Exploring Multidimensional Chemical Spaces: Instrumentation and Chemical Systems for the Parallelization of Hydrogen Evolving Photocatalytic Reactions

Lopato, Eric M.; Bernhard, Stefan

doi:10.1021/acs.energyfuels.1c02168

Exploring Multidimensional Chemical Spaces: Instrumentation and Chemical Systems for the Parallelization of Hydrogen Evolving Photocatalytic Reactions

Journal Article · 17 August 2021 · Energy and Fuels

DOI:https://doi.org/10.1021/acs.energyfuels.1c02168· OSTI ID:1977820

^[1]; ^[1]

Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, United States

Not provided.

Research Organization:: Carnegie Mellon Univ., Pittsburgh, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0020392

OSTI ID:: 1977820

Journal Information:: Energy and Fuels, Vol. 35, Issue 23; ISSN 0887-0624

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (157)

Solar hydrogen No authors listed Renewable Energy https://doi.org/10.1016/0960-1481(91)90051-P		January 1991
An overview of development and challenges in hydrogen powered vehicles No authors listed International Journal of Green Energy https://doi.org/10.1080/15435075.2019.1685999		November 2019
Materials for solar fuels and chemicals No authors listed Nature Materials https://doi.org/10.1038/nmat4778		December 2016
Solar fuels: thermodynamics, candidates, tactics, and figures of merit No authors listed Dalton Transactions https://doi.org/10.1039/c0dt00454e		January 2010
Review of greenhouse gas emissions from crop production systems and fertilizer management effects No authors listed Agriculture, Ecosystems & Environment https://doi.org/10.1016/j.agee.2009.04.021		October 2009
Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells No authors listed Journal of Applied Physics https://doi.org/10.1063/1.1736034		March 1961
On the thermodynamic limit of photovoltaic energy conversion No authors listed Applied physics https://doi.org/10.1007/BF00901283		June 1981
Design Principle and Loss Engineering for Photovoltaic–Electrolysis Cell System No authors listed ACS Omega https://doi.org/10.1021/acsomega.7b00012		March 2017
Solar water splitting by photovoltaic-electrolysis with a solar-to-hydrogen efficiency over 30% No authors listed Nature Communications https://doi.org/10.1038/ncomms13237		October 2016
Renewable hydrogen production: A techno-economic comparison of photoelectrochemical cells and photovoltaic-electrolysis No authors listed International Journal of Hydrogen Energy https://doi.org/10.1016/j.ijhydene.2020.06.092		September 2020
Solar hydrogen production: a bottom-up analysis of different photovoltaic–electrolysis pathways No authors listed Sustainable Energy & Fuels https://doi.org/10.1039/C9SE00007K		January 2019
High-efficiency integrated multijunction photovoltaic/electrolysis systems for hydrogen production No authors listed International Journal of Hydrogen Energy https://doi.org/10.1016/S0360-3199(00)00039-2		February 2001
The Transformation and Storage of Solar Energy: Progress Towards Visible-Light Induced Water Splitting No authors listed CHIMIA International Journal for Chemistry https://doi.org/10.2533/chimia.2009.709		November 2009
Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting No authors listed Chem. Soc. Rev. https://doi.org/10.1039/C3CS60378D		January 2014
Earth-abundant cocatalysts for semiconductor-based photocatalytic water splitting No authors listed Chem. Soc. Rev. https://doi.org/10.1039/C3CS60425J		January 2014
Z-Scheme Water Splitting Using Two Different Semiconductor Photocatalysts No authors listed ACS Catalysis https://doi.org/10.1021/cs4002089		June 2013
Water Splitting on Semiconductor Catalysts under Visible-Light Irradiation No authors listed ChemSusChem https://doi.org/10.1002/cssc.200900018		June 2009
Particulate photocatalysts for overall water splitting No authors listed Nature Reviews Materials https://doi.org/10.1038/natrevmats.2017.50		August 2017
