Fe[subscript 5]S[subscript 2] identified as a host of sulfur in Earth and planetary cores

Zurkowski, Claire C.; Lavina, Barbara; Case, Abigail; Swadba, Kellie; Chariton, Stella; Prakapenka, Vitali; Campbell, Andrew J.

doi:10.1016/j.epsl.2022.117650

Title: Fe[subscript 5]S[subscript 2] identified as a host of sulfur in Earth and planetary cores

Journal Article · 01 September 2022 · Earth Planet. Sci. Lett.

DOI:https://doi.org/10.1016/j.epsl.2022.117650· OSTI ID:1900673

Zurkowski, Claire C.; Lavina, Barbara; Case, Abigail; Swadba, Kellie; Chariton, Stella; Prakapenka, Vitali; Campbell, Andrew J.

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: DOE - Office Of Science; National Science Foundation (NSF)

OSTI ID:: 1900673

Journal Information:: Earth Planet. Sci. Lett., Vol. 593

Country of Publication:: United States

Language:: ENGLISH

References (56)

Venus’ internal structure, temperature and core composition Aitta, A. Icarus, Vol. 218, Issue 2 https://doi.org/10.1016/j.icarus.2012.01.007	journal	April 2012
Elastic anisotropy in textured hcp-iron to 112 GPa from sound wave propagation measurements Antonangeli, Daniele; Occelli, Florent; Requardt, Herwig Earth and Planetary Science Letters, Vol. 225, Issue 1-2 https://doi.org/10.1016/j.epsl.2004.06.004	journal	August 2004
Elasticity and constitution of the Earth's interior Birch, Francis Journal of Geophysical Research, Vol. 57, Issue 2 https://doi.org/10.1029/JZ057i002p00227	journal	June 1952
X-ray Photoelectron and Absorption Spectroscopy of Metal-Rich Phosphides M ₂ P and M ₃ P ( M = Cr−Ni) Blanchard, Peter E. R.; Grosvenor, Andrew P.; Cavell, Ronald G. Chemistry of Materials, Vol. 20, Issue 22 https://doi.org/10.1021/cm802123a	journal	November 2008
Partial melting in the iron–sulfur system at high pressure: A synchrotron X-ray diffraction study Campbell, Andrew J.; Seagle, Christopher T.; Heinz, Dion L. Physics of the Earth and Planetary Interiors, Vol. 162, Issue 1-2 https://doi.org/10.1016/j.pepi.2007.04.001	journal	June 2007
High pressure effects on the iron–iron oxide and nickel–nickel oxide oxygen fugacity buffers Campbell, Andrew J.; Danielson, Lisa; Righter, Kevin Earth and Planetary Science Letters, Vol. 286, Issue 3-4 https://doi.org/10.1016/j.epsl.2009.07.022	journal	September 2009
A structural survey of the binary transition metal phosphides and arsenides of the d-block elements Chen, Jing-Han; Whitmire, Kenton H. Coordination Chemistry Reviews, Vol. 355 https://doi.org/10.1016/j.ccr.2017.08.029	journal	January 2018
High-pressure polymorphism of Fe ₂ P and its implications for meteorites and Earth's core : HIGH PRESSURE BEHAVIOR OF Fe Dera, Przemyslaw; Lavina, Barbara; Borkowski, Lauren A. Geophysical Research Letters, Vol. 35, Issue 10 https://doi.org/10.1029/2008GL033867	journal	May 2008
Preliminary reference Earth model Dziewonski, Adam M.; Anderson, Don L. Physics of the Earth and Planetary Interiors, Vol. 25, Issue 4 https://doi.org/10.1016/0031-9201(81)90046-7	journal	June 1981
Kristallstruktur von Pd5Sb2 und Ni5As2 und einigen varianten El-boragy, M.; Bhan, S.; Schubert, K. Journal of the Less Common Metals, Vol. 22, Issue 4 https://doi.org/10.1016/0022-5088(70)90132-3	journal	December 1970
Lunar Troilite: Crystallography Evans, Howard T. Science, Vol. 167, Issue 3918 https://doi.org/10.1126/science.167.3918.621	journal	January 1970
Compositional convection and stratification of Earth's core Fearn, David R.; Loper, David E. Nature, Vol. 289, Issue 5796 https://doi.org/10.1038/289393a0	journal	January 1981
