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Title: Solution-Grown Ternary Semiconductors: Nanostructuring and Stereoelectronic Lone Pair Distortions in

Journal Article · · Chem. Mater.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; National Science Foundation (NSF)
OSTI ID:
1900956
Journal Information:
Chem. Mater., Vol. 34, Issue (16)
Country of Publication:
United States
Language:
ENGLISH

References (76)

High thermoelectric figure of merit in heavy hole dominated PbTe journal January 2011
Nanostructured Thermoelectrics: The New Paradigm? journal February 2010
Giant anharmonic phonon scattering in PbTe journal June 2011
Resonant bonding leads to low lattice thermal conductivity journal April 2014
Contrasting SnTe–NaSbTe 2 and SnTe–NaBiTe 2 Thermoelectric Alloys: High Performance Facilitated by Increased Cation Vacancies and Lattice Softening journal July 2020
Absence of Nanostructuring in NaPb m SbTe m +2 : Solid Solutions with High Thermoelectric Performance in the Intermediate Temperature Regime journal April 2018
The role of electronegativity in the thermoelectric performance of GeTe–I–V–VI2 solid solutions journal January 2021
Cubic AgPbmSbTe2+m: Bulk Thermoelectric Materials with High Figure of Merit journal February 2004
Lead-Free Thermoelectrics: High Figure of Merit in p-type AgSnmSbTem+2 journal December 2011
Enhanced Figure-of-Merit in Se-Doped p-Type AgSbTe 2 Thermoelectric Compound journal October 2010
Contrasting the Role of Mg and Ba Doping on the Microstructure and Thermoelectric Properties of p-Type AgSbSe 2 journal October 2015
Ultrahigh Average Thermoelectric Figure of Merit, Low Lattice Thermal Conductivity and Enhanced Microhardness in Nanostructured (GeTe) x (AgSbSe 2 ) 100− x journal May 2017
Enhancement of thermoelectric properties by Na doping in Te-free p-type AgSbSe 2 journal January 2015
High Thermoelectric Figure of Merit and Nanostructuring in Bulk p-type Na1−xPbmSbyTem+2 journal June 2006
Intrinsically Minimal Thermal Conductivity in Cubic IVVI2 Semiconductors journal July 2008
Enhanced atomic ordering leads to high thermoelectric performance in AgSbTe 2 journal February 2021
Phase Stability and Ordering in Rock Salt-Based Thermoelectrics: NaSbX 2 , AgSbX 2 , and Their Alloys with PbX and SnX (X = S, Se, Te) journal October 2019
Surface Chemistry of Ternary Nanocrystals: Engineering the Deposition of Conductive NaBiS 2 Films journal June 2020
Colloidal AgBiS2 nanocrystals with reduced recombination yield 6.4% power conversion efficiency in solution-processed solar cells journal September 2020
Candidate Inorganic Photovoltaic Materials from Electronic Structure-Based Optical Absorption and Charge Transport Proxies journal February 2019
Cubic AgBiS2 Colloidal Nanocrystals for Solar Cells journal April 2020
Electronic, optical, and thermoelectric properties of sodium pnictogen chalcogenides: A first principles study journal October 2020
Synthesis and characterization of NaSbS 2 thin film for potential photodetector and photovoltaic application journal April 2017
An experimental and theoretical study into NaSbS 2 as an emerging solar absorber journal January 2019
(Li,Na)SbS2 as a promising solar absorber material: A theoretical investigation journal April 2021
Electronic Properties, Screening, and Efficient Carrier Transport in NaSbS 2 journal February 2017
Photoelectric and optical properties of thin films of ternary chalcogenides of the form MeISbX 2 VI journal April 1975
Sodium antimony sulfide (NaSbS 2 ): Turning an unexpected impurity into a promising, environmentally friendly novel solar absorber material journal November 2016
Computational Screening of Indirect-Gap Semiconductors for Potential Photovoltaic Absorbers journal May 2019
Eco-Friendly NaSbS2 Quantum Dot-Sensitized Solar Cells journal July 2018
Earth-abundant photovoltaic semiconductor NaSbS2 in the rocksalt-derived structure: A first-principles study journal June 2019
Structural, stability and thermoelectric properties for the monoclinic phase of NaSbS2 and NaSbSe2: A theoretical investigation journal September 2019
Cubic NaSbS 2 as an Ionic–Electronic Coupled Semiconductor for Switchable Photovoltaic and Neuromorphic Device Applications journal November 2019
Origin of Ultralow Thermal Conductivity in n-Type Cubic Bulk AgBiS 2 : Soft Ag Vibrations and Local Structural Distortion Induced by the Bi 6s 2 Lone Pair journal June 2018
Local Structure and Influence of Sb Substitution on the Structure–Transport Properties in AgBiSe 2 journal June 2019
Local Symmetry Breaking Suppresses Thermal Conductivity in Crystalline Solids journal February 2022
Soluble Semiconductors AAsSe 2 (A = Li, Na) with a Direct-Band-Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study journal March 2010