Photocatalytic water splitting using semiconductor particles: History and recent developments No authors listed Journal of Photochemistry and Photobiology C: Photochemistry Reviews https://doi.org/10.1016/j.jphotochemrev.2011.07.001		December 2011
p -Type CuRhO ₂ as a Self-Healing Photoelectrode for Water Reduction under Visible Light No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja408876k		January 2014
Stable Hydrogen Evolution from an AgRhO ₂ Photocathode under Visible Light No authors listed Chemistry of Materials https://doi.org/10.1021/acs.chemmater.7b04911		March 2018
Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production No authors listed https://doi.org/10.2172/1218403		December 2009
Technical and economic feasibility of centralized facilities for solar hydrogen production via photocatalysis and photoelectrochemistry No authors listed Energy & Environmental Science https://doi.org/10.1039/c3ee40831k		January 2013
Hydrogen Evolution by a Chloroplast-Ferredoxin-Hydrogenase System No authors listed Proceedings of the National Academy of Sciences https://doi.org/10.1073/pnas.70.8.2317		August 1973
Hydrogen Evolution from Water by Visible Light, a Homogeneous Three Component Test System for Redox Catalysis No authors listed Helvetica Chimica Acta https://doi.org/10.1002/hlca.19780610740		November 1978
Solvent effects on metal-to-ligand charge-transfer bands in ortho-metalated complexes of iridium(III): estimates of transition dipole moments No authors listed The Journal of Physical Chemistry https://doi.org/10.1021/j100155a025		January 1991
Efficient Yellow Electroluminescence from a Single Layer of a Cyclometalated Iridium Complex No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja0345221		March 2004
A molecular water-reduction catalyst: surface derivatization of titania colloids and suspensions with a platinum complex No authors listed The Journal of Physical Chemistry https://doi.org/10.1021/j100176a075		November 1991
A water-soluble Wilkinson's complex as homogeneous catalyst for the photochemical reduction of water No authors listed Journal of Molecular Catalysis https://doi.org/10.1016/0304-5102(87)80066-4		February 1987
Highly stable CuO incorporated TiO2 catalyst for photocatalytic hydrogen production from H2O No authors listed Photochemical & Photobiological Sciences https://doi.org/10.1039/b507816d		January 2005
Photochemical hydrogen evolution from aqueous triethanolamine solutions sensitized by binaphthol-modified titanium(IV) oxide under visible-light irradiation No authors listed Journal of Photochemistry and Photobiology A: Chemistry https://doi.org/10.1016/S1010-6030(03)00222-3		August 2003
Photocatalytic hydrogen evolution on InP suspension with inorganic sacrificial reducing agent No authors listed International Journal of Hydrogen Energy https://doi.org/10.1016/S0360-3199(00)00014-8		October 2000
Automation: Chemistry shoots for the Moon No authors listed Nature https://doi.org/10.1038/d41586-019-01246-y		April 2019
A mobile robotic chemist No authors listed Nature https://doi.org/10.1038/s41586-020-2442-2		July 2020
Discovery of an -Amino C-H Arylation Reaction Using the Strategy of Accelerated Serendipity No authors listed Science https://doi.org/10.1126/science.1213920		November 2011
Accelerated Luminophore Discovery through Combinatorial Synthesis No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja047156+		October 2004
Discovery and High-Throughput Screening of Heteroleptic Iridium Complexes for Photoinduced Hydrogen Production No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja0427101		May 2005
Parallelization of photocatalytic gas-producing reactions No authors listed Review of Scientific Instruments https://doi.org/10.1063/1.4915349		March 2015
The Evolution of Chemical High-Throughput Experimentation To Address Challenging Problems in Pharmaceutical Synthesis No authors listed Accounts of Chemical Research https://doi.org/10.1021/acs.accounts.7b00428		November 2017
