Operando Elucidation of Electrocatalytic and Redox Mechanisms on a 2D Metal Organic Framework Cataly

Ross, R. Dominic; Sheng, Hongyuan; Ding, Yujia; Janes, Aurora N.; Feng, Dawei; Schmidt, J.R.; Segre, Carlo U.; Jin, Song

doi:10.1021/jacs.2c06810

Operando Elucidation of Electrocatalytic and Redox Mechanisms on a 2D Metal Organic Framework Cataly

Journal Article · 01 August 2022 · J. Am. Chem. Soc.

DOI:https://doi.org/10.1021/jacs.2c06810· OSTI ID:1900817

Ross, R. Dominic; Sheng, Hongyuan; Ding, Yujia; Janes, Aurora N.; Feng, Dawei; Schmidt, J.R.; Segre, Carlo U.; Jin, Song

Research Organization:: Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)

Sponsoring Organization:: DOE - Office Of Science; NSF

OSTI ID:: 1900817

Journal Information:: J. Am. Chem. Soc., Journal Name: J. Am. Chem. Soc. Journal Issue: (34) Vol. 144

Country of Publication:: United States

Language:: ENGLISH

References (59)

Metal–Organic Frameworks in Heterogeneous Catalysis: Recent Progress, New Trends, and Future Perspectives Bavykina, Anastasiya; Kolobov, Nikita; Khan, Il Son Chemical Reviews, Vol. 120, Issue 16 https://doi.org/10.1021/acs.chemrev.9b00685	journal	March 2020
Hydrogen peroxide generation from O2 electroreduction for environmental remediation: A state-of-the-art review Zhou, Wei; Meng, Xiaoxiao; Gao, Jihui Chemosphere, Vol. 225 https://doi.org/10.1016/j.chemosphere.2019.03.042	journal	June 2019
Computational screening of two-dimensional coordination polymers as efficient catalysts for oxygen evolution and reduction reaction Gao, Guoping; Waclawik, Eric R.; Du, Aijun Journal of Catalysis, Vol. 352 https://doi.org/10.1016/j.jcat.2017.06.032	journal	August 2017
Conductive two-dimensional metal–organic frameworks as multifunctional materials Ko, Michael; Mendecki, Lukasz; Mirica, Katherine A. Chemical Communications, Vol. 54, Issue 57 https://doi.org/10.1039/C8CC02871K	journal	January 2018
Unpaired 3d Electrons on Atomically Dispersed Cobalt Centres in Coordination Polymers Regulate both Oxygen Reduction Reaction (ORR) Activity and Selectivity for Use in Zinc–Air Batteries Lian, Yuebin; Yang, Wenjuan; Zhang, Chufeng Angewandte Chemie International Edition, Vol. 59, Issue 1 https://doi.org/10.1002/anie.201910879	journal	November 2019
Oxygen Evolution Reaction Dynamics, Faradaic Charge Efficiency, and the Active Metal Redox States of Ni–Fe Oxide Water Splitting Electrocatalysts Görlin, Mikaela; Chernev, Petko; Ferreira de Araújo, Jorge Journal of the American Chemical Society, Vol. 138, Issue 17 https://doi.org/10.1021/jacs.6b00332	journal	April 2016
Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two‐Electron Oxygen Reduction Reaction Wang, Nan; Ma, Shaobo; Zuo, Pengjian Advanced Science, Vol. 8, Issue 15 https://doi.org/10.1002/advs.202100076	journal	May 2021
Hexaaminobenzene as a building block for a Family of 2D Coordination Polymers Lahiri, Nabajit; Lotfizadeh, Neda; Tsuchikawa, Ryuichi Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b09889	journal	December 2016
A reticular chemistry guide for the design of periodic solids Jiang, Hao; Alezi, Dalal; Eddaoudi, Mohamed Nature Reviews Materials, Vol. 6, Issue 6 https://doi.org/10.1038/s41578-021-00287-y	journal	March 2021
pH Dependent Reversible Formation of a Binuclear Ni2 Metal-Center within a Peptide Scaffold Keegan, Brenna C.; Ocampo, Daniel; Shearer, Jason Inorganics, Vol. 7, Issue 7 https://doi.org/10.3390/inorganics7070090	journal	July 2019
Enabling Direct H2O2 Production in Acidic Media through Rational Design of Transition Metal Single Atom Catalyst Gao, Jiajian; Yang, Hong bin; Huang, Xiang Chem, Vol. 6, Issue 3 https://doi.org/10.1016/j.chempr.2019.12.008	journal	March 2020
Highly selective oxygen reduction to hydrogen peroxide on transition metal single atom coordination Jiang, Kun; Back, Seoin; Akey, Austin J. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11992-2	journal	September 2019
