Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Molecular Chirality and Its Monitoring by Ultrafast X-ray Pulses

Journal Article · · Chemical Reviews
 [1];  [2]
  1. Université de Lyon, UJM-Saint-Etienne, CNRS, IOGS, Laboratoire Hubert Curien UMR 5516, Saint-Etienne F-42023, France; OSTI
  2. Department of Chemistry and Physics & Astronomy, University of California, Irvine, California 92697-2025, United States
Not provided.
Research Organization:
Univ. of California, Irvine, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-04ER15571; SC0019484;
OSTI ID:
1977817
Journal Information:
Chemical Reviews, Journal Name: Chemical Reviews Journal Issue: 22 Vol. 122; ISSN 0009-2665
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (234)

Raman optical activity instrument for studies of biopolymer structure and dynamics journal September 1999
New Insight into the Source of Biomolecular Homochirality: An Extraterrestrial Origin for Molecules of Life? journal February 1999
Photoelectron Circular Dichroism in Chiral Molecules book January 2008
Molecular Quantum Electrodynamics book January 2009
Comprehensive Chiroptical Spectroscopy book December 2011
X-Ray Photoelectron Spectroscopy book January 2011
Photons and Atoms: Introduction to Quantum Electrodynamics book March 1997
A New Twist for Materials Science: The Formation of Chiral Structures Using the Angular Momentum of Light journal June 2019
How Important is Parity Violation for Molecular and Biomolecular Chirality? journal December 2002
Circular Dichroism in the Photoelectron Angular Distributions of Camphor and Fenchone from Multiphoton Ionization with Femtosecond Laser Pulses journal February 2012
BioCARS—a novel nonlinear optical technique to study vibrational spectra of chiral biological molecules in solution journal January 1995
Induced circular dichroism by chiral molecular interaction journal January 2003
Nonlinear optical spectroscopy of chiral molecules journal January 2005
The use of X-ray crystallography to determine absolute configuration journal January 2008
On circular dichroism and the separation between chromophore and chiral center: The near carbon K-edge X-ray absorption and circular dichroism spectra of noradrenaline and L-DOPA journal January 2009
Stereospecific determination, chiral inversion in vitro and pharmacokinetics in humans of the enantiomers of thalidomide journal January 1995
Conformational Sensitivity in Photoelectron Circular Dichroism of 3-Methylcyclopentanone journal April 2013
Enantiomeric Excess Sensitivity to Below One Percent by Using Femtosecond Photoelectron Circular Dichroism journal February 2016
New implementation of high-level correlated methods using a general block tensor library for high-performance electronic structure calculations journal July 2013
Simulating X‐ray absorption spectra with complete active space self‐consistent field linear response methods journal November 2020
Homochirality and life journal January 2004
Restricted active space configuration interaction methods for strong correlation: Recent developments journal July 2021
Nonlinear Spectroscopy of Core and Valence Excitations Using Short X-Ray Pulses: Simulation Challenges book January 2014
Principles of Single Atom Physics: High-Order Harmonic Generation, Above-Threshold Ionization and Non-Sequential Ionization book January 2008
Free-Electron Lasers in the Ultraviolet and X-Ray Regime book January 2014
On the degree of circular polarization of synchrotron radiation journal July 1971
The role of chirality in the origin of life journal August 1991
Calculation of X-ray natural circular dichroism journal July 1998
Chirality and Life journal September 2007
Random phase approximation calculations of K-edge rotational strengths of chiral molecules: propylene oxide journal July 1994
IV The Orbital Angular Momentum of Light book May 1999
Exploring the microscopic origin of magnetic anisotropies with X-ray magnetic circular dichroism (XMCD) spectroscopy journal October 1999
Ultrafast Nonlinear Optical Signals Viewed from the Molecule’s Perspective book January 2010
Theoretical study of the X-ray natural circular dichroism of some crystalline amino acids journal April 2015
Observation of sub-100ps conformational changes in photolyzed carbonmonoxy-myoglobin probed by time-resolved circular dichroism journal November 2005