Parallelized Screening of Characterized and DFT-Modeled Bimetallic Colloidal Cocatalysts for Photocatalytic Hydrogen Evolution No authors listed ACS Catalysis https://doi.org/10.1021/acscatal.9b05404		March 2020
High-Throughput Screening of Earth-Abundant Water Reduction Catalysts toward Photocatalytic Hydrogen Evolution No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.0c02790		January 2021
Photochemical generation of carbon monoxide and hydrogen by reduction of carbon dioxide and water under visible light irradiation No authors listed Proceedings of the National Academy of Sciences https://doi.org/10.1073/pnas.79.2.701		January 1982
Hydrogen Generation by Visible Light Irradiation of Aqueous Solutions of Metal Complexes. An approach to the photochemical conversion and storage of solar energy No authors listed Helvetica Chimica Acta https://doi.org/10.1002/hlca.19790620449		June 1979
Photocatalytic Hydrogen Production Using a Red-Absorbing Ir(III)–Co(III) Dyad No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.7b00684		May 2017
A Bisamide Ruthenium Polypyridyl Complex as a Robust and Efficient Photosensitizer for Hydrogen Production No authors listed ChemSusChem https://doi.org/10.1002/cssc.201701543		October 2017
Substituted 2,4-Di(pyridin-2-yl)pyrimidine-Based Ruthenium Photosensitizers for Hydrogen Photoevolution under Red Light No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.0c02955		December 2020
Ultrasmall CoP Nanoparticles as Efficient Cocatalysts for Photocatalytic Formic Acid Dehydrogenation No authors listed Joule https://doi.org/10.1016/j.joule.2018.01.007		March 2018
Visible Light-Driven Hydrogen Production from Aqueous Protons Catalyzed by Molecular Cobaloxime Catalysts No authors listed Inorganic Chemistry https://doi.org/10.1021/ic900389z		June 2009
Visible Light Induced Catalytic Water Reduction without an Electron Relay No authors listed Chemistry - A European Journal https://doi.org/10.1002/chem.200700480		October 2007
Single-Layer Electroluminescent Devices and Photoinduced Hydrogen Production from an Ionic Iridium(III) Complex No authors listed Chemistry of Materials https://doi.org/10.1021/cm051312+		October 2005
Analytical methods development for supramolecular design in solar hydrogen production No authors listed SPIE Optics + Photonics, SPIE Proceedings https://doi.org/10.1117/12.680961		August 2006
Photochemical Hydrogen Evolution from Neutral Water with a Cobalt Metallopeptide Catalyst No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.9b02067		November 2019
Passive Leak Detection Using Commercial Hydrogen Colorimetric Indicator No authors listed https://doi.org/10.2172/1326889		September 2016
Hysteresis-Free Nanoplasmonic Pd–Au Alloy Hydrogen Sensors No authors listed Nano Letters https://doi.org/10.1021/acs.nanolett.5b01053		April 2015
High-throughput measurement of the influence of pH on hydrogen production from BaTiO3/TiO2 core/shell photocatalysts No authors listed Applied Catalysis B: Environmental https://doi.org/10.1016/j.apcatb.2020.118750		July 2020
Autonomous discovery in the chemical sciences part I: Progress No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201909987		September 2019
Autonomous discovery in the chemical sciences part II: Outlook No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201909989		September 2019
Machine Learning for Accelerated Discovery of Solar Photocatalysts No authors listed ACS Catalysis https://doi.org/10.1021/acscatal.9b02531		October 2019
High-Throughput Screening and Automated Data-Driven Analysis of the Triplet Photophysical Properties of Structurally Diverse, Heteroleptic Iridium(III) Complexes No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.0c12290		January 2021
High-throughput Synthesis and Screening of Iridium(III) Photocatalysts for the Fast and Chemoselective Dehalogenation of Aryl Bromides No authors listed ACS Catalysis https://doi.org/10.1021/acscatal.0c02247		May 2020
