Extreme Ultraviolet Reflection–Absorption Spectroscopy: Probing Dynamics at Surfaces from a Molecular Perspective

Biswas, Somnath; Baker, L. Robert

doi:10.1021/acs.accounts.1c00765

Extreme Ultraviolet Reflection–Absorption Spectroscopy: Probing Dynamics at Surfaces from a Molecular Perspective

Journal Article · 03 March 2022 · Accounts of Chemical Research

DOI:https://doi.org/10.1021/acs.accounts.1c00765· OSTI ID:1977757

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Department of Chemistry, Princeton University, Washington Road, Princeton, New Jersey 08544, United States
Department of Chemistry and Biochemistry, The Ohio State University, Columbus, Ohio 43210, United States

Not provided.

Research Organization:: The Ohio State Univ., Columbus, OH (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0014051

OSTI ID:: 1977757

Journal Information:: Accounts of Chemical Research, Vol. 55, Issue 6; ISSN 0001-4842

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (68)

Highly Localized Charge Transfer Excitons in Metal Oxide Semiconductors Biswas, Somnath; Husek, Jakub; Londo, Stephen Nano Letters, Vol. 18, Issue 2 https://doi.org/10.1021/acs.nanolett.7b04818	journal	January 2018
Controlling polaron formation at hematite surfaces by molecular functionalization probed by XUV reflection-absorption spectroscopy Biswas, Somnath; Wallentine, Spencer; Bandaranayake, Savini The Journal of Chemical Physics, Vol. 151, Issue 10 https://doi.org/10.1063/1.5115163	journal	September 2019
Hole Thermalization Dynamics Facilitate Ultrafast Spatial Charge Separation in CuFeO ₂ Solar Photocathodes Husek, Jakub; Cirri, Anthony; Biswas, Somnath The Journal of Physical Chemistry C, Vol. 122, Issue 21 https://doi.org/10.1021/acs.jpcc.8b02996	journal	May 2018
Ultrafast Spin Crossover in a Room-Temperature Ferrimagnet: Element-Specific Spin Dynamics in Photoexcited Cobalt Ferrite Londo, Stephen; Biswas, Somnath; Husek, Jakub The Journal of Physical Chemistry C, Vol. 124, Issue 21 https://doi.org/10.1021/acs.jpcc.0c03736	journal	May 2020
Understanding Catalyst Surfaces during Catalysis through Near Ambient Pressure X-ray Photoelectron Spectroscopy Nguyen, Luan; Tao, Franklin Feng; Tang, Yu Chemical Reviews, Vol. 119, Issue 12 https://doi.org/10.1021/acs.chemrev.8b00114	journal	April 2019
Impact of surface chemistry Somorjai, G. A.; Li, Y. Proceedings of the National Academy of Sciences, Vol. 108, Issue 3, p. 917-924 https://doi.org/10.1073/pnas.1006669107	journal	September 2010
Measuring the Surface Photovoltage of a Schottky Barrier under Intense Light Conditions: Zn/p-Si(100) by Laser Time-Resolved Extreme Ultraviolet Photoelectron Spectroscopy Marsh, Brett M.; Vaida, Mihai E.; Cushing, Scott K. The Journal of Physical Chemistry C, Vol. 121, Issue 40 https://doi.org/10.1021/acs.jpcc.7b06406	journal	September 2017
Time-dependent electron phenomena at surfaces Muino, R. D.; Sanchez-Portal, D.; Silkin, V. M. Proceedings of the National Academy of Sciences, Vol. 108, Issue 3 https://doi.org/10.1073/pnas.1008517107	journal	November 2010
A surface science approach to ultrafast electron transfer and solvation dynamics at interfaces Stähler, Julia; Bovensiepen, Uwe; Meyer, Michael Chemical Society Reviews, Vol. 37, Issue 10 https://doi.org/10.1039/b800257f	journal	January 2008
Molecular Modes of Attosecond Charge Migration Folorunso, Aderonke S.; Bruner, Adam; Mauger, François Physical Review Letters, Vol. 126, Issue 13 https://doi.org/10.1103/PhysRevLett.126.133002	journal	March 2021
