Early transition metal stabilized high capacity cobalt free cathodes for lithium-ion batteries

Nanda, Jagjit; Belharouak, Ilias; Self, Ethan C.; Darbar, Devendrasinh Udaisinh

Early transition metal stabilized high capacity cobalt free cathodes for lithium-ion batteries

Patent · 19 July 2022

OSTI ID:1924918

Nanda, Jagjit; Belharouak, Ilias; Self, Ethan C.; Darbar, Devendrasinh Udaisinh

A cathode for a lithium battery includes LiNi_0.5-x/2Mn_0.5-x/2M_xO₂ where M is at least one selected from the group consisting of Mo, Ti, Cr, Zr and V, and x is between 0.005-0.02. The LiNi_0.5-x/2Mn_0.5-x/2M_xO₂ can be coated with Mn₂P₂O₇. The Mn₂P₂O₇ can be 1-3 wt. %, based on the total weight of the LiNi_0.5-x/2Mn_0.5-x/2M_xO₂ and Mn₂P₂O₇. A cathode composition, a lithium battery, and a method of making a lithium battery are also disclosed.

View Patent

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-00OR22725;

Assignee:: UT-Battelle, LLC (Oak Ridge, TN)

Patent Number(s):: 11,394,020

Application Number:: 16/448,169

OSTI ID:: 1924918

Country of Publication:: United States

Language:: English

References (31)