A Perspective on Innovating the Chemistry Lab Bench No authors listed Frontiers in Robotics and AI https://doi.org/10.3389/frobt.2020.00024		February 2020
Photocatalytic Hydrogen Evolution Driven by a Heteroleptic Ruthenium(II) Bis(terpyridine) Complex No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.9b00698		June 2019
Mimicking 2,2′:6′,2′′:6′′,2′′′-quaterpyridine complexes for the light-driven hydrogen evolution reaction: synthesis, structural, thermal and physicochemical characterizations No authors listed RSC Advances https://doi.org/10.1039/C9RA04303A		January 2019
A Smorgasbord of 17 Cobalt Complexes Active for Photocatalytic Hydrogen Evolution No authors listed Chemistry - A European Journal https://doi.org/10.1002/chem.201800396		June 2018
Photo-hydrogen-evolving activity of chloro(terpyridine)platinum(ii): a single-component molecular photocatalyst No authors listed Dalton Transactions https://doi.org/10.1039/b905610f		January 2009
Copper-based water reduction catalysts for efficient light-driven hydrogen generation No authors listed Journal of Molecular Catalysis A: Chemical https://doi.org/10.1016/j.molcata.2014.09.005		December 2014
A Noble-Metal-Free System for Photocatalytic Hydrogen Production from Water No authors listed Chemistry - A European Journal https://doi.org/10.1002/chem.201302091		October 2013
Photocatalytic Hydrogen Production with Copper Photosensitizer-Titanium Dioxide Composites No authors listed ChemCatChem https://doi.org/10.1002/cctc.201300459		August 2013
Unravelling the Mechanism of Basic Aqueous Methanol Dehydrogenation Catalyzed by Ru–PNP Pincer Complexes No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.6b05692		November 2016
Death and Rebirth: Photocatalytic Hydrogen Production by a Self-Organizing Copper–Iron System No authors listed ACS Catalysis https://doi.org/10.1021/cs500387e		April 2014
Accelerated Discovery of Organic Polymer Photocatalysts for Hydrogen Evolution from Water through the Integration of Experiment and Theory No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.9b03591		May 2019
Excited-State Engineering in Heteroleptic Ionic Iridium(III) Complexes No authors listed Accounts of Chemical Research https://doi.org/10.1021/acs.accounts.0c00825		February 2021
Molecular Photosensitizers in Energy Research and Catalysis: Design Principles and Recent Developments No authors listed ACS Energy Letters https://doi.org/10.1021/acsenergylett.8b02388		January 2019
Structure−Activity Correlations Among Iridium(III) Photosensitizers in a Robust Water-Reducing System No authors listed Inorganic Chemistry https://doi.org/10.1021/ic9007763		July 2009
A Robust Visible-Light-Harvesting Cyclometalated Ir(III) Diimine Sensitizer for Homogeneous Photocatalytic Hydrogen Production No authors listed ACS Applied Energy Materials https://doi.org/10.1021/acsaem.9b02269		January 2020
Cationic Bis(cyclometalated) Ir(III) Complexes with Pyridine–Carbene Ligands. Photophysical Properties and Photocatalytic Hydrogen Production from Water No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.7b02289		January 2018
Cocatalyst-free Photocatalytic Hydrogen Evolution with Simple Heteroleptic Iridium(III) Complexes No authors listed ACS Applied Energy Materials https://doi.org/10.1021/acsaem.1c00318		March 2021
Judicious Design of Cationic, Cyclometalated Ir(III) Complexes for Photochemical Energy Conversion and Optoelectronics No authors listed Accounts of Chemical Research https://doi.org/10.1021/acs.accounts.7b00375		January 2018
Inter-Ligand Energy Transfer and Related Emission Change in the Cyclometalated Heteroleptic Iridium Complex: Facile and Efficient Color Tuning over the Whole Visible Range by the Ancillary Ligand Structure No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja052880t		September 2005
