skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Sulfonated Poly(arylene ether sulfone) Multi-Block Copolymers with Selectively Cross-Linked Domains

Journal Article · · ACS Appl. Polym. Mater.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
Journal Information:
ACS Appl. Polym. Mater., Vol. 4, Issue (10)
Country of Publication:
United States

References (60)

Highly Proton Conducting Polyelectrolyte Membranes with Unusual Water Swelling Behavior Based on Triptycene-containing Poly(arylene ether sulfone) Multiblock Copolymers journal December 2017
Alternative Polymer Systems for Proton Exchange Membranes (PEMs) journal October 2004
Solid polymer electrolyte membranes for fuel cell applications—a review journal August 2005
A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research journal April 2011
Progression from Polyimide to Polyimide Composite in Proton-Exchange Membrane Fuel Cell: A Review journal January 2017
Soluble sulfonated naphthalenic polyimides as materials for proton exchange membranes journal January 2001
Aliphatic/Aromatic Polyimide Ionomers as a Proton Conductive Membrane for Fuel Cell Applications journal February 2006
Sulfonated PEEK-based polymers in PEMFC and DMFC applications: A review journal October 2012
Mechanically robust and highly methanol-resistant sulfonated poly(ether ether ketone)/poly(vinylidene fluoride) nanofiber composite membranes for direct methanol fuel cells journal December 2019
Synthesis and characterization of aromatic poly(ether sulfone)s containing pendant sodium sulfonate groups journal March 1993
Poly(Arylene Ether Sulfone) Copolymers and Related Systems from Disulfonated Monomer Building Blocks: Synthesis, Characterization, and Performance - A Topical Review journal April 2005
Hydrophilic–hydrophobic multiblock copolymers based on poly(arylene ether sulfone) via low-temperature coupling reactions for proton exchange membrane fuel cells journal February 2008
Synthesis and characterization of multiblock copolymers based on hydrophilic disulfonated poly(arylene ether sulfone) and hydrophobic partially fluorinated poly(arylene ether ketone) for fuel cell applications: Synthesis and Characterization of Multiblock Copolymers journal November 2009
Improving the Overall Characteristics of Proton Exchange MembranesviaNanophase Separation Technologies: A Progress Review journal February 2017
Synthesis and characterization of crosslinked sulfonated poly(arylene ether sulfone) membranes for DMFC applications journal June 2009
Preparation and properties of UV irradiation-induced crosslinked sulfonated poly(ether ether ketone) proton exchange membranes journal January 2009
Cross-Linked Sulfonated Poly(arylene ether sulfone) Containing a Flexible and Hydrophobic Bishydroxy Perfluoropolyether Cross-Linker for High-Performance Proton Exchange Membrane journal June 2018
Preparation and properties of epoxy-based cross-linked sulfonated poly(arylene ether ketone) proton exchange membrane for direct methanol fuel cell applications journal June 2010
Improved performance of acid-base composite of phosphonic acid functionalized polysulfone and triazolyl functionalized polysulfone for PEM fuel cells journal February 2017
Facile preparation of blend proton exchange membranes with highly sulfonated poly(arylene ether) and poly(arylene ether sulfone) bearing dense triazoles journal August 2018
Sulfonated polyaryletherketone with pendant benzimidazole groups for proton exchange membranes journal March 2020
High performance blend membranes based on sulfonated poly(arylene ether sulfone) and poly(p-benzimidazole) for PEMFC applications journal September 2015
Modification of polyethersulfone membranes – A review of methods journal January 2013
Poly(arylene ether sulfone) proton exchange membranes with flexible acid side chains journal July 2012
Tetra-alkylsulfonate functionalized poly(aryl ether) membranes with nanosized hydrophilic channels for efficient proton conduction journal January 2020
Constructing Amino-Functionalized Flower-like Metal–Organic Framework Nanofibers in Sulfonated Poly(ether sulfone) Proton Exchange Membrane for Simultaneously Enhancing Interface Compatibility and Proton Conduction journal September 2019
Preparation and properties of cross-linked sulfonated poly(arylene ether sulfone)/sulfonated polyimide blend membranes for fuel cell application journal March 2010
Enhanced performance of proton-conducting poly(arylene ether sulfone)s via multiple alkylsulfonated side-chains and block copolymer structures journal March 2021
