Intrinsic glassy-metallic transport in an amorphous coordination polymer

Xie, Jiaze; Ewing, Simon; Boyn, Jan-Niklas; Filatov, Alexander S.; Cheng, Baorui; Ma, Tengzhou; Grocke, Garrett L.; Zhao, Norman; Itani, Ram; Sun, Xiaotong; Cho, Himchan; Chen, Zhihengyu; Chapman, Karena W.; Patel, Shrayesh N.; Talapin, Dmitri V.; Park, Jiwoong; Mazziotti, David A.; Anderson, John S.

doi:10.1038/s41586-022-05261-4

Intrinsic glassy-metallic transport in an amorphous coordination polymer

Journal Article · 01 October 2022 · Nature

DOI:https://doi.org/10.1038/s41586-022-05261-4· OSTI ID:1901291

Xie, Jiaze; Ewing, Simon; Boyn, Jan-Niklas; Filatov, Alexander S.; Cheng, Baorui; Ma, Tengzhou; Grocke, Garrett L.; Zhao, Norman; Itani, Ram; Sun, Xiaotong; Cho, Himchan; Chen, Zhihengyu; Chapman, Karena W.; Patel, Shrayesh N.; Talapin, Dmitri V.; Park, Jiwoong; Mazziotti, David A.; Anderson, John S.

Research Organization:: Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)

Sponsoring Organization:: DOE - Office Of Science; U.S. ARMY RESEARCH

OSTI ID:: 1901291

Journal Information:: Nature, Journal Name: Nature Vol. 611

Country of Publication:: United States

Language:: ENGLISH

References (46)