Spin-state studies with XES and RIXS: From static to ultrafast journal June 2013
X-ray beam-shaping via deformable mirrors: Analytical computation of the required mirror profile
  • Spiga, Daniele; Raimondi, Lorenzo; Svetina, Cristian
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 710 https://doi.org/10.1016/j.nima.2012.10.117
journal May 2013
On optical vortex interactions with chiral matter journal July 2004
Retrieval of complex angle-dependent transition dipoles by using macroscopic high harmonics generated from aligned N2 molecules journal April 2022
Molecular Light Scattering and Optical Activity book August 2009
On the physical origin of the homochirality of life journal August 2005
Sensitive circular dichroism spectroscopy based on nonlinear degenerate four-wave mixing journal November 1993
Photoinduced Structural Dynamics of Molecular Systems Mapped by Time-Resolved X-ray Methods journal May 2017
Simulating X-ray Spectroscopies and Calculating Core-Excited States of Molecules journal April 2018
Molecular Structure and Modeling of Water–Air and Ice–Air Interfaces Monitored by Sum-Frequency Generation journal March 2020
Chiral Four-Wave Mixing Signals with Circularly Polarized X-ray Pulses journal July 2020
Probing Molecular Chirality of Ground and Electronically Excited States in the UV–vis and X-ray Regimes: An EOM-CCSD Study journal February 2022
Ab Initio Computation of Rotationally-Averaged Pump–Probe X-ray and Electron Diffraction Signals journal January 2019
New and Efficient Equation-of-Motion Coupled-Cluster Framework for Core-Excited and Core-Ionized States journal April 2019
Probing Molecular Chirality by Orbital-Angular-Momentum-Carrying X-ray Pulses journal May 2019
Photoelectron Wave Function in Photoionization: Plane Wave or Coulomb Wave? journal October 2015
Giant Helical Dichroism of Single Chiral Nanostructures with Photonic Orbital Angular Momentum journal January 2021
Chirality: Physical Chemistry journal December 2001
Density Matrix Analysis and Simulation of Electronic Excitations in Conjugated and Aggregated Molecules journal September 2002
Coherent Multidimensional Optical Spectroscopy of Excitons in Molecular Aggregates; Quasiparticle versus Supermolecule Perspectives journal June 2009
Linear-Response and Real-Time Time-Dependent Density Functional Theory Studies of Core-Level Near-Edge X-Ray Absorption journal August 2012
Ab initio vibrational Raman and Raman optical activity spectra journal October 1990
Core Electron Transitions as a Probe for Molecular Chirality:  Natural Circular Dichroism at the Carbon K-edge of Methyloxirane journal April 2004
Circular Dichroism at the Edge:  Large X-ray Natural CD in the 1s → 3d Pre-Edge Feature of 2[Co(en) 3 Cl 3 ]·NaCl·6H 2 O journal November 1999
Natural Circular Dichroism in X-ray Spectroscopy journal December 2000
Gauge-Origin Independent Density-Functional Theory Calculations of Vibrational Raman Optical Activity journal July 2002
The Current State of Ab Initio Calculations of Optical Rotation and Electronic Circular Dichroism Spectra journal December 2007
Chiroptical Study of α-Aliphatic Amino Acid Films in the Vacuum Ultraviolet Region journal October 2010
Giant Chiral Asymmetry in the C 1 s Core Level Photoemission from Randomly Oriented Fenchone Enantiomers journal April 2008
A Broadband, Background-Free Quarter-Wave Plate Based on Plasmonic Metasurfaces journal February 2012
Giant Chiral Optical Response from a Twisted-Arc Metamaterial journal January 2014
X-ray focusing with efficient high-NA multilayer Laue lenses journal November 2017
Four-wave mixing experiments with extreme ultraviolet transient gratings journal April 2015
Transfer of optical orbital angular momentum to a bound electron journal October 2016
Single bunch X-ray pulses on demand from a multi-bunch synchrotron radiation source journal May 2014
Seeing a single molecule vibrate through time-resolved coherent anti-Stokes Raman scattering journal July 2014
Generation of bright phase-matched circularly-polarized extreme ultraviolet high harmonics journal December 2014
A table-top ultrashort light source in the extreme ultraviolet for circular dichroism experiments journal December 2014
