Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Chemical Challenges that the Peroxide Dianion Presents to Rechargeable Lithium–Air Batteries

Journal Article · · Chemistry of Materials
 [1];  [1];  [2];  [3];  [1]
  1. Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States
  2. Centro de Investigaciones Químicas, IICBA, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, Col. Chamilpa, Cuernavaca, Morelos 62209, Mexico
  3. Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States
+ Show Author Affiliations

Not provided.

Research Organization:
Harvard Univ., Cambridge, MA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0021639
OSTI ID:
1977800
Journal Information:
Chemistry of Materials, Vol. 34, Issue 9; ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (78)

A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery journal January 1996
Rechargeable Li 2 O 2 Electrode for Lithium Batteries journal February 2006
A Critical Review of Li∕Air Batteries journal January 2012
Current Challenges and Routes Forward for Nonaqueous Lithium–Air Batteries journal February 2020
Advances in understanding mechanisms underpinning lithium–air batteries journal September 2016
The Importance of Nanometric Passivating Films on Cathodes for Li–Air Batteries journal November 2014
Nature of Li 2 O 2 Oxidation in a Li–O 2 Battery Revealed by Operando X-ray Diffraction journal November 2014
Why Do Lithium-Oxygen Batteries Fail: Parasitic Chemical Reactions and Their Synergistic Effect journal July 2016
Materials challenges in rechargeable lithium-air batteries journal May 2014
Mechanism and performance of lithium–oxygen batteries – a perspective journal January 2017
Variable character of O--O and M--O bonding in side-on ( 2) 1:1 metal complexes of O2 journal March 2003
Kinetics and mechanism of the oxidation of 2-mercaptoethanol by hydrogen peroxide in aqueous solution journal November 1985
LiOH Formation from Lithium Peroxide Clusters and the Role of Iodide Additive journal April 2020
Thermodynamics of the Higher Oxides. II. Lattice Energies of the Alkali and Alkaline Earth Peroxides and the Double Electron Affinity of the Oxygen Molecule1 journal August 1965
Structural Basis for Activation of Class Ib Ribonucleotide Reductase journal August 2010
Identification of a Discrete Peroxide Dianion, O22−, in a Two Sodium–(1,6-Anhydro-β-maltose)2–Peroxide Complex journal February 2010
New Polyamide Cryptand for Anion Binding journal July 2003
Reversible Reduction of Oxygen to Peroxide Facilitated by Molecular Recognition journal January 2012
On the incompatibility of lithium–O 2 battery technology with CO 2 journal January 2017
Electrical conductivity in Li 2 O 2 and its role in determining capacity limitations in non-aqueous Li-O 2 batteries journal December 2011
Dual-Phase Molecular-like Charge Transport in Nanoporous Transition Metal Oxides journal December 2018
A Study of the Influence of Lithium Salt Anions on Oxygen Reduction Reactions in Li-Air Batteries journal January 2015
Electron and Ion Transport In Li 2 O 2 journal May 2013
Lithium−Air Battery: Promise and Challenges journal June 2010
Controlling Solution-Mediated Reaction Mechanisms of Oxygen Reduction Using Potential and Solvent for Aprotic Lithium–Oxygen Batteries journal March 2016
Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li–O 2 battery capacity journal July 2015
Catalytic Behavior of Lithium Nitrate in Li-O 2 Cells journal July 2015
The Influence of Water and Protons on Li 2 O 2 Crystal Growth in Aprotic Li-O 2 Cells journal January 2015
Solvating additives drive solution-mediated electrochemistry and enhance toroid growth in non-aqueous Li–O2 batteries journal December 2014
Superoxide reactions with (isonicotinamide)pentaammineruthenium(II) and -(III) journal December 1980
How super is superoxide? journal December 1981
Effects of media and electrode materials on the electrochemical reduction of dioxygen journal September 1982
The potential diagram for oxygen at pH 7 journal July 1988
Experimental and Computational Analysis of the Solvent-Dependent O 2 /Li + -O 2 − Redox Couple: Standard Potentials, Coupling Strength, and Implications for Lithium-Oxygen Batteries journal January 2016
Electroreduction of oxygen in aprotic media journal July 1995
Diffusion of Molecules in Ionic Liquids/Organic Solvent Mixtures. Example of the Reversible Reduction of O2 to Superoxide journal January 2009
Thermodynamic Data for the Association of Phenol with a Series of Amides journal July 1962
An NMR Investigation of the Effect of Hydrogen Bonding on the Rates of Rotation about the C−N Bonds in Urea and Thiourea journal January 1996
