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Title: Rapid atom-efficient polyolefin plastics hydrogenolysis mediated by a well-defined single-site elect

Journal Article · · Nat. Commun.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; DOE - BASIC ENERGY SCIENCES
OSTI ID:
1901386
Journal Information:
Nat. Commun., Vol. 13
Country of Publication:
United States
Language:
ENGLISH

References (45)

Production, use, and fate of all plastics ever made journal July 2017
Microplastics and human health journal February 2021
Plastic waste inputs from land into the ocean journal February 2015
Towards circular carbo-chemicals – the metamorphosis of petrochemicals journal January 2021
The future of plastics recycling journal November 2017
Chemically recyclable polymers: a circular economy approach to sustainability journal January 2017
Mechanical and chemical recycling of solid plastic waste journal November 2017
Beyond Mechanical Recycling: Giving New Life to Plastic Waste journal June 2020
Efficient and selective degradation of polyethylenes into liquid fuels and waxes under mild conditions journal June 2016
Polyethylene upcycling to long-chain alkylaromatics by tandem hydrogenolysis/aromatization journal October 2020
Upcycling Single-Use Polyethylene into High-Quality Liquid Products journal September 2019
Conversion of Polyolefin Waste to Liquid Alkanes with Ru-Based Catalysts under Mild Conditions journal December 2020
Polypropylene Plastic Waste Conversion to Lubricants over Ru/TiO 2 Catalysts journal June 2021
Deconstruction of high-density polyethylene into liquid hydrocarbon fuels and lubricants by hydrogenolysis over Ru catalyst journal July 2021
Catalytic upcycling of high-density polyethylene via a processive mechanism journal October 2020
Tandem Heterogeneous Catalysis for Polyethylene Depolymerization via an Olefin-Intermediate Process journal January 2021
Catalytic Hydrogenolysis at Low Temperature and Pressure of Polyethylene and Polypropylene to Diesels or Lower Alkanes by a Zirconium Hydride Supported on Silica-Alumina: A Step Toward Polyolefin Degradation by the Microscopic Reverse of Ziegler-Natta Polymerization journal April 1998
Nontraditional Catalyst Supports in Surface Organometallic Chemistry journal September 2020
Lewis Acids:  From Conventional Homogeneous to Green Homogeneous and Heterogeneous Catalysis journal November 2003
Surface structural-chemical characterization of a single-site d0 heterogeneous arene hydrogenation catalyst having 100% active sites journal December 2012
Benzene Selectivity in Competitive Arene Hydrogenation: Effects of Single-Site Catalyst···Acidic Oxide Surface Binding Geometry journal April 2015
Supported Single-Site Organometallic Catalysts for the Synthesis of High-Performance Polyolefins journal November 2014
Solid catalyst treated with anion journal March 1990
Understanding and exploiting C–H bond activation journal May 2002
σ-Bond Metathesis: A 30-Year Retrospective journal September 2013
Disordered, Sub-Nanometer Ru Structures on CeO2 are Highly Efficient and Selective Catalysts in Polymer Upcycling by Hydrogenolysis journal April 2022
Molecular Understanding of the Formation of Surface Zirconium Hydrides upon Thermal Treatment under Hydrogen of [(⋮SiO)Zr(CH 2 t Bu) 3 ] by Using Advanced Solid-State NMR Techniques journal October 2004
Mesoporous Silica-Supported Amidozirconium-Catalyzed Carbonyl Hydroboration journal November 2015
Cationic Metallocene Polymerization Catalysts. Synthesis and Properities of the First Base-Free Zirconocene Hydride journal October 1992
Caveat on the Actual Robustness of Heteronuclear NMR Methods for Probing the Surface of γ-Alumina and Related Catalysts journal April 2019
Single-Site Tetracoordinated Aluminum Hydride Supported on Mesoporous Silica. From Dream to Reality! journal September 2016
The chemistry of sterically crowded aryl oxide ligands. 3. Crystal and molecular structure and spectroscopic properties of mixed benzyl-aryl oxide compounds of zirconium journal May 1985
On the Quest for New Mixed-Metal μ-Oxo-bridged Complexes: Synthesis of Compounds Containing Transition Metal−Oxygen−Main Group Metal Motifs M−O−M1(M = Ti, Zr; M1= Al, Ga) without Cyclopentadienyl Ligands journal July 2008
Catalytic Cleavage of the C-H and C-C Bonds of Alkanes by Surface Organometallic Chemistry: An EXAFS and IR Characterization of a Zr-H Catalyst journal February 1996
Beyond the Active Site. Cp*ZrMe 3 /Sulfated Alumina‐Catalyzed Olefin Polymerization Tacticity via Catalyst⋅⋅⋅Surface Ion‐Pairing journal April 2021
Surface vs Homogeneous Organo-Hafnium Catalyst Ion-Pairing and Ligand Effects on Ethylene Homo- and Copolymerizations journal February 2021
Introducing DDEC6 atomic population analysis: part 1. Charge partitioning theory and methodology journal January 2016
β-Alkyl Elimination: Fundamental Principles and Some Applications journal June 2016
Carbon-carbon activation at electrophilic d0/fn centers. Facile, regioselective .beta.-alkyl shift-based ring-opening polymerization reactions of methylenecyclobutane journal April 1993
Elimination stabilized alkyls. Part III. Trimethylsilylmethyl and neopentyl alkyls of transition metals journal January 1973
CP2K: An electronic structure and molecular dynamics software package - Quickstep: Efficient and accurate electronic structure calculations journal May 2020
Gaussian basis sets for accurate calculations on molecular systems in gas and condensed phases journal September 2007
Separable dual-space Gaussian pseudopotentials journal July 1996
Generalized Gradient Approximation Made Simple journal October 1996
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu journal April 2010