Probing molecular chirality on a sub-femtosecond timescale journal June 2015
A twist in coherent X-rays journal April 2017
Optical vortices 30 years on: OAM manipulation from topological charge to multiple singularities journal October 2019
53-attosecond X-ray pulses reach the carbon K-edge journal August 2017
Attosecond science based on high harmonic generation from gases and solids journal June 2020
Laguerre–Gauss and Hermite–Gauss soft X-ray states generated using diffractive optics journal January 2019
Synthetic chiral light for efficient control of chiral light–matter interaction journal October 2019
Tunable isolated attosecond X-ray pulses with gigawatt peak power from a free-electron laser journal December 2019
Photoelectric effect with a twist journal August 2020
Hard X-ray transient grating spectroscopy on bismuth germanate journal April 2021
Hard X-ray helical dichroism of disordered molecular media journal July 2022
Photoexcitation circular dichroism in chiral molecules journal February 2018
Site-specific interrogation of an ionic chiral fragment during photolysis using an X-ray free-electron laser journal August 2021
Orbital angular momentum dichroism in nanoantennas journal December 2018
Single Shot Polarization Characterization of XUV FEL Pulses from Crossed Polarized Undulators journal August 2015
Nearly diffraction-limited X-ray focusing with variable-numerical-aperture focusing optical system based on four deformable mirrors journal April 2016
Detecting chirality in molecules by imaging photoelectron circular dichroism journal January 2014
Probing ultrafast dynamics of chiral molecules using time-resolved photoelectron circular dichroism journal January 2016
Non-local real-space analysis of chiral optical signals journal January 2016
Organic photodiodes from homochiral l -proline derived squaraine compounds with strong circular dichroism journal January 2017
X-ray circular dichroism signals: a unique probe of local molecular chirality journal January 2017
Enantiomeric resolution and X-ray optical activity of a tricobalt extended metal atom chain journal January 2018
Exciton coupling in diketopyrrolopyrrole–helicene derivatives leads to red and near-infrared circularly polarized luminescence journal January 2018
X-ray Raman optical activity of chiral molecules journal January 2019
How to stay out of trouble in RIXS calculations within equation-of-motion coupled-cluster damped response theory? Safe hitchhiking in the excitation manifold by means of core–valence separation journal January 2020
Coupled nuclear–electronic decay dynamics of O2 inner valence excited states revealed by attosecond XUV wave-mixing spectroscopy journal January 2021
Pharmacologically active compounds in the environment and their chirality journal January 2010
An essential property of synchrotron radiation: linear and circular polarization for X-ray absorption spectroscopy journal June 1992
Recherches sur l'absorption et la dispersion de la lumière par les milieux doués du pouvoir rotatoire journal January 1896
Chiroptical properties from time-dependent density functional theory. I. Circular dichroism spectra of organic molecules journal April 2002
Chiroptical properties from time-dependent density functional theory. II. Optical rotations of small to medium sized organic molecules journal July 2002
Circular dichroism in the photoelectron angular distribution from randomly oriented enantiomers of camphor journal November 2003
Photoelectron circular dichroism in core level ionization of randomly oriented pure enantiomers of the chiral molecule camphor journal March 2004
Existence of a New Conservation Law in Electromagnetic Theory journal May 1964
Calculation of K-edge circular dichroism of amino acids: Comparison of random phase approximation with other methods journal June 2007
Near-edge x-ray absorption and natural circular dichroism spectra of L-alanine: A theoretical study based on the complex polarization propagator approach journal October 2007
Dyson orbitals for ionization from the ground and electronically excited states within equation-of-motion coupled-cluster formalism: Theory, implementation, and examples journal December 2007
Cross sections and photoelectron angular distributions in photodetachment from negative ions using equation-of-motion coupled-cluster Dyson orbitals journal September 2009
