Transferring Liquid Metal to form a Hybrid Solid Electrolyte via a Wettability-Tuning Technology for Lithium-Metal Anodes

Jin, Xin; Cai, Ziqiang; Zhang, Xinrui; Yu, Jianming; He, Qiya; Lu, Zhenda; Dahbi, Mouad; Alami, Jones; Lu, Jun; Amine, Khalil; Zhang, Huigang

doi:10.1002/adma.202200181

Transferring Liquid Metal to form a Hybrid Solid Electrolyte via a Wettability-Tuning Technology for Lithium-Metal Anodes

Journal Article · 01 April 2022 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202200181· OSTI ID:1922836

Jin, Xin; Cai, Ziqiang; Zhang, Xinrui; Yu, Jianming; He, Qiya; Lu, Zhenda; Dahbi, Mouad; Alami, Jones; Lu, Jun; Amine, Khalil; Zhang, Huigang

Integrating solid-state electrolyte (SSE) into Li-metal anodes has demonstrated great promise to unleash the high energy density of rechargeable Li-metal batteries. However, fabricating a highly cyclable SSE/Li-metal anode remains a major challenge because the densification of the SSE is usually incompatible with the reactive Li metal. Here, a liquid-metal-derived hybrid solid electrolyte (HSE) is proposed, and a facile transfer technology to construct an artificial HSE on the Li metal is reported. By tuning the wettability of the transfer substrates, electron- and ion-conductive liquid metal is sandwiched between electron-insulating and ion-conductive LiF and oxides to form the HSE. The transfer technology renders the HSE continuous, dense, and uniform. The HSE, having high ion transport, electron shut-off, and mechanical strength, makes the composite anode deliver excellent cyclability for over 4000 h at 0.5 mA cm(-2) and 1 mAh cm(-2) in a symmetrical cell. When pairing with LiFePO4 and sulfur cathodes, the HSE-coated Li metal dramatically enhances the performance of full cells. Therefore, this work demonstrates that tuning the interfacial wetting properties provides an alternate approach to build a robust solid electrolyte, which enables highly efficient Li-metal anodes.

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); USDOE Office of Energy Efficiency and Renewable Energy (EERE) - U.S.-China Clean Energy Research Center (CERC); USDOE Office of Energy Efficiency and Renewable Energy (EERE) - Office of Vehicle Technologies (VTO); National Key Research and Development Program of China

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1922836

Journal Information:: Advanced Materials, Vol. 34, Issue 17

Country of Publication:: United States

Language:: English

References (74)

Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries Albertus, Paul; Babinec, Susan; Litzelman, Scott Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0047-2	journal	December 2017
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy Li, Yuzhang; Li, Yanbin; Pei, Allen Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aam6014	journal	October 2017
Li metal battery, heal thyself Mukhopadhyay, Amartya; Jangid, Manoj K. Science, Vol. 359, Issue 6383 https://doi.org/10.1126/science.aat2452	journal	March 2018
Liquefied gas electrolytes for electrochemical energy storage devices Rustomji, Cyrus S.; Yang, Yangyuchen; Kim, Tae Kyoung Science, Vol. 356, Issue 6345 https://doi.org/10.1126/science.aal4263	journal	June 2017
Understanding the Relationships between Morphology, Solid Electrolyte Interphase Composition, and Coulombic Efficiency of Lithium Metal He, Yitao; Fan, Wenda; Zhang, Yaohui ACS Applied Materials & Interfaces, Vol. 12, Issue 19 https://doi.org/10.1021/acsami.0c00789	journal	April 2020
Li–air Battery with a Superhydrophobic Li-Protective Layer Li, Chao; Wei, Jishi; Qiu, Ke ACS Applied Materials & Interfaces, Vol. 12, Issue 20 https://doi.org/10.1021/acsami.0c05494	journal	April 2020
An Outlook on Low-Volume-Change Lithium Metal Anodes for Long-Life Batteries Ye, Huan; Zhang, Ying; Yin, Ya-Xia ACS Central Science, Vol. 6, Issue 5 https://doi.org/10.1021/acscentsci.0c00351	journal	May 2020
Unravelling the Mechanism of Lithium Nucleation and Growth and the Interaction with the Solid Electrolyte Interface Dong, Kang; Xu, Yaolin; Tan, Jinwang ACS Energy Letters, Vol. 6, Issue 5 https://doi.org/10.1021/acsenergylett.1c00551	journal	April 2021
Homogeneous Interface Conductivity for Lithium Dendrite-Free Anode Li, Quan; Pan, Hongyi; Li, Wenjun ACS Energy Letters, Vol. 3, Issue 9 https://doi.org/10.1021/acsenergylett.8b01244	journal	August 2018
Transition of lithium growth mechanisms in liquid electrolytes Bai, Peng; Li, Ju; Brushett, Fikile R. Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE01674J	journal	January 2016
Interactions between Lithium Growths and Nanoporous Ceramic Separators Bai, Peng; Guo, Jinzhao; Wang, Miao Joule, Vol. 2, Issue 11 https://doi.org/10.1016/j.joule.2018.08.018	journal	November 2018
Flexible rGO @ Nonwoven Fabrics’ Membranes Guide Stable Lithium Metal Anodes for Lithium–Oxygen Batteries Guo, Huanhuan; Yao, Yuqing; Cheng, Jun ACS Applied Energy Materials, Vol. 3, Issue 8 https://doi.org/10.1021/acsaem.0c01316	journal	July 2020
Unusual Inside–Outside Li Deposition within Three-Dimensional Honeycomb-like Hierarchical Nitrogen-Doped Framework for a Dendrite-Free Lithium Metal Anode Liu, Tiancun; Ge, Jiaxiao; Wang, Haichao ACS Applied Energy Materials, Vol. 4, Issue 3 https://doi.org/10.1021/acsaem.1c00137	journal	March 2021
In Situ Formed LiZn Alloy Skeleton for Stable Lithium Anodes Ouyang, Yan; Cui, Can; Guo, Yanpeng ACS Applied Materials & Interfaces, Vol. 12, Issue 23 https://doi.org/10.1021/acsami.0c04092	journal	May 2020
Guided Lithium Metal Deposition and Improved Lithium Coulombic Efficiency through Synergistic Effects of LiAsF ₆ and Cyclic Carbonate Additives Ren, Xiaodi; Zhang, Yaohui; Engelhard, Mark H. ACS Energy Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsenergylett.7b00982	journal	November 2017
High-Efficiency Lithium Metal Anode Enabled by a Concentrated/Fluorinated Ester Electrolyte Chen, Shijian; Xiang, Yuxuan; Zheng, Guorui ACS Applied Materials & Interfaces, Vol. 12, Issue 24 https://doi.org/10.1021/acsami.0c06930	journal	May 2020