Structure and Density of FeS at High Pressure and High Temperature and the Internal Structure of Mars Fei, Y.; Prewitt, C. T.; Mao, H. -k. Science, Vol. 268, Issue 5219 https://doi.org/10.1126/science.268.5219.1892	journal	June 1995
High-Pressure Iron-Sulfur Compound, Fe3S2, and Melting Relations in the Fe-FeS System Fei, Y.; Bertka, C. M.; Finger, L. W. Science, Vol. 275, Issue 5306 https://doi.org/10.1126/science.275.5306.1621	journal	March 1997
Structure type and bulk modulus of Fe ₃ S, a new iron-sulfur compound Fei, Yingwei; Li, Jie; Bertka, Constance M. American Mineralogist, Vol. 85, Issue 11-12 https://doi.org/10.2138/am-2000-11-1229	journal	November 2000
Kristallstruktur von Ni31Si12 Frank, K.; Schubert, K. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 27, Issue 5 https://doi.org/10.1107/S0567740871003261	journal	May 1971
High-pressure behavior of Fe3P and the role of phosphorus in planetary cores Gu, Tingting; Fei, Yingwei; Wu, Xiang Earth and Planetary Science Letters, Vol. 390 https://doi.org/10.1016/j.epsl.2014.01.019	journal	March 2014
Phase stabilities and spin transitions of Fe ₃ (S _1−x P _x ) at high pressure and its implications in meteorites Gu, Tingting; Fei, Yingwei; Wu, Xiang American Mineralogist, Vol. 101, Issue 1 https://doi.org/10.2138/am-2016-5466	journal	January 2016
Seismically determined elastic parameters for Earth’s outer core Irving, Jessica C. E.; Cottaar, Sanne; Lekić, Vedran Science Advances, Vol. 4, Issue 6 https://doi.org/10.1126/sciadv.aar2538	journal	June 2018
Elongation of Fe-Fe atomic pairs in the Invar alloy Fe65Ni35 Ishimatsu, N.; Iwasaki, S.; Kousa, M. Physical Review B, Vol. 103, Issue 22 https://doi.org/10.1103/PhysRevB.103.L220102	journal	June 2021
Experimental investigations of trace element fractionation in iron meteorites, II: The influence of sulfur Jones, John H.; Drake, Michael J. Geochimica et Cosmochimica Acta, Vol. 47, Issue 7 https://doi.org/10.1016/0016-7037(83)90062-5	journal	July 1983
Phase relationships of the Fe–FeS system in conditions up to the Earth's outer core Kamada, Seiji; Terasaki, Hidenori; Ohtani, Eiji Earth and Planetary Science Letters, Vol. 294, Issue 1-2 https://doi.org/10.1016/j.epsl.2010.03.011	journal	May 2010
Melting relationships in the Fe–Fe3S system up to the outer core conditions Kamada, Seiji; Ohtani, Eiji; Terasaki, Hidenori Earth and Planetary Science Letters, Vol. 359-360 https://doi.org/10.1016/j.epsl.2012.09.038	journal	December 2012
Equation of state of Fe3S at room temperature up to 2megabars Kamada, Seiji; Ohtani, Eiji; Terasaki, Hidenori Physics of the Earth and Planetary Interiors, Vol. 228 https://doi.org/10.1016/j.pepi.2013.11.001	journal	March 2014
BX90: A new diamond anvil cell design for X-ray diffraction and optical measurements Kantor, I.; Prakapenka, V.; Kantor, A. Review of Scientific Instruments, Vol. 83, Issue 12, Article No. 125102 https://doi.org/10.1063/1.4768541	journal	December 2012
High-pressure and high-temperature polymorphism of iron sulfide (FeS) King, H. E.; Prewitt, C. T. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 38, Issue 7 https://doi.org/10.1107/S0567740882007523	journal	July 1982
On the Crystal Structure of Ni5As2. Kjekshus, Arne; Skaug, Kjell Erik; Hebrew, C. Acta Chemica Scandinavica, Vol. 27 https://doi.org/10.3891/acta.chem.scand.27-0582	journal	January 1973
Protracted core formation and rapid accretion of protoplanets Kruijer, T. S.; Touboul, M.; Fischer-Godde, M. Science, Vol. 344, Issue 6188 https://doi.org/10.1126/science.1251766	journal	June 2014