Phosphorescent iridium( iii ) complexes: toward high phosphorescence quantum efficiency through ligand control No authors listed Dalton Trans. https://doi.org/10.1039/B812281D		January 2009
Elucidating the Key Role of pH on Light-Driven Hydrogen Evolution by a Molecular Cobalt Catalyst No authors listed ACS Catalysis https://doi.org/10.1021/acscatal.6b03087		January 2017
Homogeneous Photocatalytic H ₂ Production Using a Ru ^II Bathophenanthroline Metal‐to‐Ligand Charge‐Transfer Photosensitizer No authors listed ChemPlusChem https://doi.org/10.1002/cplu.201600227		October 2016
Robust and Long-Lived Excited State Ru(II) Polyimine Photosensitizers Boost Hydrogen Production No authors listed ACS Catalysis https://doi.org/10.1021/acscatal.8b02226		August 2018
Towards a comprehensive understanding of visible-light photogeneration of hydrogen from water using cobalt( ii ) polypyridyl catalysts No authors listed Energy Environ. Sci. https://doi.org/10.1039/C3EE43982H		January 2014
Comparative Study of Ru(bpz) ₃ ² +Ru(bipy) ₃ ² +and Ru(bpz) ₂ CI ₂ as Photosensitizers of DNA Cleavage and Adduct Formation No authors listed Photochemistry and Photobiology https://doi.org/10.1111/j.1751-1097.1997.tb01906.x		April 1997
Metal-complex chromophores for solar hydrogen generation No authors listed Chemical Society Reviews https://doi.org/10.1039/C6CS00436A		January 2017
Visible light-induced transition metal-catalyzed transformations: beyond conventional photosensitizers No authors listed Chemical Society Reviews https://doi.org/10.1039/C7CS00226B		January 2017
Photoactive Complexes with Earth-Abundant Metals No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.8b08822		September 2018
Robust Cuprous Phenanthroline Sensitizer for Solar Hydrogen Photocatalysis No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja407816f		September 2013
The Connection between NHC Ligand Count and Photophysical Properties in Fe(II) Photosensitizers: An Experimental Study No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.7b02624		December 2017
Photocatalytic hydrogen evolution from neutral aqueous solution by a water-soluble cobalt( ii ) porphyrin No authors listed Sustainable Energy & Fuels https://doi.org/10.1039/C8SE00253C		January 2018
Redox and photocatalytic properties of a Ni ^II complex with a macrocyclic biquinazoline (Mabiq) ligand No authors listed Chemical Science https://doi.org/10.1039/C7SC05320G		January 2018
Ligand Controls the Activity of Light‐Driven Water Oxidation Catalyzed by Nickel(II) Porphyrin Complexes in Neutral Homogeneous Aqueous Solutions No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.202103157		May 2021
Photosensitizers for H ₂ Evolution Based on Charged or Neutral Zn and Sn Porphyrins No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.9b01838		January 2020
Zinc(II) Metalated Porphyrins as Photothermogenic Photosensitizers for Cancer Photodynamic/Photothermal Synergistic Therapy No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.7b15583		December 2017
Construction of a Noble-Metal-Free Photocatalytic H ₂ Evolution System Using MoS ₂ /Reduced Graphene Oxide Catalyst and Zinc Porphyrin Photosensitizer No authors listed The Journal of Physical Chemistry C https://doi.org/10.1021/acs.jpcc.7b08290		October 2017
Enhancing photocatalytic hydrogen evolution by intramolecular energy transfer in naphthalimide conjugated porphyrins No authors listed Chemical Communications https://doi.org/10.1039/C8CC06919K		January 2018
Organic dyes in illuminated manuscripts: a unique cultural and historic record No authors listed Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences https://doi.org/10.1098/rsta.2016.0050		December 2016
Library of UV–Vis–NIR reflectance spectra of modern organic dyes from historic pattern-card coloured papers No authors listed Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy https://doi.org/10.1016/j.saa.2011.05.033		September 2011