Interfering pathways in benzene: An analytical treatment journal January 2009
Circular dichroism in photoelectron angular distributions as a probe of atomic and molecular alignment journal July 1986
Two-dimensional stimulated resonance Raman spectroscopy of molecules with broadband x-ray pulses journal May 2012
Characteristic oxygen K-edge circular dichroism spectra of amino acid films by improved measurement technique journal February 2013
Imaging photoelectron circular dichroism of chiral molecules by femtosecond multiphoton coincidence detection journal December 2013
DEIMOS: A beamline dedicated to dichroism measurements in the 350–2500 eV energy range journal January 2014
Time-, frequency-, and wavevector-resolved x-ray diffraction from single molecules journal May 2014
Circular dichroism measurements at an x-ray free-electron laser with polarization control journal August 2016
Photoinduced molecular chirality probed by ultrafast resonant X-ray spectroscopy journal July 2017
Perspective: Quantum Hamiltonians for optical interactions journal January 2018
Nano-structuring of multi-layer material by single x-ray vortex pulse with femtosecond duration journal March 2018
General theory of photoexcitation induced photoelectron circular dichroism journal August 2018
Ultrafast photoelectron spectroscopy of aqueous solutions journal September 2019
Perfect control of photoelectron anisotropy for randomly oriented ensembles of molecules by XUV REMPI and polarization shaping journal August 2019
Time resolved transient circular dichroism spectroscopy using synchrotron natural polarization journal September 2019
Magnetic circular dichroism spectra from resonant and damped coupled cluster response theory journal September 2020
Cherry-picking resolvents: A general strategy for convergent coupled-cluster damped response calculations of core-level spectra journal October 2020
Optical multidimensional coherent spectroscopy journal July 2013
The description of the physical properties of condensed matter using irreducible tensors journal July 1978
Raman optical activity comes of age journal April 2004
A unified description of sum frequency generation, parametric down conversion and two-photon fluorescence journal February 2009
Parity violation energies of C4H4X2molecules for X = O, S, Se, Te and Po† journal September 2013
Non-linear optical spectroscopy as a novel probe for molecular chirality journal April 2005
Absorption of twisted light by a mesoscopic atomic target journal May 2016
Opportunities for chiral discrimination using high harmonic generation in tailored laser fields journal October 2015
Circularly polarized molecular high harmonic generation using a bicircular laser journal May 2016
Helicity-selective phase-matching and quasi-phase matching of circularly polarized high-order harmonics: towards chiral attosecond pulses journal May 2016
Circularly polarized harmonic generation by intense bicircular laser pulses: electron recollision dynamics and frequency dependent helicity journal November 2016
Optical chiral metamaterials: a review of the fundamentals, fabrication methods and applications journal September 2016
Translational and rotational averaging of nonlocal response tensors for nano-shaped light journal January 2018
Angular emission distribution of O 1s photoelectrons of uniaxially oriented methanol journal August 2020
A plane wave theory of photoionization using the dipole acceleration form: predictions concerning circular dichroism in photoelectron angular distributions at high energies journal October 2020
Conformational effects in photoelectron circular dichroism journal November 2017
Ultrafast photoelectron spectroscopy of solutions: space-charge effect journal September 2015
Free electron laser generation of x-ray Poincaré beams journal July 2020
Photon echo using imperfect x-ray pulse with phase fluctuation journal August 2019
Optical vortices evolving from helicoidal integer and fractional phase steps journal January 2004
Optical vortices near sub-wavelength structures journal May 2004
A new soft X-ray magnetic circular dichroism facility at the BSRF beamline 4B7B journal April 2015
Ultrafast Structural Changes in Chiral Molecules Measured with Free-Electron Lasers journal January 2020