The Ni–Ni₂P phase diagram at 6 GPa with implication to meteorites and super-reduced terrestrial rocks Litasov, Konstantin D.; Shatskiy, Anton F.; Minin, Daniil A. High Pressure Research, Vol. 39, Issue 4 https://doi.org/10.1080/08957959.2019.1672677	journal	October 2019
Chemical classification of iron meteorites—X. Multielement studies of 43 irons, resolution of group IIIE from IIIAB, and evaluation of Cu as a taxonomic parameter Malvin, Daniel J.; Wang, Daode; Wasson, John T. Geochimica et Cosmochimica Acta, Vol. 48, Issue 4 https://doi.org/10.1016/0016-7037(84)90101-7	journal	April 1984
On the resolution of density within the Earth Masters, Guy; Gubbins, David Physics of the Earth and Planetary Interiors, Vol. 140, Issue 1-3 https://doi.org/10.1016/j.pepi.2003.07.008	journal	November 2003
The composition of the Earth McDonough, W. F.; Sun, S. -s. Chemical Geology, Vol. 120, Issue 3-4 https://doi.org/10.1016/0009-2541(94)00140-4	journal	March 1995
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011
In situ determination of Fe–Fe3S phase diagram and liquid structural properties up to 65 GPa Morard, G.; Andrault, D.; Guignot, N. Earth and Planetary Science Letters, Vol. 272, Issue 3-4 https://doi.org/10.1016/j.epsl.2008.05.028	journal	August 2008
Melting experiments on Fe–Fe 3 S system to 254 GPa Mori, Yuko; Ozawa, Haruka; Hirose, Kei Earth and Planetary Science Letters, Vol. 464 https://doi.org/10.1016/j.epsl.2017.02.021	journal	April 2017
The chemical composition of the Earth's core: Possibility of sulphur in the core Rama Murthy, V.; Hall, H. T. Physics of the Earth and Planetary Interiors, Vol. 2, Issue 4 https://doi.org/10.1016/0031-9201(70)90014-2	journal	June 1970
Why does Venus lack a magnetic field? Nimmo, Francis Geology, Vol. 30, Issue 11 https://doi.org/10.1130/0091-7613(2002)030<0987:WDVLAM>2.0.CO;2	journal	January 2002
Structure of synthetic perryite, (Ni,Fe)8(Si,P)3 Okada, A.; Kobayashi, K.; Ito, T. Acta Crystallographica Section C Crystal Structure Communications, Vol. 47, Issue 7 https://doi.org/10.1107/S0108270191000483	journal	July 1991
Crystal structure of HT-Ni5P2 and reinvestigation of isotypic Ni5As2 Oryshchyn, Stepan; Babizhetskyy, Volodymyr; Zhak, Olga Intermetallics, Vol. 19, Issue 7 https://doi.org/10.1016/j.intermet.2011.03.013	journal	July 2011
Decomposition of Fe ₃ S above 250 GPa Ozawa, Haruka; Hirose, Kei; Suzuki, Toshihiro Geophysical Research Letters, Vol. 40, Issue 18 https://doi.org/10.1002/grl.50946	journal	September 2013
Advanced flat top laser heating system for high pressure research at GSECARS: application to the melting behavior of germanium Prakapenka, V. B.; Kubo, A.; Kuznetsov, A. High Pressure Research, Vol. 28, Issue 3 https://doi.org/10.1080/08957950802050718	journal	September 2008
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration Prescher, Clemens; Prakapenka, Vitali B. High Pressure Research, Vol. 35, Issue 3 https://doi.org/10.1080/08957959.2015.1059835	journal	May 2015
COMPOUNDS OF THE TYPE M₅X₂: Pd₅As₂, Ni₅Si₂, AND Ni₅P₂ Saini, G. S.; Calvert, L. D.; Taylor, J. B. Canadian Journal of Chemistry, Vol. 42, Issue 7 https://doi.org/10.1139/v64-233	journal	July 1964
Classification and properties of iron meteorites Scott, Edward R. D.; Wasson, John T. Reviews of Geophysics, Vol. 13, Issue 4 https://doi.org/10.1029/RG013i004p00527	journal	January 1975