Charge migration induced by attosecond pulses in bio-relevant molecules Calegari, Francesca; Trabattoni, Andrea; Palacios, Alicia Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 49, Issue 14 https://doi.org/10.1088/0953-4075/49/14/142001	journal	June 2016
Femtosecond x-ray spectroscopy of an electrocyclic ring-opening reaction Attar, Andrew R.; Bhattacherjee, Aditi; Pemmaraju, C. D. Science, Vol. 356, Issue 6333 https://doi.org/10.1126/science.aaj2198	journal	April 2017
Direct mapping of curve-crossing dynamics in IBr by attosecond transient absorption spectroscopy Kobayashi, Yuki; Chang, Kristina F.; Zeng, Tao Science, Vol. 365, Issue 6448 https://doi.org/10.1126/science.aax0076	journal	July 2019
Tracking the Metal-Centered Triplet in Photoinduced Spin Crossover of Fe(phen) ₃ ²⁺ with Tabletop Femtosecond M-Edge X-ray Absorption Near-Edge Structure Spectroscopy Zhang, Kaili; Ash, Ryan; Girolami, Gregory S. Journal of the American Chemical Society, Vol. 141, Issue 43 https://doi.org/10.1021/jacs.9b07332	journal	October 2019
Attosecond science based on high harmonic generation from gases and solids Li, Jie; Lu, Jian; Chew, Andrew Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-16480-6	journal	June 2020
Multiplet effects in X-ray spectroscopy Groot, Frank de Coordination Chemistry Reviews, Vol. 249, Issue 1-2 https://doi.org/10.1016/j.ccr.2004.03.018	journal	January 2005
Femtosecond M _2,3 -Edge Spectroscopy of Transition-Metal Oxides: Photoinduced Oxidation State Change in α-Fe ₂ O ₃ Vura-Weis, Josh; Jiang, Chang-Ming; Liu, Chong The Journal of Physical Chemistry Letters, Vol. 4, Issue 21 https://doi.org/10.1021/jz401997d	journal	October 2013
Layer-resolved ultrafast extreme ultraviolet measurement of hole transport in a Ni-TiO ₂ -Si photoanode Cushing, Scott K.; Porter, Ilana J.; de Roulet, Bethany R. Science Advances, Vol. 6, Issue 14 https://doi.org/10.1126/sciadv.aay6650	journal	April 2020
High-Resolution X-ray Emission and X-ray Absorption Spectroscopy de Groot, Frank Chemical Reviews, Vol. 101, Issue 6 https://doi.org/10.1021/cr9900681	journal	June 2001
Ultrafast X-ray Absorption Spectroscopy Bressler, Christian; Chergui, Majed Chemical Reviews, Vol. 104, Issue 4 https://doi.org/10.1021/cr0206667	journal	April 2004
Shrinking the Synchrotron: Tabletop Extreme Ultraviolet Absorption of Transition-Metal Complexes Zhang, Kaili; Lin, Ming-Fu; Ryland, Elizabeth S. The Journal of Physical Chemistry Letters, Vol. 7, Issue 17 https://doi.org/10.1021/acs.jpclett.6b01393	journal	August 2016
Carrier-Specific Femtosecond XUV Transient Absorption of PbI ₂ Reveals Ultrafast Nonradiative Recombination Lin, Ming-Fu; Verkamp, Max A.; Leveillee, Joshua The Journal of Physical Chemistry C, Vol. 121, Issue 50 https://doi.org/10.1021/acs.jpcc.7b11147	journal	December 2017
Electronic and nuclear contributions to time-resolved optical and X-ray absorption spectra of hematite and insights into photoelectrochemical performance Hayes, Dugan; Hadt, Ryan G.; Emery, Jonathan D. Energy & Environmental Science, Vol. 9, Issue 12 https://doi.org/10.1039/C6EE02266A	journal	January 2016
Achieving Surface Sensitivity in Ultrafast XUV Spectroscopy: M _2,3 -Edge Reflection–Absorption of Transition Metal Oxides Cirri, Anthony; Husek, Jakub; Biswas, Somnath The Journal of Physical Chemistry C, Vol. 121, Issue 29 https://doi.org/10.1021/acs.jpcc.7b05127	journal	July 2017
Elucidating ultrafast electron dynamics at surfaces using extreme ultraviolet (XUV) reflection–absorption spectroscopy Biswas, Somnath; Husek, Jakub; Baker, L. Robert Chemical Communications, Vol. 54, Issue 34 https://doi.org/10.1039/C8CC01745J	journal	January 2018