Electrically Conductive Metal–Organic Frameworks Xie, Lilia S.; Skorupskii, Grigorii; Dincă, Mircea Chemical Reviews https://doi.org/10.1021/acs.chemrev.9b00766	journal	April 2020
Tailoring Acidic Oxygen Reduction Selectivity on Single-Atom Catalysts via Modification of First and Second Coordination Spheres Tang, Cheng; Chen, Ling; Li, Haijing Journal of the American Chemical Society, Vol. 143, Issue 20 https://doi.org/10.1021/jacs.1c03135	journal	May 2021
Molecule Confined Isolated Metal Sites Enable the Electrocatalytic Synthesis of Hydrogen Peroxide Li, Xiaogang; Tang, Shasha; Dou, Shuo Advanced Materials https://doi.org/10.1002/adma.202104891	journal	September 2021
Compositionally Tuned Trimetallic Thiospinel Catalysts for Enhanced Electrosynthesis of Hydrogen Peroxide and Built-In Hydroxyl Radical Generation Ross, R. Dominic; Sheng, Hongyuan; Parihar, Aditya ACS Catalysis, Vol. 11, Issue 20 https://doi.org/10.1021/acscatal.1c03349	journal	September 2021
Following ORR intermediates adsorbed on a Pt cathode catalyst during break-in of a PEM fuel cell by in operando X-ray absorption spectroscopy Ramaker, D. E.; Korovina, A.; Croze, V. Phys. Chem. Chem. Phys., Vol. 16, Issue 27 https://doi.org/10.1039/C4CP00192C	journal	January 2014
Electrocatalytic Oxygen Reduction to Hydrogen Peroxide: From Homogeneous to Heterogeneous Electrocatalysis Wang, Yulin; Waterhouse, Geoffrey I. N.; Shang, Lu Advanced Energy Materials, Vol. 11, Issue 15 https://doi.org/10.1002/aenm.202003323	journal	December 2020
Regulating Electrocatalytic Oxygen Reduction Activity of a Metal Coordination Polymer via d–π Conjugation Ni, Youxuan; Lin, Liu; Shang, Yuxin Angewandte Chemie International Edition, Vol. 60, Issue 31 https://doi.org/10.1002/anie.202104494	journal	June 2021
Efficient Electrochemical Hydrogen Peroxide Production from Molecular Oxygen on Nitrogen-Doped Mesoporous Carbon Catalysts Sun, Yanyan; Sinev, Ilya; Ju, Wen ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.7b03464	journal	February 2018
In Situ / Operando Studies for Designing Next-Generation Electrocatalysts Zhu, Yanping; Wang, Jiali; Chu, Hang ACS Energy Letters, Vol. 5, Issue 4 https://doi.org/10.1021/acsenergylett.0c00305	journal	March 2020
In Situ / Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy Timoshenko, Janis; Roldan Cuenya, Beatriz Chemical Reviews, Vol. 121, Issue 2 https://doi.org/10.1021/acs.chemrev.0c00396	journal	September 2020
Intrinsic Activity of Metal Centers in Metal–Nitrogen–Carbon Single-Atom Catalysts for Hydrogen Peroxide Synthesis Liu, Chang; Li, Hao; Liu, Fei Journal of the American Chemical Society, Vol. 142, Issue 52 https://doi.org/10.1021/jacs.0c10636	journal	December 2020
Strongly Coupled Cobalt Diselenide Monolayers for Selective Electrocatalytic Oxygen Reduction to H ₂ O ₂ under Acidic Conditions Zhang, Xiao‐Long; Su, Xiaozhi; Zheng, Ya‐Rong Angewandte Chemie International Edition, Vol. 60, Issue 52 https://doi.org/10.1002/anie.202111075	journal	October 2021
Scalable neutral H2O2 electrosynthesis by platinum diphosphide nanocrystals by regulating oxygen reduction reaction pathways Li, Hui; Wen, Peng; Itanze, Dominique S. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-17584-9	journal	August 2020
Stabilization of Hexaaminobenzene in a 2D Conductive Metal–Organic Framework for High Power Sodium Storage Park, Jihye; Lee, Minah; Feng, Dawei Journal of the American Chemical Society, Vol. 140, Issue 32 https://doi.org/10.1021/jacs.8b06020	journal	July 2018
Direct electrosynthesis of pure aqueous H 2 O 2 solutions up to 20% by weight using a solid electrolyte Xia, Chuan; Xia, Yang; Zhu, Peng Science, Vol. 366, Issue 6462 https://doi.org/10.1126/science.aay1844	journal	October 2019
Air-Stability and Carrier Type in Conductive M ₃ (Hexaaminobenzene) _2, (M = Co, Ni, Cu) Hinckley, Allison C.; Park, Jihye; Gomes, Joseph Journal of the American Chemical Society, Vol. 142, Issue 25 https://doi.org/10.1021/jacs.0c03500	journal	May 2020
