Nanocomposite membranes and methods of forming the same

Tsapatsis, Michael; Ma, Xiaoli

Nanocomposite membranes and methods of forming the same

Patent · 31 May 2022

OSTI ID:1892979

Tsapatsis, Michael; Ma, Xiaoli

A nanocomposite including a mesoporous, macroporous, or a combination thereof oxide and a zeolitic imidazolate framework (ZIF) that is filling the pores of the oxide to form a ZIF phase embedded and at least substantially confined mostly within the oxide. Methods of making nanocomposites including the steps of depositing an oxide in the pores of a mesoporous oxide; and further treating the resulting material with vapor, liquid, or supercritical CO2 comprising an azole-based compound, a carboxylate based compound, or a combination thereof. Use of disclosed articles to separate propylene and propane in a mixture thereof.

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Research Organization:: US Dept. of Energy (USDOE), Washington, DC (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: SC0001015

Assignee:: Tsapatsis, Michael (Baltimore, MD); Ma, Xiaoli (Pleasant Prairie, WI)

Patent Number(s):: 11,344,850

Application Number:: 16/172,581

OSTI ID:: 1892979

Country of Publication:: United States

Language:: English

References (71)

Chemical vapor deposition of yttria stabilized zirconia on porous supports Carolan, M. Solid State Ionics, Vol. 25, Issue 2-3 https://doi.org/10.1016/0167-2738(87)90122-6	journal	November 1987
Effect of Solution Concentration on Structure and Permeation Properties of ZIF-8 Membranes for Propylene/Propane Separation Hara, Nobuo; Yoshimune, Miki; Negishi, Hideyuki Journal of Chemical Engineering of Japan, Vol. 49, Issue 2 https://doi.org/10.1252/jcej.15we038	journal	January 2016
Heteroepitaxially Grown Zeolitic Imidazolate Framework Membranes with Unprecedented Propylene/Propane Separation Performances Kwon, Hyuk Taek; Jeong, Hae-Kwon; Lee, Albert S. Journal of the American Chemical Society, Vol. 137, Issue 38 https://doi.org/10.1021/jacs.5b06730	journal	September 2015
Energy Efficiency Limitations of the Conventional Heat Integrated Distillation Column (HIDiC) Configuration for Binary Distillation ^† Shenvi, Anirudh A.; Herron, D. Michael; Agrawal, Rakesh Industrial & Engineering Chemistry Research, Vol. 50, Issue 1 https://doi.org/10.1021/ie101698f	journal	January 2011
Zeolitic imidazolate framework membranes made by ligand-induced permselectivation Ma, Xiaoli; Kumar, Prashant; Mittal, Nitish Science, Vol. 361, Issue 6406 https://doi.org/10.1126/science.aat4123	journal	September 2018
High-Flux Zeolitic Imidazolate Framework Membranes for Propylene/Propane Separation by Postsynthetic Linker Exchange Lee, Moon Joo; Kwon, Hyuk Taek; Jeong, Hae-Kwon Angewandte Chemie International Edition, Vol. 57, Issue 1 https://doi.org/10.1002/anie.201708924	journal	December 2017
Ultrathin metal–organic framework membrane production by gel–vapour deposition Li, Wanbin; Su, Pengcheng; Li, Zhanjun Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00544-1	journal	September 2017
Olefin/paraffin separation technology: a review Eldridge, R. Bruce Industrial & Engineering Chemistry Research, Vol. 32, Issue 10 https://doi.org/10.1021/ie00022a002	journal	October 1993
Technical and economic evaluation Separation of the separation of light olefins (Ethylene and Propylene) by using π-complexationwith silver salts Salgado-Gordon, Hernando-José; Valbuena-Moreno, Gleidy CT&F - Ciencia, Tecnología y Futuro, Vol. 4, Issue 3 https://doi.org/10.29047/01225383.240	journal	May 2011
Fluidic Processing of High-Performance ZIF-8 Membranes on Polymeric Hollow Fibers: Mechanistic Insights and Microstructure Control Eum, Kiwon; Rownaghi, Ali; Choi, Dalsu Advanced Functional Materials, Vol. 26, Issue 28 https://doi.org/10.1002/adfm.201601550	journal	June 2016
Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets Jeon, Mi Young; Kim, Donghun; Kumar, Prashant Nature, Vol. 543, Issue 7647 https://doi.org/10.1038/nature21421	journal	March 2017
