design of ultrathin edge-riched FeOOH@Carbon nanotubes as high-efficiency electrocatalysts for water splitting Li, Huanxin; Zhou, Qiang; Liu, Fuyu Applied Catalysis B: Environmental, Vol. 255 https://doi.org/10.1016/j.apcatb.2019.117755	journal	October 2019
Environmental Implications of Hydroxyl Radicals ( ^• OH) Gligorovski, Sasho; Strekowski, Rafal; Barbati, Stephane Chemical Reviews, Vol. 115, Issue 24 https://doi.org/10.1021/cr500310b	journal	December 2015
Phase-controlled synthesis of polymorphic MnO ₂ structures for electrochemical energy storage Yin, Bosi; Zhang, Siwen; Jiang, He Journal of Materials Chemistry A, Vol. 3, Issue 10 https://doi.org/10.1039/C4TA06943A	journal	January 2015
Promoted catalytic transformation of polycyclic aromatic hydrocarbons by MnO2 polymorphs: Synergistic effects of Mn3+ and oxygen vacancies Wang, Zhiqiang; Jia, Hanzhong; Zheng, Tao Applied Catalysis B: Environmental, Vol. 272 https://doi.org/10.1016/j.apcatb.2020.119030	journal	September 2020
Reactive species in advanced oxidation processes: Formation, identification and reaction mechanism Wang, Jianlong; Wang, Shizong Chemical Engineering Journal, Vol. 401 https://doi.org/10.1016/j.cej.2020.126158	journal	December 2020
The Research on Formaldehyde Concentration Distribution in New Decorated Residential Buildings Liu, Liying; Yu, Xiaoping; Dong, Xiukun Procedia Engineering, Vol. 205 https://doi.org/10.1016/j.proeng.2017.10.238	journal	January 2017
Synergetic Molecular Oxygen Activation and Catalytic Oxidation of Formaldehyde over Defective MIL-88B(Fe) Nanorods at Room Temperature Zhang, Shuping; Zhuo, Yifan; Ezugwu, Chizoba I. Environmental Science & Technology, Vol. 55, Issue 12 https://doi.org/10.1021/acs.est.1c01277	journal	June 2021
Redoxable Nanosheet Crystallites of MnO ₂ Derived via Delamination of a Layered Manganese Oxide Omomo, Yoshitomo; Sasaki, Takayoshi Journal of the American Chemical Society, Vol. 125, Issue 12 https://doi.org/10.1021/ja021364p	journal	March 2003
Understanding the “seesaw effect” of interlayered K+ with different structure in manganese oxides for the enhanced formaldehyde oxidation Wang, Jinlong; Li, Jun; Zhang, Pengyi Applied Catalysis B: Environmental, Vol. 224 https://doi.org/10.1016/j.apcatb.2017.11.019	journal	May 2018
One-step synthesis of nanocarbon-decorated MnO 2 with superior activity for indoor formaldehyde removal at room temperature Liu, Fang; Rong, Shaopeng; Zhang, Pengyi Applied Catalysis B: Environmental, Vol. 235 https://doi.org/10.1016/j.apcatb.2018.04.078	journal	November 2018
Manganese dioxide-filled hierarchical porous nanofiber membrane for indoor air cleaning at room temperature Hu, Min; Yin, Linghui; Zhou, Huixian Journal of Membrane Science, Vol. 605 https://doi.org/10.1016/j.memsci.2020.118094	journal	June 2020
Ultrathin MnO2 nanosheets for optimized hydrogen evolution via formaldehyde reforming in water at room temperature Miao, Lei; Nie, Qing; Wang, Jinlong Applied Catalysis B: Environmental, Vol. 248 https://doi.org/10.1016/j.apcatb.2019.02.047	journal	July 2019
Probing reaction pathways for H2O-mediated HCHO photooxidation at room temperature Shao, Weiwei; Li, Xiaodong; Zu, Xiaolong Nano Research, Vol. 14, Issue 5 https://doi.org/10.1007/s12274-020-3205-y	journal	November 2020
