skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Elucidating the Effect of Borate Additive in High-Voltage Electrolyte for Li-Rich Layered Oxide Mate

Journal Article · · Adv. Eng. Mater.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; INDUSTRY
Journal Information:
Adv. Eng. Mater., Vol. 12, Issue (11)
Country of Publication:
United States

References (90)

An Effectively Activated Hierarchical Nano-/Microspherical Li 1.2 Ni 0.2 Mn 0.6 O 2 Cathode for Long-Life and High-Rate Lithium-Ion Batteries journal March 2016
Analysis of Rate-Limiting Factors in Thick Electrodes for Electric Vehicle Applications journal January 2018
Unraveling the Voltage-Fade Mechanism in High-Energy-Density Lithium-Ion Batteries: Origin of the Tetrahedral Cations for Spinel Conversion journal October 2014
Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study journal January 2011
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries journal December 2015
Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes journal December 2019
Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging journal July 2018
Correlation Between Oxygen Vacancy, Microstrain, and Cation Distribution in Lithium-Excess Layered Oxides During the First Electrochemical Cycle journal April 2013
Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2
  • Armstrong, A. Robert; Holzapfel, Michael; Novak, Petr
  • Journal of the American Chemical Scoiety, Vol. 128, Issue 26, p. 8694-8698
journal June 2006
Uncovering the roles of oxygen vacancies in cation migration in lithium excess layered oxides journal January 2014
In situ X-ray absorption spectroscopic study of Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2 journal August 2011
In situ X-ray diffraction study of the lithium excess layered oxide compound Li[Li0.2Ni0.2Mn0.6]O2 during electrochemical cycling journal January 2012
Improving cycling performance of Li-rich layered cathode materials through combination of Al2O3-based surface modification and stepwise precycling journal January 2016
The Effects of AlF[sub 3] Coating on the Performance of Li[Li[sub 0.2]Mn[sub 0.54]Ni[sub 0.13]Co[sub 0.13]]O[sub 2] Positive Electrode Material for Lithium-Ion Battery journal January 2008
Structural and Electrochemical Study of Al 2 O 3 and TiO 2 Coated Li 1.2 Ni 0.13 Mn 0.54 Co 0.13 O 2 Cathode Material Using ALD journal June 2013
Trace level doping of lithium-rich cathode materials journal January 2016
Mitigating oxygen release in anionic-redox-active cathode materials by cationic substitution through rational design journal January 2018
Retarded phase transition by fluorine doping in Li-rich layered Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2 cathode material journal June 2015
Metastability and Reversibility of Anionic Redox-Based Cathode for High-Energy Rechargeable Batteries journal March 2020
Regeneration of degraded Li-rich layered oxide materials through heat treatment-induced transition metal reordering journal March 2021
Enabling high areal capacity for Co-free high voltage spinel materials in next-generation Li-ion batteries journal October 2020
Evaluating the High-Voltage Stability of Conductive Carbon and Ethylene Carbonate with Various Lithium Salts journal December 2020
Scavenging Materials to Stabilize LiPF 6 ‐Containing Carbonate‐Based Electrolytes for Li‐Ion Batteries journal November 2018
Decomposition of LiPF 6 in High Energy Lithium-Ion Batteries Studied with Online Electrochemical Mass Spectrometry journal January 2016
Hydrolysis of LiPF 6 -Containing Electrolyte at High Voltage journal May 2021
Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review journal January 2018
The success story of graphite as a lithium-ion anode material – fundamentals, remaining challenges, and recent developments including silicon (oxide) composites journal January 2020