Synergistic Effect of 3D Current Collectors and ALD Surface Modification for High Coulombic Efficiency Lithium Metal Anodes Chen, Kuan-Hung; Sanchez, Adrian J.; Kazyak, Eric Advanced Energy Materials, Vol. 9, Issue 4 https://doi.org/10.1002/aenm.201802534	journal	December 2018
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model Peled, E. Journal of The Electrochemical Society, Vol. 126, Issue 12 https://doi.org/10.1149/1.2128859	journal	January 1979
Engineering stable interfaces for three-dimensional lithium metal anodes Xie, Jin; Wang, Jiangyan; Lee, Hye Ryoung Science Advances, Vol. 4, Issue 7 https://doi.org/10.1126/sciadv.aat5168	journal	July 2018
Structural modulation of lithium metal-electrolyte interface with three-dimensional metallic interlayer for high-performance lithium metal batteries Lee, Hongkyung; Song, Jongchan; Kim, Yun-Jung Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep30830	journal	August 2016
Mirror-Like Electrodeposition of Lithium Metal under a Low-Resistance Artificial Solid Electrolyte Interphase Layer Hu, Fei; Li, Zhuo; Wang, Shaofei ACS Applied Materials & Interfaces, Vol. 12, Issue 35 https://doi.org/10.1021/acsami.0c12248	journal	August 2020
Passivation of Lithium Metal Anode via Hybrid Ionic Liquid Electrolyte toward Stable Li Plating/Stripping Li, Nian-Wu; Yin, Ya-Xia; Li, Jin-Yi Advanced Science, Vol. 4, Issue 2 https://doi.org/10.1002/advs.201600400	journal	November 2016
The Effect of 1-Pentylamine as Solid Electrolyte Interphase Precursor on Lithium Metal Anodes Ding, Markus S.; Koch, Stephan L.; Passerini, Stefano Electrochimica Acta, Vol. 240 https://doi.org/10.1016/j.electacta.2017.04.098	journal	June 2017
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions Aurbach, D. Solid State Ionics, Vol. 148, Issue 3-4 https://doi.org/10.1016/S0167-2738(02)00080-2	journal	June 2002
Cationic Surfactant-Based Electrolyte Additives for Uniform Lithium Deposition via Lithiophobic Repulsion Mechanisms Dai, Hongliu; Xi, Kai; Liu, Xin Journal of the American Chemical Society, Vol. 140, Issue 50 https://doi.org/10.1021/jacs.8b08963	journal	November 2018
Nanostructured Electrolytes for Stable Lithium Electrodeposition in Secondary Batteries Tu, Zhengyuan; Nath, Pooja; Lu, Yingying Accounts of Chemical Research, Vol. 48, Issue 11 https://doi.org/10.1021/acs.accounts.5b00427	journal	October 2015
Locally Concentrated LiPF ₆ in a Carbonate-Based Electrolyte with Fluoroethylene Carbonate as a Diluent for Anode-Free Lithium Metal Batteries Hagos, Tesfaye Teka; Thirumalraj, Balamurugan; Huang, Chen-Jui ACS Applied Materials & Interfaces, Vol. 11, Issue 10 https://doi.org/10.1021/acsami.8b21052	journal	February 2019
Vinyl Ethylene Carbonate as an Effective SEI-Forming Additive in Carbonate-Based Electrolyte for Lithium-Metal Anodes Yang, Yang; Xiong, Jian; Lai, Shaobo ACS Applied Materials & Interfaces, Vol. 11, Issue 6 https://doi.org/10.1021/acsami.8b20706	journal	January 2019
Artificial Interphases for Highly Stable Lithium Metal Anode Xu, Rui; Cheng, Xin-Bing; Yan, Chong Matter, Vol. 1, Issue 2 https://doi.org/10.1016/j.matt.2019.05.016	journal	August 2019
A facile surface chemistry route to a stabilized lithium metal anode Liang, Xiao; Pang, Quan; Kochetkov, Ivan R. Nature Energy, Vol. 2, Issue 9 https://doi.org/10.1038/nenergy.2017.119	journal	July 2017
Mechanical rolling formation of interpenetrated lithium metal/lithium tin alloy foil for ultrahigh-rate battery anode Wan, Mintao; Kang, Sujin; Wang, Li Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14550-3	journal	February 2020
Solubility-mediated sustained release enabling nitrate additive in carbonate electrolytes for stable lithium metal anode Liu, Yayuan; Lin, Dingchang; Li, Yuzhang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06077-5	journal	September 2018