Investigation into the Catalytic Roles of Various Oxygen Species over Different Crystal Phases of MnO₂ for C₆H₆ and HCHO Oxidation Chen, Bingbing; Wu, Bo; Yu, Limei ACS Catalysis, Vol. 10, Issue 11 https://doi.org/10.1021/acscatal.0c00459	journal	May 2020
Synthesizing MnO₂nanosheets from graphene oxide templates for high performance pseudosupercapacitors Zhao, Guixia; Li, Jiaxing; Jiang, Lang Chem. Sci., Vol. 3, Issue 2 https://doi.org/10.1039/C1SC00722J	journal	January 2012
Room-temperature formaldehyde catalytic decomposition Ye, Jiawei; Yu, Yan; Fan, Jiajie Environmental Science: Nano, Vol. 7, Issue 12 https://doi.org/10.1039/D0EN00831A	journal	January 2020
Potassium-modulated δ-MnO2 as robust catalysts for formaldehyde oxidation at room temperature Ji, Jian; Lu, Xiaolong; Chen, Cheng Applied Catalysis B: Environmental, Vol. 260 https://doi.org/10.1016/j.apcatb.2019.118210	journal	January 2020
Formaldehyde in the Ambient Atmosphere: From an Indoor Pollutant to an Outdoor Pollutant? Salthammer, Tunga Angewandte Chemie International Edition, Vol. 52, Issue 12 https://doi.org/10.1002/anie.201205984	journal	January 2013
Review on manganese dioxide for catalytic oxidation of airborne formaldehyde Miao, Lei; Wang, Jinlong; Zhang, Pengyi Applied Surface Science, Vol. 466 https://doi.org/10.1016/j.apsusc.2018.10.031	journal	February 2019
Photoinduced Simultaneous Thermal and Photocatalytic Activities of MnO₂ Revealed by Femtosecond Transient Absorption Spectroscopy Zhang, Huiyu; Rong, Shaopeng; Zhang, Pengyi ACS Applied Materials & Interfaces, Vol. 13, Issue 16 https://doi.org/10.1021/acsami.1c05009	journal	April 2021
MnO ₂ ‐Based Materials for Environmental Applications Yang, Ruijie; Fan, Yingying; Ye, Ruquan Advanced Materials, Vol. 33, Issue 9 https://doi.org/10.1002/adma.202004862	journal	January 2021
Recent Progress of Thermocatalytic and Photo/Thermocatalytic Oxidation for VOCs Purification over Manganese-based Oxide Catalysts Wu, Peng; Jin, Xiaojing; Qiu, Yongcai Environmental Science & Technology, Vol. 55, Issue 8 https://doi.org/10.1021/acs.est.0c08179	journal	March 2021
Vertically aligned nanostructured FeOOH@MnO2 core shell electrode with better areal capacitance Pujari, Rahul B.; Patil, Swati J.; Park, Jongsung Journal of Power Sources, Vol. 436 https://doi.org/10.1016/j.jpowsour.2019.226826	journal	October 2019
La1-x(Sr, Na, K)xMnO3 perovskites for HCHO oxidation: The role of oxygen species on the catalytic mechanism Xu, Yin; Dhainaut, Jérémy; Dacquin, Jean-Philippe Applied Catalysis B: Environmental, Vol. 287 https://doi.org/10.1016/j.apcatb.2021.119955	journal	June 2021
Layered birnessite-type MnO 2 with surface pits for enhanced catalytic formaldehyde oxidation activity Wang, Jinlong; Zhang, Gaoke; Zhang, Pengyi Journal of Materials Chemistry A, Vol. 5, Issue 12 https://doi.org/10.1039/C6TA09793F	journal	January 2017
Oxygen vacancy–engineered δ-MnO /activated carbon for room-temperature catalytic oxidation of formaldehyde Huang, Yu; Liu, Yan; Wang, Wei Applied Catalysis B: Environmental, Vol. 278 https://doi.org/10.1016/j.apcatb.2020.119294	journal	December 2020
An Advanced Dual‐Function MnO ₂ ‐Fabric Air Filter Combining Catalytic Oxidation of Formaldehyde and High‐Efficiency Fine Particulate Matter Removal Dai, Zijian; Zhu, Jie; Yan, Jiaqi Advanced Functional Materials, Vol. 30, Issue 42 https://doi.org/10.1002/adfm.202001488	journal	August 2020