Thermal equation of state of Fe ₃ S and implications for sulfur in Earth's core: THERMAL EQUATION OF STATE OF Fe ₃ S Seagle, Christopher T.; Campbell, Andrew J.; Heinz, Dion L. Journal of Geophysical Research: Solid Earth, Vol. 111, Issue B6 https://doi.org/10.1029/2005JB004091	journal	June 2006
High pressure constraints on percolative core formation Shannon, M. C.; Agee, C. B. Geophysical Research Letters, Vol. 23, Issue 20 https://doi.org/10.1029/96GL02817	journal	October 1996
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015
A sulfur-poor terrestrial core inferred from metal–silicate partitioning experiments Suer, Terry-Ann; Siebert, Julien; Remusat, Laurent Earth and Planetary Science Letters, Vol. 469 https://doi.org/10.1016/j.epsl.2017.04.016	journal	July 2017
Models of the Earth's Core Stevenson, D. J. Science, Vol. 214, Issue 4521 https://doi.org/10.1126/science.214.4521.611	journal	November 1981
High-pressure experimental constraints of partitioning behavior of Si and S at the Mercury's inner core boundary Tao, Renbiao; Fei, Yingwei Earth and Planetary Science Letters, Vol. 562 https://doi.org/10.1016/j.epsl.2021.116849	journal	May 2021
Fe ₂ S: The Most Fe‐Rich Iron Sulfide at the Earth's Inner Core Pressures Tateno, Shigehiko; Ozawa, Haruka; Hirose, Kei Geophysical Research Letters, Vol. 46, Issue 21 https://doi.org/10.1029/2019GL085248	journal	November 2019
Compression experiments to 126 GPa and 2500 K and thermal equation of state of Fe3S: Implications for sulphur in the Earth's core Thompson, Samuel; Komabayashi, Tetsuya; Breton, Helene Earth and Planetary Science Letters, Vol. 534 https://doi.org/10.1016/j.epsl.2020.116080	journal	March 2020
Composition of the metal, schreibersite and perryite of enstatite achondrites and the origin of enstatite chondrites and achondrites Wasson, John T.; Wai, Chien M. Geochimica et Cosmochimica Acta, Vol. 34, Issue 2 https://doi.org/10.1016/0016-7037(70)90004-9	journal	February 1970
Melting Experiments on Liquidus Phase Relations in the Fe‐S‐O Ternary System Under Core Pressures Yokoo, Shunpei; Hirose, Kei; Sinmyo, Ryosuke Geophysical Research Letters, Vol. 46, Issue 10 https://doi.org/10.1029/2019GL082277	journal	May 2019
Core formation in planetesimals triggered by permeable flow Yoshino, Takashi; Walter, Michael J.; Katsura, Tomoo Nature, Vol. 422, Issue 6928 https://doi.org/10.1038/nature01459	journal	March 2003
The crystal structure of Fe2S at 90 GPa based on single-crystal X-ray diffraction techniques Zurkowski, Claire C.; Lavina, Barbara; Chariton, Stella American Mineralogist, Vol. 107, Issue 4 https://doi.org/10.2138/am-2022-7973	journal	April 2022

Similar Records

Fe₅S₂ identified as a host of sulfur in Earth and planetary cores

Journal Article · 2022 · Earth and Planetary Science Letters · OSTI ID:1900673

Zurkowski, Claire C.; Lavina, Barbara; Case, Abigail; +4 more

Structure and behavior of the barringerite Ni end-member, Ni[subscript 2]P, at deep Earth conditions and implications for natural Fe-Ni phosphides in planetary cores

Journal Article · 2009 · J. Geophys. Res. · OSTI ID:1900673

Dera, P; Lavina, B; Borkowski, L A; +6 more

Magnetic transition and sound velocities of Fe(sub 3)S at high pressure: implications for earth and planetary cores.

Journal Article · 2004 · Earth and Planetary Science Letters · OSTI ID:1900673

Lin, J; Fei, Y; Sturhahn, W; +5 more

Title: Fe[subscript 5]S[subscript 2] identified as a host of sulfur in Earth and planetary cores

Citation Formats

References (56)

Similar Records

Related Subjects