Dual‐Layered Film Protected Lithium Metal Anode to Enable Dendrite‐Free Lithium Deposition Yan, Chong; Cheng, Xin‐Bing; Tian, Yang Advanced Materials, Vol. 30, Issue 25 https://doi.org/10.1002/adma.201707629	journal	April 2018
Developing a “Water-Defendable” and “Dendrite-Free” Lithium-Metal Anode Using a Simple and Promising GeCl ₄ Pretreatment Method Liao, Kaiming; Wu, Shichao; Mu, Xiaowei Advanced Materials, Vol. 30, Issue 36 https://doi.org/10.1002/adma.201705711	journal	July 2018
Stable Artificial Solid Electrolyte Interphases for Lithium Batteries Ma, Lin; Kim, Mun Sek; Archer, Lynden A. Chemistry of Materials, Vol. 29, Issue 10 https://doi.org/10.1021/acs.chemmater.6b03687	journal	May 2017
Electrolyte Additives for Lithium Metal Anodes and Rechargeable Lithium Metal Batteries: Progress and Perspectives Zhang, Heng; Eshetu, Gebrekidan Gebresilassie; Judez, Xabier Angewandte Chemie International Edition, Vol. 57, Issue 46 https://doi.org/10.1002/anie.201712702	journal	October 2018
Atomic layer deposition (ALD) of lithium fluoride (LiF) protective film on Li-ion battery LiMn1.5Ni0.5O4 cathode powder material Tiurin, Ortal; Solomatin, Nickolay; Auinat, Mahmud Journal of Power Sources, Vol. 448 https://doi.org/10.1016/j.jpowsour.2019.227373	journal	February 2020
Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries Suo, Liumin; Xue, Weijiang; Gobet, Mallory Proceedings of the National Academy of Sciences, Vol. 115, Issue 6 https://doi.org/10.1073/pnas.1712895115	journal	January 2018
Bifunctional effect of laser-induced nucleation-preferable microchannels and in situ formed LiF SEI in MXenes for stable lithium-metal batteries Xiong, Cheng; Wang, Zhenyu; Peng, Xudong Journal of Materials Chemistry A, Vol. 8, Issue 28 https://doi.org/10.1039/D0TA04302H	journal	January 2020
An All-Fluorinated Ester Electrolyte for Stable High-Voltage Li Metal Batteries Capable of Ultra-Low-Temperature Operation Holoubek, John; Yu, Mingyu; Yu, Sicen ACS Energy Letters, Vol. 5, Issue 5 https://doi.org/10.1021/acsenergylett.0c00643	journal	April 2020
Long lifespan lithium metal anodes enabled by Al2O3 sputter coating Wang, Liping; Zhang, Lei; Wang, Qingji Energy Storage Materials, Vol. 10 https://doi.org/10.1016/j.ensm.2017.08.001	journal	January 2018
Poor Man’s Atomic Layer Deposition of LiF for Additive-Free Growth of Lithium Columns Chang, Wesley; Park, Jeung Hun; Steingart, Daniel A. Nano Letters, Vol. 18, Issue 11 https://doi.org/10.1021/acs.nanolett.8b03070	journal	October 2018
Stabilized lithium metal anode by an efficient coating for high-performance Li–S batteries Xia, Shuixin; Zhang, Xun; Liang, Chao Energy Storage Materials, Vol. 24 https://doi.org/10.1016/j.ensm.2019.07.042	journal	January 2020
Flexible Amalgam Film Enables Stable Lithium Metal Anodes with High Capacities He, Guang; Li, Qingwen; Shen, Yongli Angewandte Chemie International Edition, Vol. 58, Issue 51 https://doi.org/10.1002/anie.201911800	journal	November 2019
Stabilizing Lithium Plating by a Biphasic Surface Layer Formed In Situ Pang, Quan; Liang, Xiao; Kochetkov, Ivan R. Angewandte Chemie International Edition, Vol. 57, Issue 31 https://doi.org/10.1002/anie.201805456	journal	July 2018
Li ₂ O Solid Electrolyte Interphase: Probing Transport Properties at the Chemical Potential of Lithium Guo, Rui; Gallant, Betar M. Chemistry of Materials, Vol. 32, Issue 13 https://doi.org/10.1021/acs.chemmater.0c00333	journal	May 2020
