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U.S. Department of Energy
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Compositions and methods for carbon dioxide capture

Patent ·
OSTI ID:1924933
An aqueous solvent composition is provided, comprising a nucleophilic component having one or more sterically unhindered primary or secondary amine moieties, a Brønsted base component having one or more basic nitrogen moieties, a water-soluble organic solvent, and water. A biphasic composition is provided, comprising one or more carbamate compounds, one or more conjugate acids of Brønsted base, a water-soluble organic solvent, and water. A biphasic CO2 absorption process is also provided, utilizing the biphasic solvent composition.
Research Organization:
Univ. of Illinois, Urbana-Champaign, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FE0004360; FE0026434
Assignee:
The Board of Trustees of the University of Illinois (Urbana, IL)
Patent Number(s):
11,400,410
Application Number:
16/374,471
OSTI ID:
1924933
Country of Publication:
United States
Language:
English

References (12)

Promotion of CO2 mass transfer in carbonate solutions journal January 1981
CO2 absorption by biphasic solvents: Mixtures of 1,4-Butanediamine and 2-(Diethylamino)-ethanol journal August 2013
Phase separation characteristics in biphasic solvents based on mutually miscible amines for energy efficient CO2 capture journal April 2017
Thermal degradation of amines for CO2 capture journal May 2012
Kinetics of CO2 absorption in aqueous blends of N,N-diethylethanolamine (DEEA) and N-methyl-1,3-propane-diamine (MAPA) journal June 2015
Novel Thermomorphic Biphasic Amine Solvents for CO2 Absorption and Low-Temperature Extractive Regeneration journal August 2011
Carbon dioxide absorption using a phase transitional alkanolamine–alcohol mixture journal July 2014
Study on potential biphasic solvents: Absorption capacity, CO2 loading and reaction rate journal January 2013
Capturing CO2 into the Precipitate of a Phase-Changing Solvent after Absorption journal July 2014
Organic Carbamates in Drug Design and Medicinal Chemistry journal January 2015
Experimental Investigation and Thermodynamic Modeling of Phase Transition and Equilibria in a Biphasic Solvent System for CO2 Capture journal June 2018
Development of an Energy-efficient CO2 Capture Process Using Thermomorphic Biphasic Solvents journal January 2013

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