Unexpected Molecular Sieving Properties of Zeolitic Imidazolate Framework-8 Zhang, Chen; Lively, Ryan P.; Zhang, Ke The Journal of Physical Chemistry Letters, Vol. 3, Issue 16 https://doi.org/10.1021/jz300855a	journal	July 2012
Optimal design of cryogenic distillation columns with side heat pumps for the propylene/propane separation Alcántara-Avila, J. Rafael; Gómez-Castro, Fernando I.; Segovia-Hernández, J. Gabriel Chemical Engineering and Processing: Process Intensification, Vol. 82 https://doi.org/10.1016/j.cep.2014.06.006	journal	August 2014
A Comparison of Advanced Distillation Control Techniques for a Propylene/Propane Splitter Gokhale, Vikram; Hurowitz, Scott; Riggs, James B. Industrial & Engineering Chemistry Research, Vol. 34, Issue 12 https://doi.org/10.1021/ie00039a033	journal	December 1995
Effective separation of propylene/propane binary mixtures by ZIF-8 membranes Pan, Yichang; Li, Tao; Lestari, Gabriella Journal of Membrane Science, Vol. 390-391 https://doi.org/10.1016/j.memsci.2011.11.024	journal	February 2012
Bioethanol enrichment using zeolite membranes: Molecular modeling, conceptual process design and techno-economic analysis Mittal, Nitish; Bai, Peng; Siepmann, J. Ilja Journal of Membrane Science, Vol. 540 https://doi.org/10.1016/j.memsci.2017.06.075	journal	October 2017
Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene Li, Kunhao; Olson, David H.; Seidel, Jonathan Journal of the American Chemical Society, Vol. 131, Issue 30 https://doi.org/10.1021/ja9039983	journal	August 2009
Defect-induced ripening of zeolitic-imidazolate framework ZIF-8 and its implication to vapor-phase membrane synthesis Kwon, Hyuk Taek; Jeong, Hae-Kwon; Lee, Albert S. Chemical Communications, Vol. 52, Issue 78 https://doi.org/10.1039/C6CC05433A	journal	January 2016
Solution-processable exfoliated zeolite nanosheets purified by density gradient centrifugation Agrawal, Kumar Varoon; Topuz, Berna; Jiang, Zheyu AIChE Journal, Vol. 59, Issue 9, p. 3458-3467 https://doi.org/10.1002/aic.14099	journal	May 2013
Modelling and analysis of CVD processes in porous media for ceramic composite preparation Lin, Y. S.; Burggraaf, A. J. Chemical Engineering Science, Vol. 46, Issue 12 https://doi.org/10.1016/0009-2509(91)85010-U	journal	January 1991
Water and beyond: Expanding the spectrum of large-scale energy efficient separation processes Koros, William J.; Lively, Ryan P. AIChE Journal, Vol. 58, Issue 9 https://doi.org/10.1002/aic.13888	journal	July 2012
Design of Hybrid Distillation−Vapor Membrane Separation Systems Caballero, Jose A.; Grossmann, Ignacio E.; Keyvani, Majid Industrial & Engineering Chemistry Research, Vol. 48, Issue 20 https://doi.org/10.1021/ie900499y	journal	October 2009
Improved ZIF-8 membrane: Effect of activation procedure and determination of diffusivities of light hydrocarbons Pan, Yichang; Liu, Wei; Zhao, Yingjie Journal of Membrane Science, Vol. 493 https://doi.org/10.1016/j.memsci.2015.06.019	journal	November 2015
Experimental and Modeling Analysis of Propylene Polymerization in a Pilot-Scale Fluidized Bed Reactor Shamiri, Ahmad; Hussain, M. A.; Mjalli, Farouq Sabri Industrial & Engineering Chemistry Research, Vol. 53, Issue 21 https://doi.org/10.1021/ie501155h	journal	May 2014
From conventional to conformal Allendorf, Mark D.; Stavila, Vitalie Nature Materials, Vol. 15, Issue 3 https://doi.org/10.1038/nmat4527	journal	December 2015
Thickness Reduction of the Zeolitic Imidazolate Framework-8 Membrane by Controlling the Reaction Rate during the Membrane Preparation Hara, Nobuo; Yoshimune, Miki; Negishi, Hideyuki JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 47, Issue 10 https://doi.org/10.1252/jcej.14we340	journal	January 2014
Techno-economic feasibility study of membrane based propane/propylene separation process Lee, Ung; Kim, Jeongnam; Seok Chae, Il Chemical Engineering and Processing: Process Intensification, Vol. 119 https://doi.org/10.1016/j.cep.2017.05.013	journal	September 2017