Multiblock sulfonated–fluorinated poly(arylene ether)s for a proton exchange membrane fuel cell journal May 2006
Synthesis and characterization of partially fluorinated hydrophobic–hydrophilic multiblock copolymers containing sulfonate groups for proton exchange membrane journal October 2007
Partly fluorinated poly(arylene ether ketone sulfone) hydrophilic–hydrophobic multiblock copolymers for fuel cell membranes journal April 2012
Sulfonated poly(arylene sulfone) multiblock copolymers for proton exchange membrane fuel cells journal June 2014
Synthesis and Characterization of Phenolphthalein-based Poly(arylene ether sulfone) Hydrophilic−Hydrophobic Multiblock Copolymers for Proton Exchange Membranes journal December 2010
Reinforcement of Highly Proton Conducting Multi-Block Copolymers by Online Crosslinking journal February 2014
1,2,4-Triazole functionalized poly(arylene ether ketone) for high temperature proton exchange membrane with enhanced oxidative stability journal January 2018
Multi-block sulfonated poly(arylene ether nitrile) polymers bearing oligomeric benzotriazole pendants with exceptionally high H2/O2 fuel cell performance journal October 2018
Novel side-chain-type cardo poly(aryl ether sulfone) bearing pendant sulfoalkyl groups for proton exchange membranes journal February 2011
Cardo polyarylates with phthalimidine groups journal October 1974
Linear condensation polymers from phenolphthalein and related compounds journal October 1964
Phenolphthalein-based cardo poly(arylene ether sulfone): Preparation and application to separation membranes journal December 2012
Synthesis, properties, and gas permeation performance of cardo poly(arylene ether sulfone)s containing phthalimide side groups journal January 2007
Phenolphthalein-based Poly(arylene ether sulfone nitrile)s Multiblock Copolymers As Anion Exchange Membranes for Alkaline Fuel Cells journal April 2015
Enhanced performance of anion exchange membranes via crosslinking of ion cluster regions for fuel cells journal September 2016
Side-chain-type phenolphthalein-based poly(arylene ether sulfone nitrile)s anion exchange membrane for fuel cells journal March 2016
Comparison of Single-Ion Conducting Polymer Gel Electrolytes for Sodium, Potassium, and Calcium Batteries: Influence of Polymer Chemistry, Cation Identity, Charge Density, and Solvent on Conductivity journal February 2020
Disulfonated Poly(arylene ether sulfone) Random Copolymers Containing Hierarchical Iptycene Units for Proton Exchange Membranes journal August 2020
Synthesis and characterization of poly(aryl ether ketone) ionomers with sulfonic acid groups on pendant aliphatic chains for proton-exchange membrane fuel cells journal January 2010
New functionalized poly(arylene-ether ketone)s and their use as modifiers for bismaleimide resin journal April 1993
Proton conducting electrolyte membranes derived from novel branched sulfonated poly(ether ether ketone)s with benzimidazole sulfonic acid pendants via thiol-ene click chemistry journal December 2013
Propenyl ethers. I. The synthesis of propenyl ether monomers journal May 1993
High methanol resistant polyelectrolyte membrane based on semi-crystalline Poly(ether ketone) with densely sulfonated side chain for direct methanol fuel cell journal January 2021
Poly(arlyene ether sulfone) based semi-interpenetrating polymer network membranes containing cross-linked poly(vinyl phosphonic acid) chains for fuel cell applications at high temperature and low humidity conditions journal October 2015
Behavior of Raipore Radiation‐Grafted Polymer Membranes in  H 2 /  O 2 Fuel Cells journal March 1998
EPR investigation of HO/ radical initiated degradation reactions of sulfonated aromatics as model compounds for fuel cell proton conducting membranes journal January 1999
In situ EPR investigation of polymer electrolyte membrane degradation in fuel cell applications journal March 2004
Synthesis of poly(arylene ether sulfone)s with locally and densely sulfonated pentiptycene pendants as highly conductive polymer electrolyte membranes journal December 2011
Aromatic Poly(ether ketone)s with Pendant Sulfonic Acid Phenyl Groups Prepared by a Mild Sulfonation Method for Proton Exchange Membranes journal February 2007
Hydrocarbon-Based Polymer Electrolyte Membranes: Importance of Morphology on Ion Transport and Membrane Stability journal March 2017
Proton Conductivity:  Materials and Applications journal January 1996
Synthesis and characterization of multiblock semi-crystalline hydrophobic poly(ether ether ketone)–hydrophilic disulfonated poly(arylene ether sulfone) copolymers for proton exchange membranes journal July 2012