Photosensitizing Action of Eosin y for Visible Light Induced Hydrogen Evolution from Water No authors listed Chemistry Letters https://doi.org/10.1246/cl.1983.1021		July 1983
Photocatalytic hydrogen production by dye-sensitized Pt/SnO2 AND Pt/SnO2/RuO2 in aqueous methyl viologen solution No authors listed International Journal of Hydrogen Energy https://doi.org/10.1016/S0360-3199(96)00075-4		January 1997
Challenging the [Ru(bpy) ₃ ] ²⁺ Photosensitizer with a Triazatriangulenium Robust Organic Dye for Visible-Light-Driven Hydrogen Production in Water No authors listed ACS Catalysis https://doi.org/10.1021/acscatal.7b04000		March 2018
Fluorescein-sensitized Au/g-C3N4 nanocomposite for enhanced photocatalytic hydrogen evolution under visible light No authors listed Materials Research Bulletin https://doi.org/10.1016/j.materresbull.2018.02.056		June 2018
Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges No authors listed Energy & Environmental Science https://doi.org/10.1039/c2ee03250c		January 2012
Efficient Photocatalytic Hydrogen Evolution from Water without an Electron Mediator over Pt−Rose Bengal Catalysts No authors listed The Journal of Physical Chemistry C https://doi.org/10.1021/jp8085717		January 2009
Making Hydrogen from Water Using a Homogeneous System Without Noble Metals No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja903044n		July 2009
Reductive Side of Water Splitting in Artificial Photosynthesis: New Homogeneous Photosystems of Great Activity and Mechanistic Insight No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja1057357		November 2010
Poly(p-phenylene)-catalysed photoreduction of water to hydrogen No authors listed Journal of the Chemical Society, Chemical Communications https://doi.org/10.1039/c39850000474		January 1985
Conjugated Polymers: Catalysts for Photocatalytic Hydrogen Evolution No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201607375		November 2016
A metal-free polymeric photocatalyst for hydrogen production from water under visible light No authors listed Nature Materials https://doi.org/10.1038/nmat2317		November 2008
Photobleaching of organic fluorophores: quantitative characterization, mechanisms, protection No authors listed Methods and Applications in Fluorescence https://doi.org/10.1088/2050-6120/ab7365		February 2020
Robust Photogeneration of H2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst No authors listed Science https://doi.org/10.1126/science.1227775		November 2012
Improved H ₂ Evolution in Quaternary SCIGS Chalcopyrite Semiconductors No authors listed The Journal of Physical Chemistry C https://doi.org/10.1021/acs.jpcc.8b05389		September 2018
Heterostructured (Ba,Sr)TiO3/TiO2 core/shell photocatalysts: Influence of processing and structure on hydrogen production No authors listed International Journal of Hydrogen Energy https://doi.org/10.1016/j.ijhydene.2013.03.130		June 2013
Heterostructured Ceramic Powders for Photocatalytic Hydrogen Production: Nanostructured TiO2 Shells Surrounding Microcrystalline (Ba,Sr)TiO3 Cores No authors listed Journal of the American Ceramic Society https://doi.org/10.1111/j.1551-2916.2012.05076.x		February 2012
Palladium versus Platinum: The Metal in the Catalytic Center of a Molecular Photocatalyst Determines the Mechanism of the Hydrogen Production with Visible Light No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201409438		January 2015
Light in Gold Catalysis No authors listed Chemical Reviews https://doi.org/10.1021/acs.chemrev.0c00841		January 2021
Hydrogen-Evolution Catalysts Based on Non-Noble Metal Nickel-Molybdenum Nitride Nanosheets No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201200699		May 2012
Recent progress in homogeneous light-driven hydrogen evolution using first-row transition metal catalysts No authors listed Inorganica Chimica Acta https://doi.org/10.1016/j.ica.2020.119950		March 2021