In Situ Synthesis of Thin Zeolitic–Imidazolate Framework ZIF-8 Membranes Exhibiting Exceptionally High Propylene/Propane Separation Kwon, Hyuk Taek; Jeong, Hae-Kwon Journal of the American Chemical Society, Vol. 135, Issue 29 https://doi.org/10.1021/ja403849c	journal	July 2013
ZIF-8 membranes with improved reproducibility fabricated from sputter-coated ZnO/alumina supports Yu, Jian; Pan, Yichang; Wang, Chongqing Chemical Engineering Science, Vol. 141 https://doi.org/10.1016/j.ces.2015.10.035	journal	February 2016
Conceptual design of an internally heat integrated propylene-propane splitter Olujić, Ž.; Sun, L.; de Rijke, A. Energy, Vol. 31, Issue 15 https://doi.org/10.1016/j.energy.2006.03.030	journal	December 2006
Towards energy efficient distillation technologies – Making the right choice Kiss, Anton A.; Flores Landaeta, Servando J.; Infante Ferreira, Carlos A. Energy, Vol. 47, Issue 1 https://doi.org/10.1016/j.energy.2012.09.038	journal	November 2012
Nanoscale MOF/organosilica membranes on tubular ceramic substrates for highly selective gas separation Kong, Chunlong; Du, Hongbing; Chen, Liang Energy & Environmental Science, Vol. 10, Issue 8 https://doi.org/10.1039/C7EE00830A	journal	January 2017
Seven chemical separations to change the world Sholl, David S.; Lively, Ryan P. Nature, Vol. 532, Issue 7600 https://doi.org/10.1038/532435a	journal	April 2016
Formation of ZIF-8 membranes inside porous supports for improving both their H2/CO2 separation performance and thermal/mechanical stability Jang, Eunhee; Kim, Eunjoo; Kim, Heejoong Journal of Membrane Science, Vol. 540 https://doi.org/10.1016/j.memsci.2017.06.072	journal	October 2017
Ethane/Ethene Separation Turned on Its Head: Selective Ethane Adsorption on the Metal−Organic Framework ZIF-7 through a Gate-Opening Mechanism Gücüyener, Canan; van den Bergh, Johan; Gascon, Jorge Journal of the American Chemical Society, Vol. 132, Issue 50 https://doi.org/10.1021/ja1089765	journal	December 2010
Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis Bux, Helge; Liang, Fangyi; Li, Yanshuo Journal of the American Chemical Society, Vol. 131, Issue 44 https://doi.org/10.1021/ja907359t	journal	November 2009
Highly propylene-selective supported zeolite-imidazolate framework (ZIF-8) membranes synthesized by rapid microwave-assisted seeding and secondary growth Kwon, Hyuk Taek; Jeong, Hae-Kwon Chemical Communications, Vol. 49, Issue 37 https://doi.org/10.1039/c3cc41039k	journal	January 2013
Design of a Process for Production of Isopropyl Alcohol by Hydration of Propylene in a Catalytic Distillation Column Xu, Y.; Chuang, K. T.; Sanger, A. R. Chemical Engineering Research and Design, Vol. 80, Issue 6 https://doi.org/10.1205/026387602760312908	journal	September 2002
MOF Channels within Porous Polymer Film: Flexible, Self-Supporting ZIF-8 Poly(ether sulfone) Composite Membrane Hess, Samuel C.; Grass, Robert N.; Stark, Wendelin J. Chemistry of Materials, Vol. 28, Issue 21 https://doi.org/10.1021/acs.chemmater.6b02499	journal	October 2016
Structure and Electronic Properties of a Continuous Random Network Model of an Amorphous Zeolitic Imidazolate Framework (a-ZIF) Adhikari, Puja; Xiong, Mo; Li, Neng The Journal of Physical Chemistry C, Vol. 120, Issue 28 https://doi.org/10.1021/acs.jpcc.6b06337	journal	July 2016
A comparative study on thermal and hydrothermal stability of alumina, titania and zirconia membranes Chang, C. -H.; Gopalan, R.; Lin, Y. S. Journal of Membrane Science, Vol. 91, Issue 1-2 https://doi.org/10.1016/0376-7388(94)00041-7	journal	May 1994
A kinetic model of membrane formation by CVD of SiO2 and Al2O3 Tsapatsis, Michael; Gavalas, George R. AIChE Journal, Vol. 38, Issue 6 https://doi.org/10.1002/aic.690380606	journal	June 1992
Gel-Free Secondary Growth of Uniformly Oriented Silica MFI Zeolite Films and Application for Xylene Separation Pham, Tung Cao Thanh; Nguyen, Thanh Huu; Yoon, Kyung Byung Angewandte Chemie International Edition, Vol. 52, Issue 33, p. 8693-8698 https://doi.org/10.1002/anie.201301766	journal	July 2013