802. Complex halides of the transition metals. Part I. Tetrahedral nickel complexes Gill, Naida S.; Nyholm, R. S. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9590003997	journal	January 1959
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
Methods for the ICP-OES Analysis of Semiconductor Materials Morrison, Calynn; Sun, Haochen; Yao, Yuewei Chemistry of Materials, Vol. 32, Issue 5 https://doi.org/10.1021/acs.chemmater.0c00255	journal	February 2020
Synthesis of a Copper 1,3,5-Triamino-2,4,6-benzenetriol Metal–Organic Framework Jiang, Yi; Oh, Inseon; Joo, Se Hun Journal of the American Chemical Society, Vol. 142, Issue 43 https://doi.org/10.1021/jacs.0c02389	journal	October 2020
Thermal Contraction and Disordering of the Al(110) Surface Marzari, Nicola; Vanderbilt, David; De Vita, Alessandro Physical Review Letters, Vol. 82, Issue 16 https://doi.org/10.1103/PhysRevLett.82.3296	journal	April 1999
Theoretical approaches to x-ray absorption fine structure Rehr, J. J.; Albers, R. C. Reviews of Modern Physics, Vol. 72, Issue 3 https://doi.org/10.1103/RevModPhys.72.621	journal	July 2000
A Three-Dimensional Synthetic Metallic Crystal Composed of Single-Component Molecules Tanaka, H. Science, Vol. 291, Issue 5502 https://doi.org/10.1126/science.291.5502.285	journal	January 2001
Building block ligands for new molecular conductors: homobimetallic tetrathiafulvalene tetrathiolates and metal diselenolenes and ditellurolenes McCullough, Richard D.; Belot, John A.; Seth, Jyoti Journal of Materials Chemistry, Vol. 5, Issue 10 https://doi.org/10.1039/jm9950501581	journal	January 1995
Nobel Lecture: Semiconducting and metallic polymers: The fourth generation of polymeric materials Heeger, Alan J. Reviews of Modern Physics, Vol. 73, Issue 3 https://doi.org/10.1103/RevModPhys.73.681	journal	September 2001
Quantum dot solids showing state-resolved band-like transport Lan, Xinzheng; Chen, Menglu; Hudson, Margaret H. Nature Materials, Vol. 19, Issue 3 https://doi.org/10.1038/s41563-019-0582-2	journal	January 2020
Wiedemann–Franz Law for Molecular Hopping Transport Craven, Galen T.; Nitzan, Abraham Nano Letters, Vol. 20, Issue 2 https://doi.org/10.1021/acs.nanolett.9b04070	journal	January 2020
Geometric Frustration of Icosahedron in Metallic Glasses Hirata, A.; Kang, L. J.; Fujita, T. Science, Vol. 341, Issue 6144 https://doi.org/10.1126/science.1232450	journal	July 2013
Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds Xie, Jiaze; Boyn, Jan-Niklas; Filatov, Alexander S. Chemical Science, Vol. 11, Issue 4 https://doi.org/10.1039/C9SC04381K	journal	January 2020
The journey of conducting polymers from discovery to application Guo, Xugang; Facchetti, Antonio Nature Materials, Vol. 19, Issue 9 https://doi.org/10.1038/s41563-020-0778-5	journal	August 2020
Approaching disorder-free transport in high-mobility conjugated polymers Venkateshvaran, Deepak; Nikolka, Mark; Sadhanala, Aditya Nature, Vol. 515, Issue 7527 https://doi.org/10.1038/nature13854	journal	November 2014
Precision and efficiency in solid-state pseudopotential calculations Prandini, Gianluca; Marrazzo, Antimo; Castelli, Ivano E. npj Computational Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41524-018-0127-2	journal	December 2018
A Microporous and Naturally Nanostructured Thermoelectric Metal-Organic Framework with Ultralow Thermal Conductivity Sun, Lei; Liao, Bolin; Sheberla, Dennis Joule, Vol. 1, Issue 1 https://doi.org/10.1016/j.joule.2017.07.018	journal	September 2017
Advanced capabilities for materials modelling with Quantum ESPRESSO Giannozzi, P.; Andreussi, O.; Brumme, T. Journal of Physics: Condensed Matter, Vol. 29, Issue 46 https://doi.org/10.1088/1361-648X/aa8f79	journal	October 2017
Thermopower-conductivity relation for distinguishing transport mechanisms: Polaron hopping in CeO 2 and band conduction in SrTiO 3 Kang, Stephen Dongmin; Dylla, Maxwell; Snyder, G. Jeffrey Physical Review B, Vol. 97, Issue 23 https://doi.org/10.1103/PhysRevB.97.235201	journal	June 2018
Air-Stable n-Channel Organic Single Crystal Field-Effect Transistors Based on Microribbons of Core-Chlorinated Naphthalene Diimide He, Tao; Stolte, Matthias; Würthner, Frank Advanced Materials, Vol. 25, Issue 48 https://doi.org/10.1002/adma.201303392	journal	September 2013
Is metallic glass poised to come of age? Plummer, John Nature Materials, Vol. 14, Issue 6 https://doi.org/10.1038/nmat4297	journal	May 2015
Variable range hopping and thermally activated transport in molybdenum-based MXenes Halim, Joseph; Moon, Eun Ju; Eklund, Per Physical Review B, Vol. 98, Issue 10 https://doi.org/10.1103/PhysRevB.98.104202	journal	September 2018
Electrically Conductive Metal–Organic Frameworks Xie, Lilia S.; Skorupskii, Grigorii; Dincă, Mircea Chemical Reviews https://doi.org/10.1021/acs.chemrev.9b00766	journal	April 2020