Recent Advances in Electrochemical Oxygen Reduction to H ₂ O ₂ : Catalyst and Cell Design Jung, Euiyeon; Shin, Heejong; Hooch Antink, Wytse ACS Energy Letters, Vol. 5, Issue 6 https://doi.org/10.1021/acsenergylett.0c00812	journal	May 2020
Bifunctional HER/OER or OER/ORR Catalytic Activity of Two-Dimensional TM₃(HITP)₂ with TM = Fe–Zn Wang, Junru; Fan, Yingcai; Qi, Siyun The Journal of Physical Chemistry C, Vol. 124, Issue 17 https://doi.org/10.1021/acs.jpcc.0c01143	journal	April 2020
Redox Chemistry of Nickel Complexes in Aqueous Solutions Zilbermann, Israel; Maimon, Eric; Cohen, Haim Chemical Reviews, Vol. 105, Issue 6 https://doi.org/10.1021/cr030717f	journal	June 2005
The MRCAT insertion device beamline at the Advanced Photon Source Segre, C. U. The 11th US national synchrotron radiation instrumentation conference (SRI99), AIP Conference Proceedings https://doi.org/10.1063/1.1291825	conference	January 2000
High Electrical Conductivity in Ni ₃ (2,3,6,7,10,11-hexaiminotriphenylene) ₂ , a Semiconducting Metal–Organic Graphene Analogue Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A. Journal of the American Chemical Society, Vol. 136, Issue 25 https://doi.org/10.1021/ja502765n	journal	April 2014
Synthesis, structure, spectroscopy and redox chemistry of square-planar nickel(ii) complexes with tetradentate o-phenylenedioxamidates and related ligands Ottenwaelder, Xavier; Aukauloo, Ally; Journaux, Yves Dalton Transactions, Issue 15 https://doi.org/10.1039/b502478a	journal	January 2005
Robust and conductive two-dimensional metal−organic frameworks with exceptionally high volumetric and areal capacitance Feng, Dawei; Lei, Ting; Lukatskaya, Maria R. Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0044-5	journal	January 2018
Mechanistic Evidence for Ligand-Centered Electrocatalytic Oxygen Reduction with the Conductive MOF Ni ₃ (hexaiminotriphenylene) ₂ Miner, Elise M.; Gul, Sheraz; Ricke, Nathan D. ACS Catalysis, Vol. 7, Issue 11 https://doi.org/10.1021/acscatal.7b02647	journal	October 2017
Self-Nanocavity-Confined Halogen Anions Boosting the High Selectivity of the Two-Electron Oxygen Reduction Pathway over Ni-Based MOFs Liu, Meihuan; Li, Yuanli; Qi, Zeming The Journal of Physical Chemistry Letters, Vol. 12, Issue 36 https://doi.org/10.1021/acs.jpclett.1c01981	journal	September 2021
Understanding the Mechanism of High Capacitance in Nickel Hexaaminobenzene-Based Conductive Metal–Organic Frameworks in Aqueous Electrolytes Lukatskaya, Maria R.; Feng, Dawei; Bak, Seong-Min ACS Nano, Vol. 14, Issue 11 https://doi.org/10.1021/acsnano.0c07292	journal	November 2020
Oxidation-promoted Interfacial Synthesis of Redox-active Bis(diimino)nickel Nanosheet Phua, Eunice J. H.; Wu, Kuo-Hui; Wada, Keisuke Chemistry Letters, Vol. 47, Issue 2 https://doi.org/10.1246/cl.170928	journal	February 2018
Two-Dimensional Conductive Ni-HAB as a Catalyst for the Electrochemical Oxygen Reduction Reaction Park, Jihye; Chen, Zhihua; Flores, Raul A. ACS Applied Materials & Interfaces, Vol. 12, Issue 35 https://doi.org/10.1021/acsami.0c09323	journal	August 2020
Activity–Selectivity Trends in the Electrochemical Production of Hydrogen Peroxide over Single-Site Metal–Nitrogen–Carbon Catalysts Sun, Yanyan; Silvioli, Luca; Sahraie, Nastaran Ranjbar Journal of the American Chemical Society, Vol. 141, Issue 31 https://doi.org/10.1021/jacs.9b05576	journal	July 2019
Signature of Metallic Behavior in the Metal–Organic Frameworks M ₃ (hexaiminobenzene) ₂ (M = Ni, Cu) Dou, Jin-Hu; Sun, Lei; Ge, Yicong Journal of the American Chemical Society, Vol. 139, Issue 39 https://doi.org/10.1021/jacs.7b07234	journal	September 2017
Toward the Decentralized Electrochemical Production of H ₂ O ₂ : A Focus on the Catalysis Yang, Sungeun; Verdaguer-Casadevall, Arnau; Arnarson, Logi ACS Catalysis, Vol. 8, Issue 5 https://doi.org/10.1021/acscatal.8b00217	journal	March 2018
