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Process-Level Modeling Can Simultaneously Explain Secondary Organic Aerosol Evolution in Chambers and Flow Reactors

Journal Article · · Environmental Science and Technology
 [1];  [2];  [3];  [4];  [5];  [1]
  1. Department of Mechanical Engineering, Colorado State University, Fort Collins, Colorado 80523, United States
  2. Aerodyne Research Inc., Billerica, Massachusetts 01821, United States
  3. Divison of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States
  4. Department of Civil and Environmental Engineering, University of California Davis, Davis, California 95616, United States
  5. Department of Atmospheric Science, Colorado State University, Fort Collins, Colorado 80521, United States

Not provided.

Research Organization:
Colorado State Univ., Fort Collins, CO (United States); Univ. of California, Irvine, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0017975; SC0019000
OSTI ID:
1977837
Journal Information:
Environmental Science and Technology, Vol. 56, Issue 10; ISSN 0013-936X
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (65)

Evolution of Organic Aerosols in the Atmosphere journal December 2009
Ambient PM2.5 Reduces Global and Regional Life Expectancy journal August 2018
Estimates and 25-year trends of the global burden of disease attributable to ambient air pollution: an analysis of data from the Global Burden of Diseases Study 2015 journal May 2017
Recent advances in understanding secondary organic aerosol: Implications for global climate forcing: Advances in Secondary Organic Aerosol journal June 2017
An evaluation of global organic aerosol schemes using airborne observations journal January 2020
Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010 journal January 2015
Contribution of First- versus Second-Generation Products to Secondary Organic Aerosols Formed in the Oxidation of Biogenic Hydrocarbons journal April 2006
High formation of secondary organic aerosol from the photo-oxidation of toluene journal January 2009
Growth Kinetics and Size Distribution Dynamics of Viscous Secondary Organic Aerosol journal January 2018
Introducing the concept of Potential Aerosol Mass (PAM) journal January 2007
Heterogeneous oxidation of saturated organic aerosols by hydroxyl radicals: uptake kinetics, condensed-phase products, and particle size change journal January 2007
Characterization of aerosol photooxidation flow reactors: heterogeneous oxidation, secondary organic aerosol formation and cloud condensation nuclei activity measurements journal January 2011
A new oxidation flow reactor for measuring secondary aerosol formation of rapidly changing emission sources journal January 2017
Design and characterization of a new oxidation flow reactor for laboratory and long-term ambient studies journal April 2021
The heterogeneous reaction of hydroxyl radicals with sub-micron squalane particles: a model system for understanding the oxidative aging of ambient aerosols journal January 2009
Effect of oxidant concentration, exposure time, and seed particles on secondary organic aerosol chemical composition and yield journal January 2015
Simulating secondary organic aerosol in a regional air quality model using the statistical oxidation model – Part 3: Assessing the influence of semi-volatile and intermediate-volatility organic compounds and NO x journal January 2019
Modeling organic aerosol from the oxidation of α-pinene in a Potential Aerosol Mass (PAM) chamber journal January 2013
Inter-comparison of laboratory smog chamber and flow reactor systems on organic aerosol yield and composition journal January 2015
Secondary organic aerosol formation from m-xylene, toluene, and benzene journal January 2007
Secondary organic aerosol formation from photooxidation of naphthalene and alkylnaphthalenes: implications for oxidation of intermediate volatility organic compounds (IVOCs) journal January 2009
Elemental composition and oxidation of chamber organic aerosol journal January 2011
Investigation of particle and vapor wall-loss effects on controlled wood-smoke smog-chamber experiments journal January 2015
Constraining uncertainties in particle-wall deposition correction during SOA formation in chamber experiments journal January 2017
Oxygenated Aromatic Compounds are Important Precursors of Secondary Organic Aerosol in Biomass-Burning Emissions journal June 2020
Particle Size Distribution Dynamics Can Help Constrain the Phase State of Secondary Organic Aerosol journal January 2021
In situ secondary organic aerosol formation from ambient pine forest air using an oxidation flow reactor journal January 2016
Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia journal January 2018