Surface electron dynamics in hematite (α-Fe ₂ O ₃ ): correlation between ultrafast surface electron trapping and small polaron formation Husek, Jakub; Cirri, Anthony; Biswas, Somnath Chemical Science, Vol. 8, Issue 12 https://doi.org/10.1039/C7SC02826A	journal	January 2017
Ultrafast Optical Spin Switching in Ferrimagnetic Nickel Ferrite (NiFe ₂ O ₄ ) Studied by XUV Reflection–Absorption Spectroscopy Londo, Stephen; Biswas, Somnath; Pinchuk, Igor V. The Journal of Physical Chemistry C, Vol. 126, Issue 5 https://doi.org/10.1021/acs.jpcc.1c09763	journal	February 2022
Small Polarons and Surface Defects in Metal Oxide Photocatalysts Studied Using XUV Reflection–Absorption Spectroscopy Bandaranayake, Savini; Hruska, Emily; Londo, Stephen The Journal of Physical Chemistry C, Vol. 124, Issue 42 https://doi.org/10.1021/acs.jpcc.0c07047	journal	September 2020
Apparatus for soft x-ray table-top high harmonic generation Johnson, Allan S.; Wood, David; Austin, Dane R. Review of Scientific Instruments, Vol. 89, Issue 8 https://doi.org/10.1063/1.5041498	journal	August 2018
Oxygen vacancies: The origin of n -type conductivity in ZnO Liu, Lishu; Mei, Zengxia; Tang, Aihua Physical Review B, Vol. 93, Issue 23 https://doi.org/10.1103/PhysRevB.93.235305	journal	June 2016
Surface Segregation Entropy of Protons and Oxygen Vacancies in BaZrO ₃ Bjørheim, Tor S.; Arrigoni, Marco; Saeed, Sarmad W. Chemistry of Materials, Vol. 28, Issue 5 https://doi.org/10.1021/acs.chemmater.5b04327	journal	February 2016
Surface Segregation and Backscattering in Doped Silicon Nanowires Fernández-Serra, M. V.; Adessi, Ch.; Blase, X. Physical Review Letters, Vol. 96, Issue 16 https://doi.org/10.1103/PhysRevLett.96.166805	journal	April 2006
Electron trapping and impurity segregation without defects: Ab initio study of perfectly rebonded grain boundaries Arias, T. A.; Joannopoulos, J. D. Physical Review B, Vol. 49, Issue 7 https://doi.org/10.1103/PhysRevB.49.4525	journal	February 1994
Holstein Polarons Near Surfaces Goodvin, Glen L.; Covaci, Lucian; Berciu, Mona Physical Review Letters, Vol. 103, Issue 17 https://doi.org/10.1103/PhysRevLett.103.176402	journal	October 2009
Bulk and Surface Polarons in Photoexcited Anatase TiO ₂ Di Valentin, Cristiana; Selloni, Annabella The Journal of Physical Chemistry Letters, Vol. 2, Issue 17 https://doi.org/10.1021/jz2009874	journal	August 2011
Surface polaron formation in the Holstein model Nourafkan, Reza; Capone, Massimo; Nafari, Nasser Physical Review B, Vol. 80, Issue 15 https://doi.org/10.1103/PhysRevB.80.155130	journal	October 2009
X-Ray Interactions: Photoabsorption, Scattering, Transmission, and Reflection at E = 50-30,000 eV, Z = 1-92 Henke, B. L.; Gullikson, E. M.; Davis, J. C. Atomic Data and Nuclear Data Tables, Vol. 54, Issue 2, p. 181-342 https://doi.org/10.1006/adnd.1993.1013	journal	July 1993
Polaron-formation revealed by transient XUV imaginary refractive index changes in different iron compounds Chen, Wenfan; Xiong, Wei Physical Chemistry Chemical Physics, Vol. 23, Issue 8 https://doi.org/10.1039/D1CP00103E	journal	January 2021
Characterization of Photo-Induced Charge Transfer and Hot Carrier Relaxation Pathways in Spinel Cobalt Oxide (Co ₃ O ₄ ) Jiang, Chang-Ming; Baker, L. Robert; Lucas, J. Matthew The Journal of Physical Chemistry C, Vol. 118, Issue 39 https://doi.org/10.1021/jp5071133	journal	September 2014