Metallic transport in polyaniline Lee, Kwanghee; Cho, Shinuk; Heum Park, Sung Nature, Vol. 441, Issue 7089 https://doi.org/10.1038/nature04705	journal	May 2006
Superconductivity in a Copper(II)-Based Coordination Polymer with Perfect Kagome Structure Huang, Xing; Zhang, Shuai; Liu, Liyao Angewandte Chemie International Edition, Vol. 57, Issue 1 https://doi.org/10.1002/anie.201707568	journal	December 2017
Semi-metallic polymers Bubnova, Olga; Khan, Zia Ullah; Wang, Hui Nature Materials, Vol. 13, Issue 2 https://doi.org/10.1038/nmat3824	journal	December 2013
A LAXS (large angle x-ray scattering) and EXAFS (extended x-ray absorption fine structure) investigation of conductive amorphous nickel tetrathiolato polymers Vogt, Thomas.; Faulmann, Christophe.; Soules, Regis. Journal of the American Chemical Society, Vol. 110, Issue 6 https://doi.org/10.1021/ja00214a028	journal	March 1988
Electronic transport properties of conducting polymers and carbon nanotubes Kaiser, A. B. Reports on Progress in Physics, Vol. 64, Issue 1 https://doi.org/10.1088/0034-4885/64/1/201	journal	December 2000
Reproducibility in density functional theory calculations of solids Lejaeghere, K.; Bihlmayer, G.; Bjorkman, T. Science, Vol. 351, Issue 6280 https://doi.org/10.1126/science.aad3000	journal	March 2016
Carrier generation and electronic properties of a single-component pure organic metal Kobayashi, Yuka; Terauchi, Takeshi; Sumi, Satoshi Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4768	journal	October 2016
Large-Scale Semidefinite Programming for Many-Electron Quantum Mechanics Mazziotti, David A. Physical Review Letters, Vol. 106, Issue 8 https://doi.org/10.1103/PhysRevLett.106.083001	journal	February 2011
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502 https://doi.org/10.1088/0953-8984/21/39/395502	journal	September 2009
A nonconjugated radical polymer glass with high electrical conductivity Joo, Yongho; Agarkar, Varad; Sung, Seung Hyun Science, Vol. 359, Issue 6382 https://doi.org/10.1126/science.aao7287	journal	March 2018
Comparative X-ray absorption spectroscopic structural characterization of nickel metalloenzyme active sites Scott, Robert A. Physica B: Condensed Matter, Vol. 158, Issue 1-3 https://doi.org/10.1016/0921-4526(89)90207-X	journal	June 1989
Tutorial on Powder X-ray Diffraction for Characterizing Nanoscale Materials Holder, Cameron F.; Schaak, Raymond E. ACS Nano, Vol. 13, Issue 7 https://doi.org/10.1021/acsnano.9b05157	journal	July 2019
Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design Liu, Zilu; Liu, Tianjun; Savory, Christopher N. Advanced Functional Materials, Vol. 30, Issue 32 https://doi.org/10.1002/adfm.202003106	journal	June 2020
Signature of Metallic Behavior in the Metal–Organic Frameworks M ₃ (hexaiminobenzene) ₂ (M = Ni, Cu) Dou, Jin-Hu; Sun, Lei; Ge, Yicong Journal of the American Chemical Society, Vol. 139, Issue 39 https://doi.org/10.1021/jacs.7b07234	journal	September 2017
Recent progress on conducting organic charge-transfer salts Bryce, Martin R. Chemical Society Reviews, Vol. 20, Issue 3 https://doi.org/10.1039/cs9912000355	journal	January 1991
XCrySDen—a new program for displaying crystalline structures and electron densities Kokalj, Anton Journal of Molecular Graphics and Modelling, Vol. 17, Issue 3-4 https://doi.org/10.1016/S1093-3263(99)00028-5	journal	June 1999
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Noninnocence in Metal Complexes: A Dithiolene Dawn Eisenberg, Richard; Gray, Harry B. Inorganic Chemistry, Vol. 50, Issue 20 https://doi.org/10.1021/ic2011748	journal	October 2011
TTF[Ni(dmit)2]2: From single-crystals to thin layers, nanowires, and nanoparticles Valade, Lydie; de Caro, Dominique; Faulmann, Christophe Coordination Chemistry Reviews, Vol. 308 https://doi.org/10.1016/j.ccr.2015.05.014	journal	February 2016
Thermal conductivity of metallic glasses Choy, C. L.; Leung, W. P.; Ng, Y. K. Journal of Applied Physics, Vol. 66, Issue 11 https://doi.org/10.1063/1.343725	journal	December 1989
Single-Component Molecular Metals with Extended-TTF Dithiolate Ligands Kobayashi, Akiko; Fujiwara, Emiko; Kobayashi, Hayao Chemical Reviews, Vol. 104, Issue 11 https://doi.org/10.1021/cr030656l	journal	November 2004
Leveraging Sequential Doping of Semiconducting Polymers to Enable Functionally Graded Materials for Organic Thermoelectrics Ma, Tengzhou; Dong, Ban Xuan; Grocke, Garrett L. Macromolecules, Vol. 53, Issue 8 https://doi.org/10.1021/acs.macromol.0c00402	journal	April 2020
Metallic Thin Films of TTF[Ni(dmit)2]2 by Electrodeposition on (001)-Oriented Silicon Substrates de Caro, D.; Fraxedas, J.; Faulmann, C. Advanced Materials, Vol. 16, Issue 910 https://doi.org/10.1002/adma.200306427	journal	May 2004

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