Review on noble metal-based catalysts for formaldehyde oxidation at room temperature Guo, Jiahong; Lin, Chuxia; Jiang, Chuanjia Applied Surface Science, Vol. 475 https://doi.org/10.1016/j.apsusc.2018.12.238	journal	May 2019
Scalable synthesis of water-dispersible 2D manganese dioxide monosheets Rong, Shaopeng; Zhang, Pengyi; Liu, Fang Journal of Physics: Condensed Matter, Vol. 32, Issue 1 https://doi.org/10.1088/1361-648X/ab401d	journal	October 2019
Exposure to airborne formaldehyde: Sampling and analytical methods—A review Dugheri, Stefano; Massi, Daniela; Mucci, Nicola Trends in Environmental Analytical Chemistry, Vol. 29 https://doi.org/10.1016/j.teac.2021.e00116	journal	March 2021
Occupational exposure to volatile organic compounds and health risks in Colorado nail salons Lamplugh, Aaron; Harries, Megan; Xiang, Feng Environmental Pollution, Vol. 249 https://doi.org/10.1016/j.envpol.2019.03.086	journal	June 2019
Atomically-thin two-dimensional sheets for understanding active sites in catalysis Sun, Yongfu; Gao, Shan; Lei, Fengcai Chemical Society Reviews, Vol. 44, Issue 3 https://doi.org/10.1039/C4CS00236A	journal	January 2015
Active site-directed tandem catalysis on CuO/VO-MnO2 for efficient and stable catalytic ozonation of S-VOCs under mild condition Yang, Jingling; Huang, Yajing; Chen, Yun-Wen Nano Today, Vol. 35 https://doi.org/10.1016/j.nantod.2020.100944	journal	December 2020
Formaldehyde Oxidation over Co@N-Doped Carbon at Room Temperature: Tunable Co Size and Intensified Surface Electron Density Zhu, Dandan; Huang, Yu; Li, Rong ACS ES&T Engineering, Vol. 1, Issue 5 https://doi.org/10.1021/acsestengg.1c00080	journal	April 2021
Improved Oxygen Activation over a Carbon/Co₃O₄ Nanocomposite for Efficient Catalytic Oxidation of Formaldehyde at Room Temperature Li, Rong; Huang, Yu; Zhu, Dandan Environmental Science & Technology, Vol. 55, Issue 6 https://doi.org/10.1021/acs.est.1c00490	journal	March 2021
Unveiling the Effects of Alkali Metal Ions Intercalated in Layered MnO₂ for Formaldehyde Catalytic Oxidation Wang, Yu; Liu, Kaisi; Wu, Ji ACS Catalysis, Vol. 10, Issue 17 https://doi.org/10.1021/acscatal.0c02310	journal	August 2020
Study of structural defects in ?-MnO2 by Raman spectroscopy Julien, C.; Massot, M.; Rangan, S. Journal of Raman Spectroscopy, Vol. 33, Issue 4 https://doi.org/10.1002/jrs.838	journal	January 2002

Similar Records

Promotional catalytic oxidation of airborne Formaldehyde over mineral-supported MnO₂ at ambient temperature

Journal Article · 2019 · Applied Clay Science · OSTI ID:1598216

A highly efficient catalyst of palygorskite-supported manganese oxide for formaldehyde oxidation at ambient and low temperature: Performance, mechanism and reaction kinetics

Journal Article · 2019 · Applied Surface Science · OSTI ID:1598238

Detection and quantification of reactive oxygen species (ROS) in indoor air

Journal Article · 2015 · Talanta · OSTI ID:1432396

Related Subjects

Engineering
Environmental Sciences & Ecology

Ultrathin MnO 2 -Coated FeOOH Catalyst for Indoor Formaldehyde Oxidation at Ambient Temperature: New Insight into Surface Reactive Oxygen Species and In-Field Testing in an Air Cleaner

Citation Formats

References (42)

Similar Records

Related Subjects

Ultrathin MnO ₂ -Coated FeOOH Catalyst for Indoor Formaldehyde Oxidation at Ambient Temperature: New Insight into Surface Reactive Oxygen Species and In-Field Testing in an Air Cleaner