High Performing Inverted Flexible Perovskite Solar Cells via Solution Phase Deposition of Yttrium-Doped SnO2 Directly on Perovskite

Chapagain, Sashil; Martin, Blake; Armstrong, Peter; Perkins, Craig L.; Reese, Matthew O.; Druffel, Thad; Grapperhaus, Craig A.

doi:10.1021/acsaem.2c03720

High Performing Inverted Flexible Perovskite Solar Cells via Solution Phase Deposition of Yttrium-Doped SnO2 Directly on Perovskite

Journal Article · 25 April 2023 · ACS Applied Energy Materials

DOI:https://doi.org/10.1021/acsaem.2c03720· OSTI ID:1974738

Chapagain, Sashil; Martin, Blake; Armstrong, Peter; Perkins, Craig L.; Reese, Matthew O.; Druffel, Thad; Grapperhaus, Craig A.

Solution processing of flexible perovskite solar cells (f-PSCs) provides an avenue for scalable, high-throughput printing of lightweight, scalable, and cost-effective flexible solar cells. However, the deposition of fully solution-processed metal oxide charge transport layers on perovskites has been limited by solvent incompatibilities and high processing temperatures for metal oxide nanoparticles. In this study, we present high-performance, inverted f-PSCs from the direct deposition of yttrium-doped SnO2 nanoparticles functionalized with acetate on top of perovskite as an ink in anhydrous ethanol via blade coating. Yttrium doping improved device performance by improving the charge extraction with a decreased series resistance leading to improvements in the open-circuit voltage and fill factor. The champion power conversion efficiency for 0.1 cm2 devices increased from 14.3% for undoped SnO2 to 16.5% with 2% Y:SnO2 doping, which is unprecedented for f-PSCs on ITO-PET substrates employing SnO2 as an ETL.

Research Organization:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

DOE Contract Number:: AC36-08GO28308

OSTI ID:: 1974738

Report Number(s):: NREL/JA-5K00-85319; MainId:86092; UUID:c91ef776-7b98-466e-b89b-5ed4d65c03d2; MainAdminID:69560

Journal Information:: ACS Applied Energy Materials, Vol. 6, Issue 9

Country of Publication:: United States

Language:: English

References (28)

Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells Snaith, Henry J. The Journal of Physical Chemistry Letters, Vol. 4, Issue 21, p. 3623-3630 https://doi.org/10.1021/jz4020162	journal	October 2013
Cost-Performance Analysis of Perovskite Solar Modules Cai, Molang; Wu, Yongzhen; Chen, Han Advanced Science, Vol. 4, Issue 1 https://doi.org/10.1002/advs.201600269	journal	September 2016
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains Nie, W.; Tsai, H.; Asadpour, R. Science, Vol. 347, Issue 6221, p. 522-525 https://doi.org/10.1126/science.aaa0472	journal	January 2015
Low-Temperature Solution-Processed Perovskite Solar Cells with High Efficiency and Flexibility You, Jingbi; Hong, Ziruo; Yang, Yang (Michael) ACS Nano, Vol. 8, Issue 2 https://doi.org/10.1021/nn406020d	journal	January 2014
A Lab-to-Fab Study toward Roll-to-Roll Fabrication of Reproducible Perovskite Solar Cells under Ambient Room Conditions Angmo, Dechan; DeLuca, Giovanni; Scully, Andrew D. Cell Reports Physical Science, Vol. 2, Issue 1 https://doi.org/10.1016/j.xcrp.2020.100293	journal	January 2021
Increasing markets and decreasing package weight for high-specific-power photovoltaics Reese, Matthew O.; Glynn, Stephen; Kempe, Michael D. Nature Energy, Vol. 3, Issue 11 https://doi.org/10.1038/s41560-018-0258-1	journal	November 2018
Metal Oxide Charge Transport Layers for Efficient and Stable Perovskite Solar Cells Shin, Seong Sik; Lee, Seon Joo; Seok, Sang Il Advanced Functional Materials, Vol. 29, Issue 47 https://doi.org/10.1002/adfm.201900455	journal	June 2019
Recent Progress in Organic Electron Transport Materials in Inverted Perovskite Solar Cells Said, Ahmed Ali; Xie, Jian; Zhang, Qichun Small, Vol. 15, Issue 27 https://doi.org/10.1002/smll.201900854	journal	April 2019
Enhanced electron extraction using SnO2 for high-efficiency planar-structure HC(NH2)2PbI3-based perovskite solar cells Jiang, Qi; Zhang, Liuqi; Wang, Haolin Nature Energy, Vol. 2, Issue 1 https://doi.org/10.1038/nenergy.2016.177	journal	November 2016
Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide Anaraki, Elham Halvani; Kermanpur, Ahmad; Steier, Ludmilla Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE02390H	journal	January 2016
Low-Temperature Solution-Processed Tin Oxide as an Alternative Electron Transporting Layer for Efficient Perovskite Solar Cells Ke, Weijun; Fang, Guojia; Liu, Qin Journal of the American Chemical Society, Vol. 137, Issue 21 https://doi.org/10.1021/jacs.5b01994	journal	May 2015
Exploring wide bandgap metal oxides for perovskite solar cells Shin, S. S.; Lee, S. J.; Seok, S. I. APL Materials, Vol. 7, Issue 2 https://doi.org/10.1063/1.5055607	journal	February 2019
High Visible Light Photocatalytic Activity of SnO _2‐x Nanocrystals with Rich Oxygen Vacancy Liu, Quan; Zhan, Hongquan; Huang, Xuchun European Journal of Inorganic Chemistry, Vol. 2021, Issue 42 https://doi.org/10.1002/ejic.202100617	journal	September 2021
Surface passivation of perovskite film for efficient solar cells Jiang, Qi; Zhao, Yang; Zhang, Xingwang Nature Photonics, Vol. 13, Issue 7 https://doi.org/10.1038/s41566-019-0398-2	journal	April 2019
Pre‐Buried Additive for Cross‐Layer Modification in Flexible Perovskite Solar Cells with Efficiency Exceeding 22% Zheng, Zhonghao; Li, Faming; Gong, Jue Advanced Materials, Vol. 34, Issue 21 https://doi.org/10.1002/adma.202109879	journal	April 2022
Direct Deposition of Nonaqueous SnO₂ Dispersion by Blade Coating on Perovskites for the Scalable Fabrication of p–i–n Perovskite Solar Cells Chapagain, Sashil; Chandrasekhar, Pakanati S.; McGott, Deborah ACS Applied Energy Materials, Vol. 4, Issue 10 https://doi.org/10.1021/acsaem.1c01287	journal	September 2021
Reducing Hysteresis and Enhancing Performance of Perovskite Solar Cells Using Low-Temperature Processed Y-Doped SnO ₂ Nanosheets as Electron Selective Layers Yang, Guang; Lei, Hongwei; Tao, Hong Small, Vol. 13, Issue 2 https://doi.org/10.1002/smll.201601769	journal	November 2016
Low-Temperature Nb-Doped SnO ₂ Electron-Selective Contact Yields over 20% Efficiency in Planar Perovskite Solar Cells Halvani Anaraki, Elham; Kermanpur, Ahmad; Mayer, Matthew T. ACS Energy Letters, Vol. 3, Issue 4 https://doi.org/10.1021/acsenergylett.8b00055	journal	March 2018
Low-temperature solution-processed Li-doped SnO2 as an effective electron transporting layer for high-performance flexible and wearable perovskite solar cells Park, Minwoo; Kim, Jae-Yup; Son, Hae Jung Nano Energy, Vol. 26 https://doi.org/10.1016/j.nanoen.2016.04.060	journal	August 2016
Low Temperature Solution-Processed Sb:SnO ₂ Nanocrystals for Efficient Planar Perovskite Solar Cells Bai, Yang; Fang, Yanjun; Deng, Yehao ChemSusChem, Vol. 9, Issue 18 https://doi.org/10.1002/cssc.201600944	journal	August 2016
Highly Soluble Ligand Stabilized Tin Oxide Nanocrystals: Gel Formation and Thin Film Production McManus, James S.; Cunningham, Patrick D.; Regan, Laura B. Crystal Growth & Design, Vol. 14, Issue 9 https://doi.org/10.1021/cg5009957	journal	August 2014
Crystallization Pathway of Size-Controlled SnO₂ Nanoparticles Synthesized via a Nonaqueous Sol–Gel Route Lemarchand, Alex; Rémondière, Fabien; Jouin, Jenny Crystal Growth & Design, Vol. 20, Issue 2 https://doi.org/10.1021/acs.cgd.9b01428	journal	January 2020
Low-Temperature Fabrication of Highly Crystalline SnO2 Nanorods Zhang, D. -F.; Sun, L. -D.; Yin, J. -L. Advanced Materials, Vol. 15, Issue 12 https://doi.org/10.1002/adma.200304899	journal	June 2003
Gap states in the electronic structure of SnO2 single crystals and amorphous SnOx thin films Haeberle, J.; Machulik, S.; Janowitz, C. Journal of Applied Physics, Vol. 120, Issue 10 https://doi.org/10.1063/1.4962313	journal	September 2016
Structure of SnO2 nanoparticles by sol–gel method Aziz, Madzlan; Abbas, Saad Saber; Baharom, Wan Rosemaria Wan Materials Letters, Vol. 74 https://doi.org/10.1016/j.matlet.2012.01.073	journal	May 2012
SnO2 nanoparticles synthesized with Citrus aurantifolia and their performance in photocatalysis Luque, P. A.; Nava, O.; Soto-Robles, C. A. Journal of Materials Science: Materials in Electronics, Vol. 31, Issue 19 https://doi.org/10.1007/s10854-020-04242-5	journal	August 2020
Solution-Processed Nb:SnO₂ Electron Transport Layer for Efficient Planar Perovskite Solar Cells Ren, Xiaodong; Yang, Dong; Yang, Zhou ACS Applied Materials & Interfaces, Vol. 9, Issue 3 https://doi.org/10.1021/acsami.6b13362	journal	January 2017
17.78% efficient low-temperature carbon-based planar perovskite solar cells using Zn-doped SnO2 electron transport layer Ye, Haibo; Liu, Zhiyong; Liu, Xingyue Applied Surface Science, Vol. 478 https://doi.org/10.1016/j.apsusc.2019.01.237	journal	June 2019

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