skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The role of copper crystallization and segregation toward enhanced methanol synthesis via CO[subscri

Journal Article · · Chem. Eng. J.
; ; ; ; ; ; ; ; ; ;

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; FOREIGN
OSTI ID:
1901074
Journal Information:
Chem. Eng. J., Vol. 452, Issue (3)
Country of Publication:
United States
Language:
ENGLISH

References (46)

Advances in studies of the structural effects of supported Ni catalysts for CO2 hydrogenation: from nanoparticle to single atom catalyst journal January 2022
Computational design of a metal-based frustrated Lewis pair on defective UiO-66 for CO 2 hydrogenation to methanol journal January 2020
Influence of ZrO 2 Structure and Copper Electronic State on Activity of Cu/ZrO 2 Catalysts in Methanol Synthesis from CO 2 journal September 2014
Mechanism of Methanol Synthesis on Cu through CO 2 and CO Hydrogenation journal February 2011
Improving the Cu/ZnO-Based Catalysts for Carbon Dioxide Hydrogenation to Methanol, and the Use of Methanol As a Renewable Energy Storage Media journal September 2020
Heterogeneous catalysts for production of chemicals using carbon dioxide as raw material: A review journal September 2012
Design of Interfacial Sites between Cu and Amorphous ZrO 2 Dedicated to CO 2 -to-Methanol Hydrogenation journal July 2018
Cu Species Incorporated into Amorphous ZrO 2 with High Activity and Selectivity in CO 2 -to-Methanol Hydrogenation journal February 2018
Optimizing Binding Energies of Key Intermediates for CO 2 Hydrogenation to Methanol over Oxide-Supported Copper journal September 2016
Inverse ZrO2/Cu as a highly efficient methanol synthesis catalyst from CO2 hydrogenation journal November 2020
Structure–activity relationships of Cu–ZrO 2 catalysts for CO 2 hydrogenation to methanol: interaction effects and reaction mechanism journal January 2017
In Situ Characterization of Cu/CeO 2 Nanocatalysts for CO 2 Hydrogenation: Morphological Effects of Nanostructured Ceria on the Catalytic Activity journal May 2018
Insights into the methanol synthesis mechanism via CO2 hydrogenation over Cu-ZnO-ZrO2 catalysts: Effects of surfactant/Cu-Zn-Zr molar ratio journal October 2020
Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry journal November 2017
Effect of operating parameters on H2/CO2 conversion to methanol over Cu-Zn oxide supported on ZrO2 polymorph catalysts: Characterization and kinetics journal January 2022
Thermodynamic Analysis of Chemical and Phase Equilibria in CO 2 Hydrogenation to Methanol, Dimethyl Ether, and Higher Alcohols journal March 2018
First-principles codes for computational crystallography in the Quantum-ESPRESSO package journal May 2005
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials journal September 2009
Next-Generation Nonlocal van der Waals Density Functional journal July 2020
CO2 hydrogenation to methanol over Cu/ZnO/ZrO2 catalysts prepared by precipitation-reduction method journal August 2016
Hierarchical N-Doped CuO/Cu Composites Derived from Dual-Ligand Metal–Organic Frameworks as Cost-Effective Catalysts for Low-Temperature CO Oxidation journal October 2021
Inside the reaction mechanism of direct CO2 conversion to DME over zeolite-based hybrid catalysts journal October 2021
Mechanism and catalytic performance for direct dimethyl ether synthesis by CO2 hydrogenation over CuZnZr/ferrierite hybrid catalyst journal June 2020
Sol–gel synthesis of mesoporous spherical zirconia journal January 2015
Fabrication of Porous ZrO2 Nanostructures with Controlled Crystalline Phases and Structures via a Facile and Cost-Effective Hydrothermal Approach journal December 2015
Tailoring the surface area and the acid–base properties of ZrO2 for biodiesel production from Nannochloropsis sp. journal November 2019
Interaction of Carbon Dioxide with the Surface of Zirconia Polymorphs journal June 1998
Surface interaction of CO2/H2 mixture on mesoporous ZrO2: Effect of crystalline polymorph phases journal December 2019
Highly selective hydrogenation of CO2 to methanol over CuO–ZnO–ZrO2 catalysts prepared by a surfactant-assisted co-precipitation method journal April 2015
Tuning of catalytic CO2 hydrogenation by changing composition of CuO–ZnO–ZrO2 catalysts journal June 2016
The influence of La doping on the catalytic behavior of Cu/ZrO2 for methanol synthesis from CO2 hydrogenation journal July 2011
Catalytic reduction of CO 2 by H 2 for synthesis of CO, methanol and hydrocarbons: challenges and opportunities journal January 2016
CO 2 Hydrogenation at Atmospheric Pressure and Low Temperature Using Plasma-Enhanced Catalysis over Supported Cobalt Oxide Catalysts journal November 2020
Catalytic hydrogenation of CO 2 into methanol and dimethyl ether over Cu-X/V-Al PILC (X = Ce and Nb) catalysts journal July 2017
How oxide carriers control the catalytic functionality of the Cu–ZnO system in the hydrogenation of CO2 to methanol journal July 2013
Recent Advances in Carbon Dioxide Hydrogenation to Methanol via Heterogeneous Catalysis journal February 2020
CO2 capture via catalytic hydrogenation to methanol: Thermodynamic limit vs. ‘kinetic limit’ journal August 2011
CO 2 Hydrogenation to Methanol over ZrO 2 -Containing Catalysts: Insights into ZrO 2 Induced Synergy journal July 2019
In situ EXAFS studies of copper on ZrO2 during catalytic hydrogenation of CO2 journal June 2005
XPS, XANES and EXAFS investigations of CuO/ZnO/Al2O3/ZrO2 mixed oxide catalysts journal April 2002
A highly selective and stable ZnO-ZrO 2 solid solution catalyst for CO 2 hydrogenation to methanol journal October 2017
Time evolution of the CO2 hydrogenation to fuels over Cu-Zr-SBA-15 catalysts journal June 2018
Role of Hydrogen Spillover in Methanol Synthesis over Cu/ZrO2 journal July 2000
CO 2 -to-Methanol Hydrogenation on Zirconia-Supported Copper Nanoparticles: Reaction Intermediates and the Role of the Metal-Support Interface journal January 2017
CO2 fixation into methanol at Cu/ZrO2 interface from first principles kinetic Monte Carlo journal April 2009
The Role of the Oxide Component in the Development of Copper Composite Catalysts for Methanol Synthesis journal May 2013

Similar Records

The role of copper crystallization and segregation toward enhanced methanol synthesis via CO2 hydrogenation over CuZrO2 catalysts: A combined experimental and computational study
Journal Article · 2022 · Chemical Engineering Journal · OSTI ID:1901074
+8 more
Hydrogenation of CO2 on ZnO/Cu(100) and ZnO/Cu(111) Catalysts: Role of Copper Structure and Metal–Oxide Interface in Methanol Synthesis
Journal Article · 2017 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry · OSTI ID:1901074
+8 more
Enhanced catalytic performance of Zr modified CuO/ZnO/Al2O3 catalyst for methanol and DME synthesis via CO2 hydrogenation
Journal Article · 2019 · Journal of CO2 Utilization · OSTI ID:1901074
+7 more

Related Subjects