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Atypical Spectroscopic Behavior in Divalent Lanthanide Dibenzyldiaza-18-crown-6 Complexes (Ln = Sm, Eu, Yb)

Journal Article · · Crystal Growth and Design
 [1];  [1];  [1]
  1. Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, Florida 32306, United States
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Not provided.

Research Organization:
Florida State Univ., Tallahassee, FL (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0010677
OSTI ID:
1977778
Journal Information:
Crystal Growth and Design, Vol. 22, Issue 4; ISSN 1528-7483
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (38)

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Complex formation of the lanthanides and actinides in lower oxidation states journal June 1991
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Divalent Thulium Crown Ether Complexes with Field-Induced Slow Magnetic Relaxation journal February 2019
Ytterbium(II) amides and crown ethers: addition versus amide substitution journal March 2002
Nonclassical Organolanthanoid Metal Chemistry:  [K([18]-crown-6)(η 2 -PhMe) 2 ]X (X = [(LnCp t 3 ) 2 (μ-H)], [(LnCp‘ ‘ 2 ) 2 (μ-η 6 :η 6 -PhMe)]) from [LnCp x 3 ], K, and [18]-crown-6 in Toluene (Ln = La, Ce; Cp t = η 5 -C 5 H 4 SiMe 2 Bu t ; Cp‘ ‘ = η 5 -C 5 H 3 (SiMe 3 ) 2 -1,3) journal July 2000
Synthesis and reactivity of rare-earth metal phosphaethynolates journal January 2018
Influence of Outer-Sphere Anions on the Photoluminescence from Samarium(II) Crown Complexes journal September 2021
Structural and Spectroscopic Analysis of Ln(II) 18-crown-6 and Benzo-18-crown-6 Complexes (Ln = Sm, Eu, Yb) journal December 2021
Calix (aza-)crowns as potential ionophores for divalent and trivalent cations journal January 1991
Structure and conformation of (dibenzyldiaza-18-crown-6)-Nd(III) and Eu(III) thiocyanates: infrared spectroscopic and X-ray crystallographic studies journal January 1999
A structural study of (dibenzyldiaza-18-crown-6) lanthanum(III) thiocyanate journal August 1997
SHELXT – Integrated space-group and crystal-structure determination journal January 2015
OLEX2 : a complete structure solution, refinement and analysis program journal January 2009
Crystal Structure and Magnetic Properties of Gd 2 ([18]crown-6) 2 (OH) 2 (CH 3 CN) 2 [Ni(dmit) 2 ] 4 Complex Having f- and π-Spins journal March 2003
The first structurally characterized cationic lanthanide–alkyl complexesElectronic supplementary information (ESI) available: experimental and spectroscopic details. See http://www.rsc.org/suppdata/cc/b2/b201613n/ journal April 2002
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Effect of Lanthanide Contraction on Crystal Structures of Three-Dimensional Lanthanide Based Metal–Organic Frameworks with Thiophene-2,5-Dicarboxylate and Oxalate journal June 2011
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Spectroscopy of f–f radiative transitions of Y b 3 + ions in ytterbium doped orthophosphates at ambient and high hydrostatic pressures journal May 2010
On the color of the trivalent lanthanide ions journal March 1995

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Related Subjects

Chemistry
Crystallography
Materials Science