Li ₂ OHCl Crystalline Electrolyte for Stable Metallic Lithium Anodes Hood, Zachary D.; Wang, Hui; Samuthira Pandian, Amaresh Journal of the American Chemical Society, Vol. 138, Issue 6 https://doi.org/10.1021/jacs.5b11851	journal	January 2016
Phosphonium Bromides Regulating Solid Electrolyte Interphase Components and Optimizing Solvation Sheath Structure for Suppressing Lithium Dendrite Growth Qi, Shihan; He, Jian; Liu, Jiandong Advanced Functional Materials, Vol. 31, Issue 11 https://doi.org/10.1002/adfm.202009013	journal	December 2020
Suppressing dendrite growth by a functional electrolyte additive for robust Li metal anodes Wang, Gang; Xiong, Xunhui; Xie, Dong Energy Storage Materials, Vol. 23 https://doi.org/10.1016/j.ensm.2019.02.026	journal	December 2019
Fluorinated Electrolyte Compound as a Bi-Functional Interphase Additive for Both, Anodes and Cathodes in Lithium-Ion Batteries Janssen, Pia; Kasnatscheew, Johannes; Streipert, Benjamin Journal of The Electrochemical Society, Vol. 165, Issue 14 https://doi.org/10.1149/2.1221814jes	journal	January 2018
Liquid Metal Alloys as Self-Healing Negative Electrodes for Lithium Ion Batteries Deshpande, Rutooj D.; Li, Juchuan; Cheng, Yang-Tse Journal of The Electrochemical Society, Vol. 158, Issue 8 https://doi.org/10.1149/1.3591094	journal	January 2011
High-performance bismuth-gallium positive electrode for liquid metal battery Xie, Hongliang; Zhao, Hailei; Wang, Jie Journal of Power Sources, Vol. 472 https://doi.org/10.1016/j.jpowsour.2020.228634	journal	October 2020
A Catalytic Path for Electrolyte Reduction in Lithium-Ion Cells Revealed by in Situ Attenuated Total Reflection-Fourier Transform Infrared Spectroscopy Shi, Feifei; Ross, Philip N.; Zhao, Hui Journal of the American Chemical Society, Vol. 137, Issue 9 https://doi.org/10.1021/ja5128456	journal	February 2015
How Can the Electrode Influence the Formation of the Solid Electrolyte Interface? Li, Ying; Liu, Mingquan; Feng, Xin ACS Energy Letters, Vol. 6, Issue 9 https://doi.org/10.1021/acsenergylett.1c01359	journal	August 2021
Predicting trends in rate parameters for self-diffusion on FCC metal surfaces Agrawal, Paras M.; Rice, Betsy M.; Thompson, Donald L. Surface Science, Vol. 515, Issue 1 https://doi.org/10.1016/S0039-6028(02)01916-7	journal	August 2002
Many-Body Effects in fcc Metals: A Lennard-Jones Embedded-Atom Potential Baskes, M. I. Physical Review Letters, Vol. 83, Issue 13 https://doi.org/10.1103/PhysRevLett.83.2592	journal	September 1999
Effective Lennard–Jones potential for cubic metals in the frame of embedded atom model Avinc, Ahmet; Ivanov Dimitrov, Ventzislav Computational Materials Science, Vol. 13, Issue 4 https://doi.org/10.1016/S0927-0256(98)00091-3	journal	January 1999
Compression of Carbon Nanotubes Filled with C 60 , CH 4 , or Ne: Predictions from Molecular Dynamics Simulations Ni, Boris; Sinnott, Susan B.; Mikulski, Paul T. Physical Review Letters, Vol. 88, Issue 20 https://doi.org/10.1103/PhysRevLett.88.205505	journal	May 2002
Atomic-scale computations of the lattice contribution to thermal conductivity of single-walled carbon nanotubes Grujicic, M.; Cao, G.; Gersten, Bonnie Materials Science and Engineering: B, Vol. 107, Issue 2 https://doi.org/10.1016/j.mseb.2003.11.012	journal	March 2004
A reactive potential for hydrocarbons with intermolecular interactions Stuart, Steven J.; Tutein, Alan B.; Harrison, Judith A. The Journal of Chemical Physics, Vol. 112, Issue 14 https://doi.org/10.1063/1.481208	journal	April 2000
The Fe-Ga (Iron-Gallium) system Okamoto, H. Bulletin of Alloy Phase Diagrams, Vol. 11, Issue 6 https://doi.org/10.1007/BF02841721	journal	December 1990
