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Title: Photochemically Mediated Polymerization of Molecular Furan and Pyridine: Synthesis of Nanothreads at

Journal Article · · J. Am. Chem. Soc.
DOI:· OSTI ID:1902359

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; DOE - BASIC ENERGY SCIENCES; DOE-NNSA; National Science Foundation (NSF); OTHER; UNIVERSITY
Journal Information:
J. Am. Chem. Soc., Vol. 144, Issue (48)
Country of Publication:
United States

References (66)

Pressure-Induced Polymerization of CO 2 in Lithium–Carbon Dioxide Phases journal December 2017
Pressure‐induced actin polymerization in vascular smooth muscle as a mechanism underlying myogenic behavior journal January 2002
Benzene-derived carbon nanothreads journal September 2014
Mechanochemical Synthesis of Carbon Nanothread Single Crystals journal November 2017
Carbon Nitride Nanothread Crystals Derived from Pyridine journal March 2018
‘Sacrificial’ supramolecular assembly and pressure-induced polymerization: toward sequence-defined functionalized nanothreads journal January 2020
Mechanistic insights into the pressure-induced polymerization of aryl/perfluoroaryl co-crystals journal January 2022
Scalable Synthesis of Crystalline One-Dimensional Carbon Nanothreads through Modest-Pressure Polymerization of Furan journal January 2021
Evidence for Functionalized Carbon Nanothreads from π-Stacked, para -Disubstituted Benzenes journal November 2020
Controlled Single-Crystalline Polymerization of C 10 H 8 ·C 10 F 8 under Pressure journal September 2019
Nanoarchitecture through Strained Molecules: Cubane-Derived Scaffolds and the Smallest Carbon Nanothreads journal January 2020
Evidence for Orientational Order in Nanothreads Derived from Thiophene journal October 2019
Solid-State Pathway Control via Reaction-Directing Heteroatoms: Ordered Pyridazine Nanothreads through Selective Cycloaddition journal January 2022
Structure–Reactivity Relationship in the High-Pressure Formation of Double-Core Carbon Nanothreads from Azobenzene Crystal journal July 2021
Synthesis of double core chromophore-functionalized nanothreads by compressing azobenzene in a diamond anvil cell journal January 2021
Towards custom built double core carbon nanothreads using stilbene and pseudo-stilbene type systems journal January 2022
One-dimensional diamondoid polyaniline-like nanothreads from compressed crystal aniline journal January 2018
Pressure-Induced Polymerization of Polycyclic Arene–Perfluoroarene Cocrystals: Single Crystal X-ray Diffraction Studies, Reaction Kinetics, and Design of Columnar Hydrofluorocarbons journal October 2020
Modulating the H-bond strength by varying the temperature for the high pressure synthesis of nitrogen rich carbon nanothreads journal January 2020
The Chemical Structure of Carbon Nanothreads Analyzed by Advanced Solid-State NMR journal May 2018
Perfect and Defective 13 C-Furan-Derived Nanothreads from Modest-Pressure Synthesis Analyzed by 13 C NMR journal June 2021
Constraining Carbon Nanothread Structures by Experimental and Calculated Nuclear Magnetic Resonance Spectra journal June 2018
Visible Light Photocatalysis: The Development of Photocatalytic Radical Ion Cycloadditions journal April 2013
Supramolecular Control of Reactivity in the Solid State: From Templates to Ladderanes to Metal−Organic Frameworks journal February 2008
Selection Rules for Concerted Cycloaddition Reactions journal May 1965
Radical Cation Diels–Alder Cycloadditions by Visible Light Photocatalysis journal December 2011
Radical Cation Diels–Alder Reactions by TiO2 Photocatalysis journal March 2019
Visible-Light-Irradiated Graphitic Carbon Nitride Photocatalyzed Diels-Alder Reactions with Dioxygen as Sustainable Mediator for Photoinduced Electrons journal July 2017
Photooxidizing Chromium Catalysts for Promoting Radical Cation Cycloadditions journal April 2015
Photochemically induced radical-cation Diels-Alder reaction of indole and electron-rich dienes journal February 1991
Enantioselective counter-anions in photoredox catalysis: The asymmetric cation radical Diels-Alder reaction journal June 2018
Organophotoredox-Catalyzed Intermolecular Oxa-[4+2] Cycloaddition Reactions journal July 2019
Metal-Free Ring-Opening Metathesis Polymerization journal January 2015
Molecular Weight Control via Cross Metathesis in Photo‐Redox Mediated Ring‐Opening Metathesis Polymerization journal March 2020
Cationic Polymerization of Vinyl Ethers Controlled by Visible Light journal November 2016
Organocatalyzed Photoredox Radical Ring-Opening Polymerization of Functionalized Vinylcyclopropanes journal September 2020
Controlling Polymer Composition in Organocatalyzed Photoredox Radical Ring-Opening Polymerization of Vinylcyclopropanes journal July 2019
Organocatalyzed Atom Transfer Radical Polymerization Using N -Aryl Phenoxazines as Photoredox Catalysts journal August 2016
Visible-Light-Controlled Living Radical Polymerization from a Trithiocarbonate Iniferter Mediated by an Organic Photoredox Catalyst journal April 2015
Selective Photoactivation: From a Single Unit Monomer Insertion Reaction to Controlled Polymer Architectures journal February 2016
Confirmation of Phase Transitions and Laser-Assisted Chemical Reaction for Pyridine under High Pressure journal July 2022
High-pressure photochemistry of furane crystal journal May 2003
Structure and reactivity of pyridine crystal under pressure journal May 2011
High Pressure Photoinduced Ring Opening of Benzene journal February 2002
Single-Crystal-to-Single-Crystal Topochemical Polymerizations by Design journal September 2008
Supramolecular Construction of Molecular Ladders in the Solid State journal January 2004
Topochemical polymerizations for the solid-state synthesis of organic polymers journal January 2021
Single‐Crystal to Single‐Crystal Photochemical Structural Transformations of Interpenetrated 3 D Coordination Polymers by [2+2] Cycloaddition Reactions journal January 2010
Dewar pyridine studied by matrix isolation infrared spectroscopy and DFT calculation journal May 1999
High pressure reactivity of solid furan probed by infrared and Raman spectroscopy journal January 2003
Extended multi-configuration quasi-degenerate perturbation theory: The new approach to multi-state multi-reference perturbation theory journal June 2011
Communication: Extended multi-state complete active space second-order perturbation theory: Energy and nuclear gradients journal August 2011
Density matrix averaged atomic natural orbital (ANO) basis sets for correlated molecular wave functions: I. First row atoms journal January 1990
Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen journal January 1989
Electron affinities of the first‐row atoms revisited. Systematic basis sets and wave functions journal May 1992
Modeling Photochemical [4 + 4] Cycloadditions:  Conical Intersections Located with CASSCF for Butadiene + Butadiene journal January 1997
Photochemical Dimerization of 2-Aminopyridines and 2-Pyridones journal March 1963
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu journal April 2010
Compression curves of transition metals in the Mbar range: Experiments and projector augmented-wave calculations journal September 2008
Enhancing the mechanical properties of single-crystal CVD diamond journal August 2009
Assessment of type IIA diamond as an optical material for use in severe environments conference December 1992
Modern quantum chemistry with [Open]Molcas journal June 2020
OpenMolcas: From Source Code to Insight journal September 2019
Density matrix averaged atomic natural orbital (ANO) basis sets for correlated molecular wave functions: IV. Medium size basis sets for the atoms H-Kr journal January 1995
Geodesic interpolation for reaction pathways journal April 2019
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals journal July 2007