Influence of vapor wall loss in laboratory chambers on yields of secondary organic aerosol journal April 2014
Evaporation kinetics and phase of laboratory and ambient secondary organic aerosol journal January 2011
Bounce behavior of freshly nucleated biogenic secondary organic aerosol particles journal January 2011
Experimental determination of chemical diffusion within secondary organic aerosol particles journal January 2013
Estimating the Viscosity Range of SOA Particles Based on Their Coalescence Time journal December 2013
Model for Simulating Aerosol Interactions and Chemistry (MOSAIC) journal January 2008
Equilibration timescale of atmospheric secondary organic aerosol partitioning journal December 2012
Global distribution of particle phase state in atmospheric secondary organic aerosols journal April 2017
Particle-Phase Diffusion Modulates Partitioning of Semivolatile Organic Compounds to Aged Secondary Organic Aerosol journal January 2020
Modeling kinetic partitioning of secondary organic aerosol and size distribution dynamics: representing effects of volatility, phase state, and particle-phase reaction journal January 2014
Measurement of fragmentation and functionalization pathways in the heterogeneous oxidation of oxidized organic aerosol journal January 2009
Real-time measurements of secondary organic aerosol formation and aging from ambient air in an oxidation flow reactor in the Los Angeles area journal January 2016
Constraining nucleation, condensation, and chemistry in oxidation flow reactors using size-distribution measurements and aerosol microphysical modeling journal January 2018
Measurements of Kinetics and Equilibria for the Condensed Phase Reactions of Hydroperoxides with Carbonyls to Form Peroxyhemiacetals journal February 2020
Multi-generation gas-phase oxidation, equilibrium partitioning, and the formation and evolution of secondary organic aerosol journal January 2012
Predicting global aerosol size distributions in general circulation models journal January 2002
Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol journal January 2019
Heterogeneous Nucleation Drives Particle Size Segregation in Sequential Ozone and Nitrate Radical Oxidation of Catechol journal November 2021
Modeling the formation and composition of secondary organic aerosol from diesel exhaust using parameterized and semi-explicit chemistry and thermodynamic models journal January 2018
Effective Rate Constants and Uptake Coefficients for the Reactions of Organic Molecular Markers (n-Alkanes, Hopanes, and Steranes) in Motor Oil and Diesel Primary Organic Aerosols with Hydroxyl Radicals journal October 2009
Heterogeneous oxidation of atmospheric aerosol particles by gas-phase radicals journal August 2010
A mixed-phase relative rates technique for measuring aerosol reaction kinetics journal January 2006
Photo-Oxidation of Low-Volatility Organics Found in Motor Vehicle Emissions: Production and Chemical Evolution of Organic Aerosol Mass journal March 2010
Oxidation Products of Biogenic Emissions Contribute to Nucleation of Atmospheric Particles journal May 2014
Ion-induced nucleation of pure biogenic particles journal May 2016
Quantitative constraints on autoxidation and dimer formation from direct probing of monoterpene-derived peroxy radical chemistry journal November 2018
Molecular understanding of the suppression of new-particle formation by isoprene journal January 2020
SOA and gas phase organic acid yields from the sequential photooxidation of seven monoterpenes journal August 2018
A computationally efficient model to represent the chemistry, thermodynamics, and microphysics of secondary organic aerosols (simpleSOM): model development and application to α-pinene SOA journal January 2021
Oligomers in the Early Stage of Biogenic Secondary Organic Aerosol Formation and Growth journal September 2007
Composition Domains in Monoterpene Secondary Organic Aerosol journal September 2009
Modelling non-equilibrium secondary organic aerosol formation and evaporation with the aerosol dynamics, gas- and particle-phase chemistry kinetic multilayer model ADCHAM journal January 2014
Gas and aerosol wall losses in Teflon film smog chambers journal December 1985
Rethinking the global secondary organic aerosol (SOA) budget: stronger production, faster removal, shorter lifetime journal January 2016
Gas–particle partitioning of atmospheric aerosols: interplay of physical state, non-ideal mixing and morphology journal January 2013
Aqueous Organic Chemistry in the Atmosphere: Sources and Chemical Processing of Organic Aerosols journal January 2015
Photolysis Controls Atmospheric Budgets of Biogenic Secondary Organic Aerosol journal March 2020