Structure Tuning, Strong Second Harmonic Generation Response, and High Optical Stability of the Polar Semiconductors Na1–xKxAsQ2 journal October 2021
Ternary Zinc Antimonides Unlocked Using Hydride Synthesis journal June 2021
From NaZn 4 Sb 3 to HT -Na 1– x Zn 4– y Sb 3 : Panoramic Hydride Synthesis, Structural Diversity, and Thermoelectric Properties journal October 2019
Rapid Phase Screening via Hydride Route: A Discovery of K 8– x Zn 18+3 x Sb 16 journal November 2018
Clathrate XI K 58 Zn 122 Sb 207 : A New Branch on the Clathrate Family Tree journal October 2020
Facile Synthesis of Ba 1– x K x Fe 2 As 2 Superconductors via Hydride Route journal November 2014
Got LiZnP? Solution phase synthesis of filled tetrahedral semiconductors in the nanoregime journal January 2016
Expanding the I–II–V Phase Space: Soft Synthesis of Polytypic Ternary and Binary Zinc Antimonides journal August 2018
Ternary ACd 4 P 3 (A = Na, K) Nanostructures via a Hydride Solution-Phase Route journal July 2021
Solution-Grown Sodium Bismuth Dichalcogenides: Toward Earth-Abundant, Biocompatible Semiconductors journal February 2018
Synthesis of Colloidal Metal Nanocrystals: A Comprehensive Review on the Reductants journal July 2018
A General Synthesis Strategy for Monodisperse Metallic and Metalloid Nanoparticles (In, Ga, Bi, Sb, Zn, Cu, Sn, and Their Alloys) via in Situ Formed Metal Long-Chain Amides journal January 2015
The rise of the X-ray atomic pair distribution function method: a series of fortunate events journal April 2019
The crystal structure of antimony selenide, Sb2Se3 journal February 1957
Influence of the stereochemically active bismuth lone pair structure on ferroelectricity and photocalytic activity of Aurivillius phase Bi2WO6 journal January 2011
Structure and Bonding in SnWO 4 , PbWO 4 , and BiVO 4 :  Lone Pairs vs Inert Pairs journal May 2007
Chemistry, Structure, and Function of Lone Pairs in Extended Solids journal March 2022
Ligand Exchange and the Stoichiometry of Metal Chalcogenide Nanocrystals: Spectroscopic Observation of Facile Metal-Carboxylate Displacement and Binding
  • Anderson, Nicholas C.; Hendricks, Mark P.; Choi, Joshua J.
  • Journal of the American Chemical Society, Vol. 135, Issue 49, p. 18536-18548 https://doi.org/10.1021/ja4086758
journal November 2013
How Robust are Semiconductor Nanorods? Investigating the Stability and Chemical Decomposition Pathways of Photoactive Nanocrystals journal June 2014
Characterization of Primary Amine Capped CdSe, ZnSe, and ZnS Quantum Dots by FT-IR: Determination of Surface Bonding Interaction and Identification of Selective Desorption journal June 2011
Surface Doping Quantum Dots with Chemically Active Native Ligands: Controlling Valence without Ligand Exchange journal October 2012
Multiple-Quantum Magic-Angle Spinning NMR: A New Method for the Study of Quadrupolar Nuclei in Solids journal December 1995
Two-Dimensional Multiple-Quantum MAS NMR of Quadrupolar Nuclei: A Comparison of Methods journal September 1997
Dynamic Stereochemical Activity of the Sn 2+ Lone Pair in Perovskite CsSnBr 3 journal September 2016
PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions journal March 2013
PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals journal July 2007
NMR nomenclature: nuclear spin properties and conventions for chemical shifts. IUPAC Recommendations 2001. International Union of Pure and Applied Chemistry. Physical Chemistry Division. Commission on Molecular Structure and Spectroscopy journal January 2002
Rotary resonance echo double resonance for measuring heteronuclear dipolar coupling under MAS journal December 2006
Through-space R3-HETCOR experiments between spin-1/2 and half-integer quadrupolar nuclei in solid-state NMR journal June 2007
Proton detection of MAS solid-state NMR spectra of half-integer quadrupolar nuclei journal July 2017
Proton-Selective 17 O− 1 H Distance Measurements in Fast Magic-Angle-Spinning Solid-State NMR Spectroscopy for the Determination of Hydrogen Bond Lengths journal November 2006
Sensitivity enhancement of the central transition NMR signal of quadrupolar nuclei under magic-angle spinning journal September 2000
A Simple Technique for Determining Nuclear Quadrupole Coupling Constants with RAPT Solid-State NMR Spectroscopy journal May 2002
Population transfer HMQC for half-integer quadrupolar nuclei journal March 2015
Rotational-Echo, Double-Resonance NMR book January 2007
13C/14N heteronuclear multiple-quantum correlation with rotary resonance and REDOR dipolar recoupling journal January 2007
Triple, quintuple and higher order multiple quantum MAS NMR of quadrupolar nuclei journal February 1998
BaGe 2 Pn 2 (Pn = P, As): Two Congruent-Melting Non-chalcopyrite Pnictides as Mid- and Far-Infrared Nonlinear Optical Materials Exhibiting Large Second Harmonic Generation Effects journal November 2019
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996