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Title: Disordered, Sub-Nanometer Ru Structures on CeO[subscript 2] are Highly Efficient and Selective Catal

Authors:
; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
DOE - Office Of Science; DOE - BASIC ENERGY SCIENCES
OSTI Identifier:
1901269
Resource Type:
Journal Article
Journal Name:
ACS Catal.
Additional Journal Information:
Journal Volume: 12; Journal Issue: (8)
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Chen, Linxiao, Meyer, Laura C., Kovarik, Libor, Meira, Debora, Pereira-Hernandez, Xavier I., Shi, Honghong, Khivantsev, Konstantin, Gutierrez, Oliver Y., and Szanyi, Janos. Disordered, Sub-Nanometer Ru Structures on CeO[subscript 2] are Highly Efficient and Selective Catal. United States: N. p., 2022. Web. doi:10.1021/acscatal.2c00684.
Chen, Linxiao, Meyer, Laura C., Kovarik, Libor, Meira, Debora, Pereira-Hernandez, Xavier I., Shi, Honghong, Khivantsev, Konstantin, Gutierrez, Oliver Y., & Szanyi, Janos. Disordered, Sub-Nanometer Ru Structures on CeO[subscript 2] are Highly Efficient and Selective Catal. United States. https://doi.org/10.1021/acscatal.2c00684
Chen, Linxiao, Meyer, Laura C., Kovarik, Libor, Meira, Debora, Pereira-Hernandez, Xavier I., Shi, Honghong, Khivantsev, Konstantin, Gutierrez, Oliver Y., and Szanyi, Janos. 2022. "Disordered, Sub-Nanometer Ru Structures on CeO[subscript 2] are Highly Efficient and Selective Catal". United States. https://doi.org/10.1021/acscatal.2c00684.
@article{osti_1901269,
title = {Disordered, Sub-Nanometer Ru Structures on CeO[subscript 2] are Highly Efficient and Selective Catal},
author = {Chen, Linxiao and Meyer, Laura C. and Kovarik, Libor and Meira, Debora and Pereira-Hernandez, Xavier I. and Shi, Honghong and Khivantsev, Konstantin and Gutierrez, Oliver Y. and Szanyi, Janos},
abstractNote = {},
doi = {10.1021/acscatal.2c00684},
url = {https://www.osti.gov/biblio/1901269}, journal = {ACS Catal.},
number = (8),
volume = 12,
place = {United States},
year = {2022},
month = {4}
}

Works referenced in this record:

Production, use, and fate of all plastics ever made
journal, July 2017


Accumulation and fragmentation of plastic debris in global environments
journal, July 2009

  • Barnes, David K. A.; Galgani, Francois; Thompson, Richard C.
  • Philosophical Transactions of the Royal Society B: Biological Sciences, Vol. 364, Issue 1526
  • https://doi.org/10.1098/rstb.2008.0205

Olefins from polyolefins and mixed plastics by pyrolysis
journal, April 1995


Catalytic pyrolysis of polyethylene
journal, March 2002


Catalytical and thermal pyrolysis of polyolefins
journal, May 2007


Upcycling Single-Use Polyethylene into High-Quality Liquid Products
journal, September 2019


Catalytic upcycling of high-density polyethylene via a processive mechanism
journal, October 2020


Polyethylene upcycling to long-chain alkylaromatics by tandem hydrogenolysis/aromatization
journal, October 2020


Non-thermal plasma-assisted hydrogenolysis of polyethylene to light hydrocarbons
journal, February 2021


Hydrogenolysis of Linear Low-Density Polyethylene during Heterogeneous Catalytic Hydrogen–Deuterium Exchange
journal, July 2020


Towards the Circular Economy: Converting Aromatic Plastic Waste Back to Arenes over a Ru/Nb 2 O 5 Catalyst
journal, January 2021


Conversion of Polyolefin Waste to Liquid Alkanes with Ru-Based Catalysts under Mild Conditions
journal, December 2020


Low-temperature catalytic upgrading of waste polyolefinic plastics into liquid fuels and waxes
journal, May 2021


Polypropylene Plastic Waste Conversion to Lubricants over Ru/TiO 2 Catalysts
journal, June 2021


Hydrogenolysis of Polypropylene and Mixed Polyolefin Plastic Waste over Ru/C to Produce Liquid Alkanes
journal, July 2021


Polyethylene Hydrogenolysis at Mild Conditions over Ruthenium on Tungstated Zirconia
journal, August 2021


Effect of reaction conditions on the hydrogenolysis of polypropylene and polyethylene into gas and liquid alkanes
journal, January 2022


Thermally stable single-atom platinum-on-ceria catalysts via atom trapping
journal, July 2016


Activation of surface lattice oxygen in single-atom Pt/CeO 2 for low-temperature CO oxidation
journal, December 2017


Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on alumina
journal, September 2014


Mechanistic Pathways for Methylcyclohexane Hydrogenolysis over Supported Ir Catalysts
journal, August 2014


Catalytic Consequences of Particle Size and Chloride Promotion in the Ring-Opening of Cyclopentane on Pt/Al 2 O 3
journal, January 2013


Influence of the hydrocarbon structure on the hydrogenolysis of alkanes over rhodium/alumina catalysts
journal, April 1987


Effect of Various Pretreatments on the Structure and Properties of Ruthenium Catalysts
journal, June 1996


Effects of Chain Length on the Mechanism and Rates of Metal-Catalyzed Hydrogenolysis of n -Alkanes
journal, April 2016


Metal-Catalyzed C–C Bond Cleavage in Alkanes: Effects of Methyl Substitution on Transition-State Structures and Stability
journal, June 2014


Transition-State Enthalpy and Entropy Effects on Reactivity and Selectivity in Hydrogenolysis of n -Alkanes
journal, November 2013


Regioselectivity and Reaction Mechanism of Ru-Catalyzed Hydrogenolysis of Squalane and Model Alkanes
journal, November 2016


Relation between Crystallite Size and Dispersion on Supported Metal Catalysts
journal, October 1997


Estimation of mean size and shape of small metal particles by EXAFS
journal, January 1999


Hydrogenation of CO2 to formic acid on supported ruthenium catalysts
journal, February 2011


Alkali-Stabilized Pt-OHx Species Catalyze Low-Temperature Water-Gas Shift Reactions
journal, September 2010


Mild metal-catalyzed C–H activation: examples and concepts
journal, January 2016


Carbon-hydrogen and hydrogen-hydrogen activation in transition metal complexes and on surfaces
journal, April 1984


Tailoring the Shape of Metal Ad-Particles by Doping the Oxide Support
journal, October 2011


Gold Supported on Thin Oxide Films: From Single Atoms to Nanoparticles
journal, August 2008


Three-Site Model for Hydrogen Adsorption on Supported Platinum Particles:  Influence of Support Ionicity and Particle Size on the Hydrogen Coverage
journal, February 2005

  • Oudenhuijzen, Michiel K.; van Bokhoven, Jeroen A.; Miller, Jeffrey T.
  • Journal of the American Chemical Society, Vol. 127, Issue 5
  • https://doi.org/10.1021/ja045286c

Carboxyl intermediate formation via an in situ-generated metastable active site during water-gas shift catalysis
journal, September 2019


Hydrogenolysis of alkanes. Part 3.—Hydrogenolysis of n-hexane and methylcyclopentane over variously treated Ru/TiO2 catalysts
journal, January 1986

  • Burch, Robert; Bond, Geoffrey C.; Rajaram, Raj R.
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 82, Issue 6
  • https://doi.org/10.1039/f19868201985