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Substrate Effects When Using Photons to Make Perovskite Solar Cells

Conference ·
DOI:https://doi.org/10.2172/1959887· OSTI ID:1959887

To shorten annealing time and minimize substrate heating, flash lamps that deliver short, intense light pulses, commonly called photonic curing, are used to replace thermal annealing using hot plates or ovens. This method is different from equilibrium heating in that the radiant energy is selectively absorbed by the film. The high-intensity light pulses produce a high peak temperature in the film. Because most processes follow Arrhenius behavior, reaching high temperatures allow chemical reactions/phase transformations to occur in a short time, significantly reducing the processing time. Often the results are non-intuitive. We will present fabricating flexible halide perovskite solar cells (PSCs) on indium tin oxide (ITO) coated Willow glass. The effect of ITO transmittance on the photonic curing of nickel nitrate sol-gel precursors into nickel oxide to fabricate hole transport layer and consequently the performance of PSCs. Unexpectedly, ITO samples processed by photonic curing show improved optical and electrical properties.

Research Organization:
University of Texas at Dalals
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
DOE Contract Number:
EE0009518
OSTI ID:
1959887
Resource Relation:
Conference: American Physical Society March Meeting, Las Vegas, NV, 3/5-3/10/2023; Related Information: R. T. Piper, W. Xu, and J. W. P. Hsu, “How Optical and Electrical Properties of ITO Coated Willow Glass Affect Photonic Curing Outcome for Upscaling Perovskite Solar Cell Manufacturing,” IEEE J. Photovol 12 (3), 722-727 (2022)
Country of Publication:
United States
Language:
English

References (1)