Measurement and comparison of absolute value of soft X-ray natural circular dichroism of serine and alanine journal November 2009
NitrogenK-edge soft X-ray natural circular dichroism of histidine thin film journal April 2014
Chiral Toxicology: It's the Same Thing…Only Different journal May 2009
X-ray Raman scattering: a building block for nonlinear spectroscopy journal April 2019
Imaging charge migration in chiral molecules using time-resolved x-ray diffraction journal November 2021
Theory of high-harmonic generation by low-frequency laser fields journal March 1994
Characterizing optical chirality journal February 2011
Nonadiabatic tunneling in circularly polarized laser fields: Physical picture and calculations journal December 2011
Dependence of high-order-harmonic-generation yield on driving-laser ellipticity journal July 2012
Noncollinear wave mixing of attosecond XUV and few-cycle optical laser pulses in gas-phase atoms: Toward multidimensional spectroscopy involving XUV excitations journal November 2016
Emitter-site-selective photoelectron circular dichroism of trifluoromethyloxirane journal May 2017
Circular dichroism in high-order harmonic generation from chiral molecules journal August 2018
Generalized perspective on chiral measurements without magnetic interactions journal December 2018
Conditions for perfect circular polarization of high-order harmonics driven by bichromatic counter-rotating laser fields journal February 2019
Dynamical symmetry and valley-selective circularly polarized high-harmonic generation in monolayer molybdenum disulfide journal January 2022
Circular dichroism in photoelectron angular distributions from adsorbed atoms journal December 1985
Soft-x-ray magnetic circular dichroism at the L 2 , 3 edges of nickel journal October 1990
Nonlinear circular dichroism in a liquid of chiral molecules: A theoretical investigation journal September 1999
X-ray natural circular dichroism journal September 2000
Multiple core-hole coherence in x-ray four-wave-mixing spectroscopies journal December 2005
Proposal for Generating Brilliant X-Ray Beams Carrying Orbital Angular Momentum journal March 2008
Optical Chirality and Its Interaction with Matter journal April 2010
First Observation of Photons Carrying Orbital Angular Momentum in Undulator Radiation journal July 2013
Stimulated Electronic X-Ray Raman Scattering journal December 2013
Free-Electron Laser Design for Four-Wave Mixing Experiments with Soft-X-Ray Pulses journal July 2014
Optical Chirality in Nonlinear Optics: Application to High Harmonic Generation journal March 2018
First Evidence of Purely Extreme-Ultraviolet Four-Wave Mixing journal June 2018
Quantum Control of Photoelectron Circular Dichroism journal January 2019
Recovery of High-Energy Photoelectron Circular Dichroism through Fano Interference journal July 2019
Electronic Population Transfer via Impulsive Stimulated X-Ray Raman Scattering with Attosecond Soft-X-Ray Pulses journal August 2020
Fourfold Differential Photoelectron Circular Dichroism journal September 2021
Second harmonic generation in an optically active liquid: Experimental observation of a fourth-order optical nonlinearity due to molecular chirality journal February 1993
Solving the Phase Problem Using Reference-Beam X-Ray Diffraction journal April 1998
X-Ray Natural Circular Dichroism journal May 1998
Three-Wave Mixing in Chiral Liquids journal November 2000
Experimental Evidence of Third-Order Nonlinear Dichroism in a Liquid of Chiral Molecules journal November 2000
Sum-Frequency Generation in Chiral Liquids near Electronic Resonance journal August 2001
Coherent X-Ray Raman Spectroscopy: A Nonlinear Local Probe for Electronic Excitations journal July 2002
Focusing X-Ray Beams to Nanometer Dimensions journal November 2003
Probing Enantioselectivity with X-Ray Photoelectron Spectroscopy and Density Functional Theory journal March 2007
Obtaining high degree of circular polarization at x-ray free electron lasers via a reverse undulator taper journal November 2013
Control of the Polarization of a Vacuum-Ultraviolet, High-Gain, Free-Electron Laser journal December 2014
Extreme-Ultraviolet Vortices from a Free-Electron Laser journal August 2017