Ultrafast Photoinduced Electron Transfer from Peroxide Dianion journal December 2014
Synthetic oxygen carriers related to biological systems journal April 1979
Electron transfers in chemistry and biology journal August 1985
Charge Transport Properties of Lithium Superoxide in Li–O 2 Batteries journal November 2020
Theoretical Evidence for Low Charging Overpotentials of Superoxide Discharge Products in Metal–Oxygen Batteries journal December 2015
First-Principles Study of the Charge Transport Mechanisms in Lithium Superoxide journal February 2017
Charge Transport in Alkali-Metal Superoxides: A Systematic First-Principles Study journal October 2019
Electrolytes for Rechargeable Lithium–Air Batteries journal February 2020
Interactions of Dimethoxy Ethane with Li 2 O 2 Clusters and Likely Decomposition Mechanisms for Li–O 2 Batteries journal April 2013
Li–O 2 Battery Degradation by Lithium Peroxide (Li 2 O 2 ): A Model Study journal December 2012
The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries journal July 2014
Solvent Degradation in Nonaqueous Li-O 2 Batteries: Oxidative Stability versus H-Abstraction journal June 2014
Critical CO2 Concentration for Practical Lithium–Air Batteries journal May 2021
State of the Climate in 2019 journal August 2020
Implications of CO 2 Contamination in Rechargeable Nonaqueous Li–O 2 Batteries journal December 2012
Promise and reality of post-lithium-ion batteries with high energy densities journal March 2016
Twin Problems of Interfacial Carbonate Formation in Nonaqueous Li–O 2 Batteries journal March 2012
The Carbon Electrode in Nonaqueous Li–O2 Cells
  • Ottakam Thotiyl, Muhammed M.; Freunberger, Stefan A.; Peng, Zhangquan
  • Journal of the American Chemical Society, Vol. 135, Issue 1, p. 494-500 https://doi.org/10.1021/ja310258x
journal December 2012
Singlet Oxygen Formation during the Charging Process of an Aprotic Lithium-Oxygen Battery journal April 2016
Singlet oxygen generation as a major cause for parasitic reactions during cycling of aprotic lithium–oxygen batteries journal March 2017
Mechanism for Singlet Oxygen Production in Li-Ion and Metal–Air Batteries journal May 2020
Singlet Oxygen in Electrochemical Cells: A Critical Review of Literature and Theory journal July 2021
Electrochemical Oxidation of Lithium Carbonate Generates Singlet Oxygen journal April 2018
Rechargeability of Li–air cathodes pre-filled with discharge products using an ether-based electrolyte solution: implications for cycle-life of Li–air cells journal January 2013
Deciphering the Enigma of Li2CO3 Oxidation Using a Solid-State Li–Air Battery Configuration journal March 2021
Chemical vs Electrochemical Formation of Li 2 CO 3 as a Discharge Product in Li–O 2 /CO 2 Batteries by Controlling the Superoxide Intermediate journal December 2016
A reversible lithium–CO 2 battery with Ru nanoparticles as a cathode catalyst journal January 2017
Li-CO2 Electrochemistry: A New Strategy for CO2 Fixation and Energy Storage journal October 2017
Anion-Receptor Mediated Oxidation of Carbon Monoxide to Carbonate by Peroxide Dianion journal November 2015
Cesium carbonate: A powerful inorganic base in organic synthesis journal February 1999
Mechanism of Sulfide Oxidations by Peroxymonocarbonate journal May 2001
Mechanism of Formation of Peroxocarbonates RhOOC(O)O(Cl)(P)3 and Their Reactivity as Oxygen Transfer Agents Mimicking Monooxygenases. The First Evidence of CO2 Insertion into the O−O Bond of Rh(η2-O2) Complexes journal January 1996
Carbonate radical anion — Thermochemistry journal December 2006
Nitrogen dioxide and carbonate radical anion: two emerging radicals in biology journal May 2002
Theoretical and Experimental Studies of the Spin Trapping of Inorganic Radicals by 5,5-Dimethyl-1-Pyrroline N -Oxide (DMPO). 2. Carbonate Radical Anion journal December 2006
Electron transfer reaction rates and equilibria of the carbonate and sulfate radical anions
  • Huie, Robert E.; Clifton, Carol L.; Neta, Pedatsur
  • International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry, Vol. 38, Issue 5 https://doi.org/10.1016/1359-0197(91)90065-A
journal January 1991
Li 2 CO 3 -free Li–O 2 /CO 2 battery with peroxide discharge product journal January 2018
Toward a Lithium–“Air” Battery: The Effect of CO 2 on the Chemistry of a Lithium–Oxygen Cell journal June 2013
Nucleophilic oxygenation of carbon dioxide by superoxide ion in aprotic media to form the peroxydicarbonate(2-) ion species journal August 1984
Peroxynitrite Mediates Active Site Tyrosine Nitration in Manganese Superoxide Dismutase. Evidence of a Role for the Carbonate Radical Anion journal November 2010

Similar Records

Related Subjects

Chemistry
Materials Science