Excitation-wavelength-dependent small polaron trapping of photoexcited carriers in α-Fe2O3 Carneiro, Lucas M.; Cushing, Scott K.; Liu, Chong Nature Materials, Vol. 16, Issue 8 https://doi.org/10.1038/nmat4936	journal	July 2017
In situ observation of picosecond polaron self-localisation in α-Fe2O3 photoelectrochemical cells Pastor, Ernest; Park, Ji-Sang; Steier, Ludmilla Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11767-9	journal	September 2019
Photoexcited Small Polaron Formation in Goethite (α-FeOOH) Nanorods Probed by Transient Extreme Ultraviolet Spectroscopy Porter, Ilana J.; Cushing, Scott K.; Carneiro, Lucas M. The Journal of Physical Chemistry Letters, Vol. 9, Issue 14 https://doi.org/10.1021/acs.jpclett.8b01525	journal	June 2018
Computer simulation of electron transfer at hematite surfaces Kerisit, Sebastien; Rosso, Kevin M. Geochimica et Cosmochimica Acta, Vol. 70, Issue 8 https://doi.org/10.1016/j.gca.2005.12.021	journal	April 2006
Charge transport in metal oxides: A theoretical study of hematite α-Fe2O3 Iordanova, N.; Dupuis, M.; Rosso, K. M. The Journal of Chemical Physics, Vol. 122, Issue 14 https://doi.org/10.1063/1.1869492	journal	April 2005
Electron transport via polaron hopping in bulk Ti O 2 : A density functional theory characterization Deskins, N. Aaron; Dupuis, Michel Physical Review B, Vol. 75, Issue 19 https://doi.org/10.1103/PhysRevB.75.195212	journal	May 2007
Direct and simultaneous observation of ultrafast electron and hole dynamics in germanium Zürch, Michael; Chang, Hung-Tzu; Borja, Lauren J. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15734	journal	June 2017
Intrinsically distinct hole and electron transport in conjugated polymers controlled by intra and intermolecular interactions Pace, Giuseppina; Bargigia, Ilaria; Noh, Yong-Young Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13155-9	journal	November 2019
Quantifying Photoinduced Polaronic Distortions in Inorganic Lead Halide Perovskite Nanocrystals Cannelli, Oliviero; Colonna, Nicola; Puppin, Michele Journal of the American Chemical Society, Vol. 143, Issue 24 https://doi.org/10.1021/jacs.1c02403	journal	June 2021
Localized holes and delocalized electrons in photoexcited inorganic perovskites: Watching each atomic actor by picosecond X-ray absorption spectroscopy Santomauro, Fabio G.; Grilj, Jakob; Mewes, Lars Structural Dynamics, Vol. 4, Issue 4 https://doi.org/10.1063/1.4971999	journal	July 2017
Revealing hole trapping in zinc oxide nanoparticles by time-resolved X-ray spectroscopy Penfold, Thomas J.; Szlachetko, Jakub; Santomauro, Fabio G. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-02870-4	journal	February 2018
Oxygen 1 s x-ray-absorption edges of transition-metal oxides de Groot, F. M. F.; Grioni, M.; Fuggle, J. C. Physical Review B, Vol. 40, Issue 8 https://doi.org/10.1103/PhysRevB.40.5715	journal	September 1989
Hot phonon and carrier relaxation in Si(100) determined by transient extreme ultraviolet spectroscopy Cushing, Scott K.; Zürch, Michael; Kraus, Peter M. Structural Dynamics, Vol. 5, Issue 5 https://doi.org/10.1063/1.5038015	journal	September 2018
Femtosecond tracking of carrier relaxation in germanium with extreme ultraviolet transient reflectivity Kaplan, Christopher J.; Kraus, Peter M.; Ross, Andrew D. Physical Review B, Vol. 97, Issue 20 https://doi.org/10.1103/PhysRevB.97.205202	journal	May 2018
Ultrafast carrier thermalization and trapping in silicon-germanium alloy probed by extreme ultraviolet transient absorption spectroscopy Zürch, Michael; Chang, Hung-Tzu; Kraus, Peter M. Structural Dynamics, Vol. 4, Issue 4 https://doi.org/10.1063/1.4985056	journal	July 2017