Non-noble-metal Ni nanoparticles modified N-doped g-C3N4 for efficient photocatalytic hydrogen evolution No authors listed International Journal of Hydrogen Energy https://doi.org/10.1016/j.ijhydene.2019.09.129		November 2019
[NiFe] hydrogenases: how close do structural and functional mimics approach the active site? No authors listed Dalton Transactions https://doi.org/10.1039/c4dt00539b		January 2014
Photo-induced H2 production by [NiFe]-hydrogenase from T. roseopersicina covalently linked to a Ru(II) photosensitizer No authors listed Journal of Inorganic Biochemistry https://doi.org/10.1016/j.jinorgbio.2011.09.012		January 2012
Polypyridyl Co complex-based water reduction catalysts: why replace a pyridine group with isoquinoline rather than quinoline? No authors listed Dalton Transactions https://doi.org/10.1039/C9DT04767K		January 2021
Recent developments in hydrogen evolving molecular cobalt(II)–polypyridyl catalysts No authors listed Coordination Chemistry Reviews https://doi.org/10.1016/j.ccr.2015.03.014		December 2015
Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes No authors listed Chemical Reviews https://doi.org/10.1021/acs.chemrev.8b00392		October 2018
Unimolecular and bimolecular homolytic reactions of organochromium and organocobalt complexes. Kinetics and equilibria No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja00330a027		September 1984
Substituent Effects on Cobalt Diglyoxime Catalysts for Hydrogen Evolution No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja208091e		November 2011
Theoretical Analysis of Mechanistic Pathways for Hydrogen Evolution Catalyzed by Cobaloximes No authors listed Inorganic Chemistry https://doi.org/10.1021/ic201842v		November 2011
Hydrogen Evolution Catalyzed by Cobaloximes No authors listed Accounts of Chemical Research https://doi.org/10.1021/ar900253e		December 2009
Mechanism of H ₂ Evolution from a Photogenerated Hydridocobaloxime No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja109351h		December 2010
Toward the rational benchmarking of homogeneous H ₂ -evolving catalysts No authors listed Energy Environ. Sci. https://doi.org/10.1039/C4EE01709A		January 2014
Photocatalytic Hydrogen Production from Water by Noble-Metal-Free Molecular Catalyst Systems Containing Rose Bengal and the Cobaloximes of BF _x -Bridged Oxime Ligands No authors listed The Journal of Physical Chemistry C https://doi.org/10.1021/jp106512a		August 2010
Cobalt(II)–Salen Complexes for Photocatalytic Hydrogen Production in Noble Metal-Free Molecular Systems No authors listed Catalysis Letters https://doi.org/10.1007/s10562-018-2509-y		August 2018
Cobalt-catalyzed evolution of molecular hydrogen No authors listed Inorganic Chemistry https://doi.org/10.1021/ic00236a006		July 1986
Cobaloxime-Based Photocatalytic Devices for Hydrogen Production No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.200702953		January 2008
Photocatalytic H2 generation based on noble-metal-free binuclear cobalt complexes using visible-light No authors listed Physical Chemistry Chemical Physics https://doi.org/10.1039/c3cp51550h		January 2013
A Homogeneous System for the Photogeneration of Hydrogen from Water Based on a Platinum(II) Terpyridyl Acetylide Chromophore and a Molecular Cobalt Catalyst No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja804650g		September 2008
Proton Electroreduction Catalyzed by Cobaloximes: Functional Models for Hydrogenases No authors listed Inorganic Chemistry https://doi.org/10.1021/ic050167z		June 2005
Photochemical hydrogen production and cobaloximes: the influence of the cobalt axial N-ligand on the system stability No authors listed Dalton Transactions https://doi.org/10.1039/C5DT04502A		January 2016
Development and understanding of cobaloxime activity through electrochemical molecular catalyst screening No authors listed Phys. Chem. Chem. Phys. https://doi.org/10.1039/C4CP00453A		January 2014