Structural and Chemical Evolution of the Layered Li-Excess Li _x MnO ₃ as a Function of Li Content from First-Principles Calculations Lee, Eunseok; Persson, Kristin A. Advanced Energy Materials, Vol. 4, Issue 15 https://doi.org/10.1002/aenm.201400498	journal	June 2014
Narrowing the Gap between Theoretical and Practical Capacities in Li-Ion Layered Oxide Cathode Materials Radin, Maxwell D.; Hy, Sunny; Sina, Mahsa Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201602888	journal	July 2017
Structural changes in vanadium oxide-based cathodes during cycling in a lithium polymer electrolyte cell Macklin, W. J.; Neat, R. J.; Sandhu, S. S. Electrochimica Acta, Vol. 37, Issue 9 https://doi.org/10.1016/0013-4686(92)80145-C	journal	January 1992
Structure and bonding in Li2MoO3 and Li2−xMoO3 (0 ≤ x ≤ 1.7) James, A. C. W. P.; Goodenough, J. B. Journal of Solid State Chemistry, Vol. 76, Issue 1 https://doi.org/10.1016/0022-4596(88)90194-6	journal	September 1988
Synthesis and electrochemical properties of lithium molybdenum oxides Kobayashi, Hironori; Tabuchi, Mitsuharu; Shikano, Masahiro Journal of Power Sources, Vol. 81-82 https://doi.org/10.1016/S0378-7753(98)00227-4	journal	September 1999
Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes Gallagher, Kevin G.; Croy, Jason R.; Balasubramanian, Mahalingam Electrochemistry Communications, Vol. 33 https://doi.org/10.1016/j.elecom.2013.04.022	journal	August 2013
Electrochemical behavior of submicron Li2MoO3 as anodes in lithium-ion batteries Li, Dan; He, Hongyan; Wu, Ximin Journal of Alloys and Compounds, Vol. 682 https://doi.org/10.1016/j.jallcom.2016.05.055	journal	October 2016
The effect of different binders on electrochemical properties of LiNi1/3Mn1/3Co1/3O2 cathode material in lithium ion batteries Xu, Jiantie; Chou, Shu-Lei; Gu, Qin-fen Journal of Power Sources, Vol. 225 https://doi.org/10.1016/j.jpowsour.2012.10.033	journal	March 2013
Structural and electrochemical stability of Li-rich layer structured Li2MoO3 in air Ma, Jun; Gao, Yurui; Wang, Zhaoxiang Journal of Power Sources, Vol. 258 https://doi.org/10.1016/j.jpowsour.2014.02.056	journal	July 2014
Li-ion battery materials: present and future Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae Materials Today, Vol. 18, Issue 5 https://doi.org/10.1016/j.mattod.2014.10.040	journal	June 2015
Synthesis, Structure, and Electrochemical Performance of High Capacity Li ₂ Cu _0.5 Ni _0.5 O ₂ Cathodes Ruther, Rose E.; Zhou, Hui; Dhital, Chetan Chemistry of Materials, Vol. 27, Issue 19 https://doi.org/10.1021/acs.chemmater.5b02843	journal	September 2015
Structural Transformations in High-Capacity Li ₂ Cu _0.5 Ni _0.5 O ₂ Cathodes Ruther, Rose E.; Samuthira Pandian, Amaresh; Yan, Pengfei Chemistry of Materials, Vol. 29, Issue 7 https://doi.org/10.1021/acs.chemmater.6b05442	journal	March 2017
Beyond One-Electron Reaction in Li Cathode Materials: Designing Li ₂ Mn _x Fe ₁ _- _x SiO ₄ Kokalj, Anton; Dominko, Robert; Mali, Gregor Chemistry of Materials, Vol. 19, Issue 15 https://doi.org/10.1021/cm063011l	journal	July 2007
LiFeO ₂ -Incorporated Li ₂ MoO ₃ as a Cathode Additive for Lithium-Ion Battery Safety Park, Kyu-Sung; Im, Dongmin; Benayad, Anass Chemistry of Materials, Vol. 24, Issue 14 https://doi.org/10.1021/cm300505y	journal	July 2012
Feasibility of Using Li ₂ MoO ₃ in Constructing Li-Rich High Energy Density Cathode Materials Ma, Jun; Zhou, Yong-Ning; Gao, Yurui Chemistry of Materials, Vol. 26, Issue 10 https://doi.org/10.1021/cm501025r	journal	May 2014
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Surface Structures of Supported Molybdenum Oxide Catalysts: Characterization by Raman and Mo L3-Edge XANES Hu, Hangchun; Wachs, Israel E.; Bare, Simon R. The Journal of Physical Chemistry, Vol. 99, Issue 27 https://doi.org/10.1021/j100027a034	journal	July 1995
Raman and ultraviolet spectroscopic characterization of molybdena on alumina catalysts Jeziorowski, Helge.; Knoezinger, Helmut. The Journal of Physical Chemistry, Vol. 83, Issue 9 https://doi.org/10.1021/j100472a012	journal	May 1979
Examining Hysteresis in Composite x Li ₂ MnO ₃ ·(1– x )LiMO ₂ Cathode Structures Croy, Jason R.; Gallagher, Kevin G.; Balasubramanian, Mahalingam The Journal of Physical Chemistry C, Vol. 117, Issue 13 https://doi.org/10.1021/jp312658q	journal	March 2013
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander Nature Chemistry, Vol. 8, Issue 7 https://doi.org/10.1038/nchem.2524	journal	May 2016
Tuning charge–discharge induced unit cell breathing in layer-structured cathode materials for lithium-ion batteries Zhou, Yong-Ning; Ma, Jun; Hu, Enyuan Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6381	journal	November 2014
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes Sathiya, M.; Rousse, G.; Ramesha, K. Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3699	journal	July 2013
Preparation and electrochemical properties of Li ₂ MoO ₃ /C composites for rechargeable Li-ion batteries Kumakura, Shinichi; Shirao, Yotaro; Kubota, Kei Physical Chemistry Chemical Physics, Vol. 18, Issue 41 https://doi.org/10.1039/C6CP05162F	journal	January 2016
Material design of high-capacity Li-rich layered-oxide electrodes: Li ₂ MnO ₃ and beyond Kim, Soo; Aykol, Muratahan; Hegde, Vinay I. Energy & Environmental Science, Vol. 10, Issue 10 https://doi.org/10.1039/C7EE01782K	journal	January 2017
Li₂MnO₃-stabilized LiMO₂ (M = Mn, Ni, Co) electrodes for lithium-ion batteries Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S. Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125 https://doi.org/10.1039/b702425h	journal	January 2007
Challenges in the development of advanced Li-ion batteries: a review Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c1ee01598b	journal	January 2011
Finite size effects on the structural progression induced by lithiation of V2O5: a combined diffraction and Raman spectroscopy study Horrocks, Gregory A.; Likely, Maliek F.; Velazquez, Jesus M. Journal of Materials Chemistry A, Vol. 1, Issue 48 https://doi.org/10.1039/c3ta13690f	journal	January 2013
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
High Capacity, Surface-Modified Layered Li [Li _(1−x) ∕ ₃Mn _(2−x) ∕ ₃Ni_x ∕ ₃Co_{x ∕ 3} ] O₂ Cathodes with Low Irreversible Capacity Loss Wu, Y.; Manthiram, A. Electrochemical and Solid-State Letters, Vol. 9, Issue 5, p. A221-A224 https://doi.org/10.1149/1.2180528	journal	March 2006
Unexpected Voltage Fade in LMR-NMC Oxides Cycled below the “Activation” Plateau Li, Yan; Bareño, Javier; Bettge, Martin Journal of The Electrochemical Society, Vol. 162, Issue 1 https://doi.org/10.1149/2.0741501jes	journal	November 2014
Optimization of Layered Cathode Materials for Lithium-Ion Batteries Julien, Christian; Mauger, Alain; Zaghib, Karim Materials, Vol. 9, Issue 7 https://doi.org/10.3390/ma9070595	journal	July 2016

Similar Records

A path toward cobalt-free lithium-ion cathodes

Journal Article · 2019 · Journal of Power Sources · OSTI ID:1606408

A Cobalt– and Manganese–Free High–Nickel Layered Oxide Cathode for Long–Life, Safer Lithium–Ion Batteries

Journal Article · 2021 · Advanced Energy Materials · OSTI ID:2217347

Related Subjects

25 ENERGY STORAGE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Early transition metal stabilized high capacity cobalt free cathodes for lithium-ion batteries

Citation Formats

References (31)

Similar Records

Related Subjects