Ultrasensitive Chiral Spectroscopy by Dynamical Symmetry Breaking in High Harmonic Generation journal July 2019
Circular dichroism beamline B23 at the Diamond Light Source journal November 2011
DESIRS: a state-of-the-art VUV beamline featuring high resolution and variable polarization for spectroscopy and dichroism at SOLEIL journal May 2012
New soft X-ray beamline BL07LSU at SPring-8 journal February 2014
Planning, performing and analyzing X-ray Raman scattering experiments journal February 2015
An endstation for resonant inelastic X-ray scattering studies of solid and liquid samples journal January 2017
The SwissFEL soft X-ray free-electron laser beamline: Athos journal June 2019
Polarization control with an X-ray phase retarder for high-time-resolution pump–probe experiments at SACLA journal June 2019
XUV polarimeter for undulator radiation measurements conference November 1991
Resolving enantiomers using the optical angular momentum of twisted light journal March 2016
Seeing real-space dynamics of liquid water through inelastic x-ray scattering journal December 2017
Multidimensional spectroscopy with attosecond extreme ultraviolet and shaped near-infrared pulses journal September 2018
Enhanced Enantioselectivity in Excitation of Chiral Molecules by Superchiral Light journal April 2011
Circular Polarization in Star- Formation Regions: Implications for Biomolecular Homochirality journal July 1998
Multidimensional Attosecond Resonant X-Ray Spectroscopy of Molecules: Lessons from the Optical Regime journal April 2013
Ultrafast Solvation Dynamics Explored by Femtosecond Photon echo Spectroscopies journal October 1998
The Effects of Chiral Isolates of Methadone on the Cardiac Potassium Channel IKr journal November 2008
Novel non-linear optical techniques for studying chiral molecules of biological importance book July 2021
Orbital angular momentum: origins, behavior and applications journal January 2011
X-ray vortex beams: A theoretical analysis journal September 2003
Focusing properties of Fresnel zone plates with spiral phase journal May 2010
Direct laser printing of chiral plasmonic nanojets by vortex beams journal January 2017
High harmonic generation from axial chiral molecules journal September 2017
High resolution beam profiling of X-ray free electron laser radiation by polymer imprint development journal January 2017
High-order harmonic source spanning up to the oxygen K-edge based on filamentation pulse compression journal April 2018
Circularly polarized extreme ultraviolet high harmonic generation in graphene journal January 2019
Topological charge of asymmetric optical vortices journal June 2020
Strong chiral response in non-collinear high harmonic generation driven by purely electric-dipole interactions journal January 2022
Detecting multiple chiral centers in chiral molecules with high harmonic generation journal January 2022
Diffraction of a plane, finite-radius wave by a spiral phase plate journal June 2006
Soft-x-ray microscopy using spiral zone plates journal January 2007
Characterization of x-ray phase vortices by ptychographic coherent diffractive imaging journal January 2014
Optical orbital angular momentum: twisted light and chirality journal January 2018
Refractive hard x-ray vortex phase plates journal January 2019
Ultrafast broadband circular dichroism in the deep ultraviolet journal January 2019
Core-level Time Resolved Spectroscopy of Photoelectron Circular Dichroism in Fenchone conference January 2020
Transient grating spectroscopy: An ultrarapid, nondestructive materials evaluation technique journal May 2019
Orbital Angular Momentum (OAM) Multiplexing: An Enabler of a New Era of Wireless Communications journal January 2017
Polarization Characterization of Soft X-Ray Radiation at FERMI FEL-2 journal April 2017
The Chiral Puzzle of Life journal May 2020

Similar Records

Probing Molecular Chirality by Orbital-Angular-Momentum-Carrying X-ray Pulses
Journal Article · 2019 · Journal of Chemical Theory and Computation · OSTI ID:1609511

Photoinduced molecular chirality probed by ultrafast resonant X-ray spectroscopy
Journal Article · 2017 · Structural Dynamics · OSTI ID:1374552

Ultrafast X-Ray Probes of Elementary Molecular Events
Journal Article · 2023 · Annual Review of Physical Chemistry · OSTI ID:2419011

Related Subjects