1,3,6-Hexanetricarbonitrile as electrolyte additive for enhancing electrochemical performance of high voltage Li-rich layered oxide cathode journal September 2017
Constructing a Protective Interface Film on Layered Lithium-Rich Cathode Using an Electrolyte Additive with Special Molecule Structure journal October 2016
Stabilizing a High-Voltage Lithium-Rich Layered Oxide Cathode with a Novel Electrolyte Additive journal July 2019
Preparation of LiBOB via rheological phase method and its application to mitigate voltage fade of Li 1.16 [Mn 0.75 Ni 0.25 ] 0.84 O 2 cathode journal January 2015
Mechanisms for electrochemical performance enhancement by the salt-type electrolyte additive, lithium difluoro(oxalato)borate, in high-voltage lithium-ion batteries journal July 2017
In Situ Construction of Uniform and Robust Cathode–Electrolyte Interphase for Li‐Rich Layered Oxides journal December 2020
Inhibition of transition metals dissolution in cobalt-free cathode with ultrathin robust interphase in concentrated electrolyte journal July 2020
Ionic liquid electrolytes for high-voltage, lithium-ion batteries journal December 2020
Fluorinated Carbonate-Based Electrolyte for High-Voltage Li(Ni 0.5 Mn 0.3 Co 0.2 )O 2 /Graphite Lithium-Ion Battery journal January 2017
Toward 5 V Lithium-Ion Battery: Exploring the Limit of Charge Cut-off Voltage of Li-Rich Layered Oxide Cathode and High-Voltage Interfacial Processes journal November 2017
Suppression of irreversible capacity loss in Li-rich layered oxide by fluorine doping journal May 2016
Effect of Using Fluorinated Ether and Sulfone as Electrolyte Solvents for Lithium Ion Batteries with Lithium-Rich Layered Cathodes and Silicon Oxide Anodes journal October 2017
Oxidatively stable fluorinated sulfone electrolytes for high voltage high energy lithium-ion batteries journal January 2017
Ethylene Carbonate-Free, Adiponitrile-Based Electrolytes Compatible with Graphite Anodes journal April 2017
Adiponitrile-based electrolytes for high voltage, graphite-based Li-ion battery journal September 2018
Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions journal January 2001
LiBOB as Salt for Lithium-Ion Batteries:A Possible Solution for High Temperature Operation journal January 2002
Electrochemical behavior of Al in a non-aqueous alkyl carbonate solution containing LiBOB salt journal December 2010
LiBOB: Is it an alternative salt for lithium ion chemistry? journal August 2005
Improving the Performance of Graphite/ LiNi 0.5 Mn 1.5 O 4 Cells at High Voltage and Elevated Temperature with Added Lithium Bis(oxalato) Borate (LiBOB) journal January 2013
Effect of Added LiBOB on High Voltage (LiNi0.5Mn1.5O4) Spinel Cathodes journal January 2011
Effect of LiBOB Additive on the Electrochemical Performance of LiCoPO 4 journal January 2012
Lithium bis(oxalate)borate additive in the electrolyte to improve Li-rich layered oxide cathode materials journal January 2020
Effect of Lithium Borate Additives on Cathode Film Formation in LiNi 0.5 Mn 1.5 O 4 /Li Cells journal May 2017
Understanding the Effect of Lithium Bis(oxalato) Borate (LiBOB) on the Structural and Electrochemical Aging of Li and Mn Rich High Capacity Li 1.2 Ni 0.16 Mn 0.56 Co 0.08 O 2 Cathodes journal January 2015
Addressing voltage decay in Li-rich cathodes by broadening the gap between metallic and anionic bands journal May 2021
Eliminating Voltage Decay of Lithium-Rich Li 1.14 Mn 0.54 Ni 0.14 Co 0.14 O 2 Cathodes by Controlling the Electrochemical Process journal March 2015
Mitigating Voltage Decay of Li-Rich Cathode Material via Increasing Ni Content for Lithium-Ion Batteries journal July 2016
Lithium- and Manganese-Rich Oxide Cathode Materials for High-Energy Lithium Ion Batteries journal August 2016
Synthesis, Structure, and Electrochemical Behavior of Li[Ni[sub x]Li[sub 1/3−2x/3]Mn[sub 2/3−x/3]]O[sub 2] journal January 2002
Understanding the Anomalous Capacity of Li / Li [ NixLi ( 1 / 3 − 2x / 3 ) Mn ( 2 / 3 − x / 3 ) ]  O2 Cells Using In Situ X-Ray Diffraction and Electrochemical Studies journal January 2002