Simultaneous Observation of Carrier-Specific Redistribution and Coherent Lattice Dynamics in 2H-MoTe ₂ with Femtosecond Core-Level Spectroscopy Attar, Andrew R.; Chang, Hung-Tzu; Britz, Alexander ACS Nano, Vol. 14, Issue 11 https://doi.org/10.1021/acsnano.0c06988	journal	October 2020
Photoelectrochemical CO ₂ Reduction to Acetate on Iron–Copper Oxide Catalysts Yang, Xin; Fugate, Elizabeth A.; Mueanngern, Yutichai ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b02984	journal	December 2016
The role of phase impurities and lattice defects on the electron dynamics and photochemistry of CuFeO2 solar photocathodes Fugate, Elizabeth A.; Biswas, Somnath; Clement, Mathew C. Nano Research, Vol. 12, Issue 9 https://doi.org/10.1007/s12274-019-2493-6	journal	August 2019
Electronic Structure and Performance Bottlenecks of CuFeO ₂ Photocathodes Jiang, Chang-Ming; Reyes-Lillo, Sebastian E.; Liang, Yufeng Chemistry of Materials, Vol. 31, Issue 7 https://doi.org/10.1021/acs.chemmater.9b00009	journal	March 2019
Bright Coherent Ultrahigh Harmonics in the keV X-ray Regime from Mid-Infrared Femtosecond Lasers Popmintchev, T.; Chen, M. -C.; Popmintchev, D. Science, Vol. 336, Issue 6086 https://doi.org/10.1126/science.1218497	journal	June 2012
Spatiotemporal isolation of attosecond soft X-ray pulses in the water window Silva, Francisco; Teichmann, Stephan M.; Cousin, Seth L. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7611	journal	March 2015
In Situ / Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy Timoshenko, Janis; Roldan Cuenya, Beatriz Chemical Reviews, Vol. 121, Issue 2 https://doi.org/10.1021/acs.chemrev.0c00396	journal	September 2020
Time-resolved x-ray absorption spectroscopy with a water window high-harmonic source Pertot, Yoann; Schmidt, Cédric; Matthews, Mary Science, Vol. 355, Issue 6322 https://doi.org/10.1126/science.aah6114	journal	January 2017
Soft X-ray Absorption Spectroscopy of Aqueous Solutions Using a Table-Top Femtosecond Soft X-ray Source Kleine, Carlo; Ekimova, Maria; Goldsztejn, Gildas The Journal of Physical Chemistry Letters, Vol. 10, Issue 1 https://doi.org/10.1021/acs.jpclett.8b03420	journal	December 2018
Femtosecond Soft-X-ray Absorption Spectroscopy of Liquids with a Water-Window High-Harmonic Source Smith, Adam D.; Balčiu̅nas, Tadas; Chang, Yi-Ping The Journal of Physical Chemistry Letters, Vol. 11, Issue 6 https://doi.org/10.1021/acs.jpclett.9b03559	journal	February 2020
Multidimensional spectroscopy with attosecond extreme ultraviolet and shaped near-infrared pulses Marroux, Hugo J. B.; Fidler, Ashley P.; Neumark, Daniel M. Science Advances, Vol. 4, Issue 9 https://doi.org/10.1126/sciadv.aau3783	journal	September 2018
Near-resonant four-wave mixing of attosecond extreme-ultraviolet pulses with near-infrared pulses in neon: Detection of electronic coherences Cao, Wei; Warrick, Erika R.; Fidler, Ashley Physical Review A, Vol. 94, Issue 2 https://doi.org/10.1103/PhysRevA.94.021802	journal	August 2016
Phase cycling of extreme ultraviolet pulse sequences generated in rare gases Wituschek, Andreas; Kornilov, Oleg; Witting, Tobias New Journal of Physics, Vol. 22, Issue 9 https://doi.org/10.1088/1367-2630/abb43a	journal	September 2020
Ultrafast X-Ray Spectroscopy of Conical Intersections Neville, Simon P.; Chergui, Majed; Stolow, Albert Physical Review Letters, Vol. 120, Issue 24 https://doi.org/10.1103/PhysRevLett.120.243001	journal	June 2018

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