Stable and selective electrosynthesis of hydrogen peroxide and the electro-Fenton process on CoSe ₂ polymorph catalysts Sheng, Hongyuan; Janes, Aurora N.; Ross, R. Dominic Energy & Environmental Science, Vol. 13, Issue 11 https://doi.org/10.1039/d0ee01925a	journal	January 2020
Modular O ₂ electroreduction activity in triphenylene-based metal–organic frameworks Miner, Elise M.; Wang, Lu; Dincă, Mircea Chemical Science, Vol. 9, Issue 29 https://doi.org/10.1039/c8sc02049c	journal	January 2018
The New MRCAT (Sector 10) Bending Magnet Beamline at the Advanced Photon Source Kropf, A. J.; Katsoudas, J.; Chattopadhyay, S. SRI 2009, 10TH INTERNATIONAL CONFERENCE ON RADIATION INSTRUMENTATION, AIP Conference Proceedings https://doi.org/10.1063/1.3463194	conference	January 2010
Atomic-level tuning of Co–N–C catalyst for high-performance electrochemical H2O2 production Jung, Euiyeon; Shin, Heejong; Lee, Byoung-Hoon Nature Materials, Vol. 19, Issue 4 https://doi.org/10.1038/s41563-019-0571-5	journal	January 2020
Porous Scaffolds for Electrochemically Controlled Reversible Capture and Release of Ethylene Mendecki, Lukasz; Ko, Michael; Zhang, Xiaoping Journal of the American Chemical Society, Vol. 139, Issue 48 https://doi.org/10.1021/jacs.7b08102	journal	November 2017
Design Principle of Fe–N–C Electrocatalysts: How to Optimize Multimodal Porous Structures? Lee, Soo Hong; Kim, Jiheon; Chung, Dong Young Journal of the American Chemical Society, Vol. 141, Issue 5 https://doi.org/10.1021/jacs.8b11129	journal	January 2019
Electrochemical generation of hydrogen peroxide from dissolved oxygen in acidic solutions Qiang, Zhimin; Chang, Jih-Hsing; Huang, Chin-Pao Water Research, Vol. 36, Issue 1 https://doi.org/10.1016/S0043-1354(01)00235-4	journal	January 2002
Analysis of X-ray Absorption Spectra of Some Nickel Oxycompounds Using Theoretical Standards Mansour, A. N.; Melendres, C. A. The Journal of Physical Chemistry A, Vol. 102, Issue 1 https://doi.org/10.1021/jp9619853	journal	January 1998
2D Metal–Organic Frameworks as Multifunctional Materials in Heterogeneous Catalysis and Electro/Photocatalysis Dhakshinamoorthy, Amarajothi; Asiri, Abdullah M.; Garcia, Hermenegildo Advanced Materials, Vol. 31, Issue 41 https://doi.org/10.1002/adma.201900617	journal	August 2019
Tuning the Redox Activity of Metal–Organic Frameworks for Enhanced, Selective O ₂ Binding: Design Rules and Ambient Temperature O ₂ Chemisorption in a Cobalt–Triazolate Framework Rosen, Andrew S.; Mian, M. Rasel; Islamoglu, Timur Journal of the American Chemical Society, Vol. 142, Issue 9 https://doi.org/10.1021/jacs.9b12401	journal	February 2020
Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2 Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10942	journal	March 2016
Probing the active site in single-atom oxygen reduction catalysts via operando X-ray and electrochemical spectroscopy Lien, Hsiang-Ting; Chang, Sun-Tang; Chen, Po-Tuan Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-17975-y	journal	August 2020
Electrocatalytic hydrogen peroxide production in acidic media enabled by NiS ₂ nanosheets Liang, Jie; Wang, Yuanyuan; Liu, Qian Journal of Materials Chemistry A, Vol. 9, Issue 10 https://doi.org/10.1039/d0ta12008a	journal	January 2021
How to Effectively Utilize MOFs for Electrocatalysis Jin, Song ACS Energy Letters, Vol. 4, Issue 6 https://doi.org/10.1021/acsenergylett.9b01134	journal	May 2019
Electrocatalytic Production of H ₂ O ₂ by Selective Oxygen Reduction Using Earth-Abundant Cobalt Pyrite (CoS ₂ ) Sheng, Hongyuan; Hermes, Eric D.; Yang, Xiaohua ACS Catalysis, Vol. 9, Issue 9 https://doi.org/10.1021/acscatal.9b02546	journal	August 2019
Challenges and Opportunities for Applications of Advanced X-ray Spectroscopy in Catalysis Research Cutsail III, George E.; DeBeer, Serena ACS Catalysis https://doi.org/10.1021/acscatal.2c01016	journal	May 2022

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