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials journal May 2016
Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries journal April 2018
Considering Critical Factors of Li-rich Cathode and Si Anode Materials for Practical Li-ion Cell Applications journal June 2015
Understanding and Controlling Anionic Electrochemical Activity in High-Capacity Oxides for Next Generation Li-Ion Batteries journal January 2017
Fundamental interplay between anionic/cationic redox governing the kinetics and thermodynamics of lithium-rich cathodes journal December 2017
Stable cycling of high-voltage lithium metal batteries in ether electrolytes journal July 2018
Generation of Cathode Passivation Films via Oxidation of Lithium Bis(oxalato) Borate on High Voltage Spinel (LiNi 0.5 Mn 1.5 O 4 ) journal March 2014
Using a lithium bis(oxalato) borate additive to improve electrochemical performance of high-voltage spinel LiNi0.5Mn1.5O4 cathodes at 60°C journal August 2013
Structure and Interface Design Enable Stable Li-Rich Cathode journal April 2020
Local structure adaptability through multi cations for oxygen redox accommodation in Li-Rich layered oxides journal January 2020
Replacing conventional battery electrolyte additives with dioxolone derivatives for high-energy-density lithium-ion batteries journal February 2021
Optimizing interphase structure to enhance electrochemical performance of high voltage LiNi0.5Mn1.5O4 cathode via anhydride additives journal April 2021
Deciphering the lithium ion movement in lithium ion batteries: determination of the isotopic abundances of 6 Li and 7 Li journal January 2019
Increased Cycling Performance of Li-Ion Batteries by Phosphoric Acid Modified LiNi 0.5 Mn 1.5 O 4 Cathodes in the Presence of LiBOB journal July 2019
Decomposition Reactions of Anode Solid Electrolyte Interphase (SEI) Components with LiPF 6 journal October 2017
Role of Lithium Salt on Solid Electrolyte Interface (SEI) Formation and Structure in Lithium Ion Batteries journal January 2014
Long cycle life and dendrite-free lithium morphology in anode-free lithium pouch cells enabled by a dual-salt liquid electrolyte journal July 2019
Deciphering the Interface of a High‐Voltage (5 V‐Class) Li‐Ion Battery Containing Additive‐Assisted Sulfolane‐Based Electrolyte journal September 2019
Thermal Reactions of LiPF[sub 6] with Added LiBOB journal January 2007
Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries journal January 2015
Diagnosing and correcting anode-free cell failure via electrolyte and morphological analysis journal August 2020
XPS-Surface Analysis of SEI Layers on Li-Ion Cathodes: Part II. SEI-Composition and Formation inside Composite Electrodes journal January 2018
The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling journal August 2016
Lithium-Ion Conducting Electrolyte Salts for Lithium Batteries journal November 2011
Enhanced performance of Li-ion cell with LiBF4-PC based electrolyte by addition of small amount of LiBOB journal June 2006
LiBOB as Additive in LiPF[sub 6]-Based Lithium Ion Electrolytes journal January 2005
Exploring the redox decomposition of ethylene carbonate–propylene carbonate in Li-ion batteries journal January 2021
Carbon Coating Stability on High-Voltage Cathode Materials in H 2 O-Free and H 2 O-Containing Electrolyte journal January 2015
Hydrolysis of Ethylene Carbonate with Water and Hydroxide under Battery Operating Conditions journal January 2016
Theoretical Investigations on Oxidative Stability of Solvents and Oxidative Decomposition Mechanism of Ethylene Carbonate for Lithium Ion Battery Use journal December 2009
Synergistic Effect of LiPF 6 and LiBF 4 as Electrolyte Salts in Lithium-Ion Cells journal January 2017
GSAS-II : the genesis of a modern open-source all purpose crystallography software package journal March 2013