Supplemental Literature Review of Binary Phase Diagrams: Al-Nd, Al-Sm, Al-V, Bi-Yb, Ca-In, Ca-Sb, Cr-Nb, Cu-Ga, Ge-O, Pt-Sn, Re-Y, and Te-Yb Okamoto, H. Journal of Phase Equilibria and Diffusion, Vol. 37, Issue 3 https://doi.org/10.1007/s11669-016-0452-4	journal	February 2016
Elimination of “Voltage Noise” of Poly (Ethylene Oxide)-Based Solid Electrolytes in High-Voltage Lithium Batteries: Linear versus Network Polymers Homann, Gerrit; Stolz, Lukas; Winter, Martin iScience, Vol. 23, Issue 6 https://doi.org/10.1016/j.isci.2020.101225	journal	June 2020
Poly(Ethylene Oxide)-based Electrolyte for Solid-State-Lithium-Batteries with High Voltage Positive Electrodes: Evaluating the Role of Electrolyte Oxidation in Rapid Cell Failure Homann, Gerrit; Stolz, Lukas; Nair, Jijeesh Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-61373-9	journal	March 2020
Stabilizing Lithium Metal Anode Enabled by a Natural Polymer Layer for Lithium–Sulfur Batteries Cui, Can; Zhang, Rupeng; Fu, Chuankai ACS Applied Materials & Interfaces, Vol. 13, Issue 24 https://doi.org/10.1021/acsami.1c06289	journal	June 2021
Implantable Solid Electrolyte Interphase in Lithium-Metal Batteries Cheng, Xin-Bing; Yan, Chong; Chen, Xiang Chem, Vol. 2, Issue 2 https://doi.org/10.1016/j.chempr.2017.01.003	journal	February 2017
Stable cycling of high-voltage lithium metal batteries in ether electrolytes Jiao, Shuhong; Ren, Xiaodi; Cao, Ruiguo Nature Energy, Vol. 3, Issue 9 https://doi.org/10.1038/s41560-018-0199-8	journal	July 2018
Bisalt ether electrolytes: a pathway towards lithium metal batteries with Ni-rich cathodes Alvarado, Judith; Schroeder, Marshall A.; Pollard, Travis P. Energy & Environmental Science, Vol. 12, Issue 2 https://doi.org/10.1039/C8EE02601G	journal	January 2019
Effective Suppression of Dendritic Lithium Growth Using an Ultrathin Coating of Nitrogen and Sulfur Codoped Graphene Nanosheets on Polymer Separator for Lithium Metal Batteries Shin, Won-Kyung; Kannan, Aravindaraj G.; Kim, Dong-Won ACS Applied Materials & Interfaces, Vol. 7, Issue 42 https://doi.org/10.1021/acsami.5b07730	journal	October 2015
High-Energy Density Li metal Dual-Ion Battery with a Lithium Nitrate-Modified Carbonate-Based Electrolyte Wu, Li-Na; Peng, Jun; Sun, Ya-Ke ACS Applied Materials & Interfaces, Vol. 11, Issue 20 https://doi.org/10.1021/acsami.9b05053	journal	April 2019
Efficient Ni ₂ Co ₄ P ₃ Nanowires Catalysts Enhance Ultrahigh‐Loading Lithium–Sulfur Conversion in a Microreactor‐Like Battery Shen, Zihan; Cao, Mengqiu; Zhang, Zili Advanced Functional Materials, Vol. 30, Issue 3 https://doi.org/10.1002/adfm.201906661	journal	October 2019
Sulfophobic and Vacancy Design Enables Self‐Cleaning Electrodes for Efficient Desulfurization and Concurrent Hydrogen Evolution with Low Energy Consumption Zhang, Shuo; Zhou, Qingwen; Shen, Zihan Advanced Functional Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adfm.202101922	journal	May 2021

Similar Records

Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface

Journal Article · 2017 · Science Advances · OSTI ID:1425393

Fu, Kun (Kelvin); Gong, Yunhui; Liu, Boyang; +10 more

A New Lamination and doping Concepts for Enhanced Li – S Battery Performance

Technical Report · 2017 · OSTI ID:1417532

Kumta, Prashant N.; Datta, Moni K.; Velikokhatnyi, Oleg; +2 more

Solid‐State Electrolyte Design for Lithium Dendrite Suppression

Journal Article · 2020 · Advanced Materials · OSTI ID:1804192

Ji, Xiao; Hou, Singyuk; Wang, Pengfei; +5 more

Related Subjects

li-metal anodes
liquid metals
wettability

Transferring Liquid Metal to form a Hybrid Solid Electrolyte via a Wettability-Tuning Technology for Lithium-Metal Anodes

Citation Formats

References (74)

Similar Records

Related Subjects