Catalytic proton reduction with transition metal complexes of the redox-active ligand bpy2PYMe No authors listed Chemical Science https://doi.org/10.1039/c3sc51660a		January 2013
Photo- and Electrocatalytic H ₂ Production by New First-Row Transition-Metal Complexes Based on an Aminopyridine Pentadentate Ligand No authors listed Chemistry - A European Journal https://doi.org/10.1002/chem.201303317		April 2014
Ni-based photocatalytic H2-production cocatalysts2 No authors listed Chinese Journal of Catalysis https://doi.org/10.1016/S1872-2067(19)63294-8		March 2019
Photocatalytic Hydrogen Generation System Using a Nickel-Thiolate Hexameric Cluster No authors listed Inorganic Chemistry https://doi.org/10.1021/ic4013069		July 2013
First-row transition metal polypyridine complexes that catalyze proton to hydrogen reduction No authors listed Coordination Chemistry Reviews https://doi.org/10.1016/j.ccr.2019.213079		January 2020
Efficient electro/photocatalytic water reduction using a [Ni ^II (N ₂ Py ₃ )] ²⁺ complex No authors listed Chemical Communications https://doi.org/10.1039/C6CC06629A		January 2016
Mechanistic Insights into Homogeneous Electrocatalytic and Photocatalytic Hydrogen Evolution Catalyzed by High-Spin Ni(II) Complexes with S ₂ N ₂ -Type Tetradentate Ligands No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.8b00881		May 2018
Iron Polypyridyl Complexes for Photocatalytic Hydrogen Generation No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.6b01413		August 2016
Gold nanoparticle-catalysed photosensitized water reduction for hydrogen generation No authors listed Journal of Materials Chemistry A https://doi.org/10.1039/C4TA06853J		January 2015
Modular Homogeneous Chromophore–Catalyst Assemblies No authors listed Accounts of Chemical Research https://doi.org/10.1021/acs.accounts.5b00539		April 2016
Molecular Chromophore–Catalyst Assemblies for Solar Fuel Applications No authors listed Chemical Reviews https://doi.org/10.1021/acs.chemrev.5b00229		August 2015
Impact of Ligand Exchange in Hydrogen Production from Cobaloxime-Containing Photocatalytic Systems No authors listed Inorganic Chemistry https://doi.org/10.1021/ic2010166		November 2011
Photochemical hydrogen production catalyzed by polypyridyl ruthenium–cobaloxime heterobinuclear complexes with different bridges No authors listed Journal of Organometallic Chemistry https://doi.org/10.1016/j.jorganchem.2009.04.041		August 2009
Efficient H2-producing photocatalytic systems based on cyclometalated iridium- and tricarbonylrhenium-diimine photosensitizers and cobaloxime catalysts No authors listed Dalton Transactions https://doi.org/10.1039/b812605b		January 2008
Supramolecular Cobaloxime Assemblies for H ₂ Photocatalysis: An Initial Solution State Structure−Function Analysis ^† No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/jp1023636		November 2010
Light-Driven Hydrogen Evolution by BODIPY-Sensitized Cobaloxime Catalysts No authors listed Inorganic Chemistry https://doi.org/10.1021/ic500218q		April 2014
Orchestrated Photocatalytic Water Reduction Using Surface-Adsorbing Iridium Photosensitizers No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja201514e		August 2011

Similar Records

Parallelized Screening of Characterized and DFT-Modeled Bimetallic Colloidal Cocatalysts for Photocatalytic Hydrogen Evolution

Journal Article · 2020 · ACS Catalysis · OSTI ID:1803972

Lopato, Eric M.; Eikey, Emily A.; Simon, Zoe C.; +9 more

Parallelized Screening of Characterized and DFT-Modeled Bimetallic Colloidal Cocatalysts for Photocatalytic Hydrogen Evolution

Journal Article · 2020 · ACS Catalysis · OSTI ID:1832912

Lopato, Eric M.; Eikey, Emily A.; Simon, Zoe C.; +9 more

Related Subjects

Energy & Fuels
Engineering

Exploring Multidimensional Chemical Spaces: Instrumentation and Chemical Systems for the Parallelization of Hydrogen Evolving Photocatalytic Reactions

Citation Formats

References (157)

Similar Records

Related Subjects