A generalized methodology for optimal configurations of hybrid distillation–pervaporation processes Naidu, Yellaiah; Malik, Ranjan K. Chemical Engineering Research and Design, Vol. 89, Issue 8 https://doi.org/10.1016/j.cherd.2011.02.025	journal	August 2011
Zeolitic Imidazolate Framework Membranes for Light Olefin/Paraffin Separation Ma, Xiaoli; Liu, Defei Crystals, Vol. 9, Issue 1 https://doi.org/10.3390/cryst9010014	journal	December 2018
A mathematical model for zeolite membrane module performance and its use for techno-economic evaluation of improved energy efficiency hybrid membrane-distillation processes for butane isomer separations Mittal, Nitish; Bai, Peng; Kelloway, Adam Journal of Membrane Science, Vol. 520 https://doi.org/10.1016/j.memsci.2016.06.041	journal	December 2016
Improving propylene/propane separation performance of Zeolitic-Imidazolate framework ZIF-8 Membranes Kwon, Hyuk Taek; Jeong, Hae-Kwon Chemical Engineering Science, Vol. 124 https://doi.org/10.1016/j.ces.2014.06.021	journal	March 2015
Zeolitic imidazolate framework composite membranes and thin films: synthesis and applications Yao, Jianfeng; Wang, Huanting Chem. Soc. Rev., Vol. 43, Issue 13 https://doi.org/10.1039/C3CS60480B	journal	January 2014
ZIF-8 membranes prepared at miscible and immiscible liquid–liquid interfaces Hara, Nobuo; Yoshimune, Miki; Negishi, Hideyuki Microporous and Mesoporous Materials, Vol. 206 https://doi.org/10.1016/j.micromeso.2014.12.018	journal	April 2015
ZIF-8 Membranes via Interfacial Microfluidic Processing in Polymeric Hollow Fibers: Efficient Propylene Separation at Elevated Pressures Eum, Kiwon; Ma, Chen; Rownaghi, Ali ACS Applied Materials & Interfaces, Vol. 8, Issue 38 https://doi.org/10.1021/acsami.6b08801	journal	September 2016
Solid polymer electrolyte composite membranes for olefin/paraffin separation Pinnau, Ingo; Toy, Lora G. Journal of Membrane Science, Vol. 184, Issue 1 https://doi.org/10.1016/S0376-7388(00)00603-7	journal	March 2001
Diffusive separation of propylene/propane with ZIF-8 membranes Hara, Nobuo; Yoshimune, Miki; Negishi, Hideyuki Journal of Membrane Science, Vol. 450 https://doi.org/10.1016/j.memsci.2013.09.012	journal	January 2014
Zeolite-like metal–organic frameworks (ZMOFs): design, synthesis, and properties Eddaoudi, Mohamed; Sava, Dorina F.; Eubank, Jarrod F. Chemical Society Reviews, Vol. 44, Issue 1 https://doi.org/10.1039/C4CS00230J	journal	January 2015
Interfacial microfluidic processing of metal-organic framework hollow fiber membranes Brown, Andrew J.; Brunelli, Nicholas A.; Eum, Kiwon Science, Vol. 345, Issue 6192 https://doi.org/10.1126/science.1251181	journal	July 2014
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Highly Permeable Zeolite Imidazolate Framework-8 Membranes for CO ₂ /CH ₄ Separation Venna, Surendar R.; Carreon, Moises A. Journal of the American Chemical Society, Vol. 132, Issue 1 https://doi.org/10.1021/ja909263x	journal	January 2010
An innovative approach for the preparation of confined ZIF-8 membranes by conversion of ZnO ALD layers Drobek, Martin; Bechelany, Mikhael; Vallicari, Cyril Journal of Membrane Science, Vol. 475 https://doi.org/10.1016/j.memsci.2014.10.011	journal	February 2015
Optimal Design of Membrane/Distillation Column Hybrid Processes Kookos, Ioannis K. Industrial & Engineering Chemistry Research, Vol. 42, Issue 8 https://doi.org/10.1021/ie020616s	journal	April 2003
Melt-Quenched Hybrid Glasses from Metal-Organic Frameworks Tao, Haizheng; Bennett, Thomas D.; Yue, Yuanzheng Advanced Materials, Vol. 29, Issue 20 https://doi.org/10.1002/adma.201601705	journal	January 2017
Chemical vapour deposition of zeolitic imidazolate framework thin films Stassen, Ivo; Styles, Mark; Grenci, Gianluca Nature Materials, Vol. 15, Issue 3 https://doi.org/10.1038/nmat4509	journal	December 2015
Sub-micron Polymer–Zeolitic Imidazolate Framework Layered Hybrids via Controlled Chemical Transformation of Naked ZnO Nanocrystal Films Meckler, Stephen M.; Li, Changyi; Queen, Wendy L. Chemistry of Materials, Vol. 27, Issue 22 https://doi.org/10.1021/acs.chemmater.5b03219	journal	November 2015
50th Anniversary Perspective : Polymers and Mixed Matrix Membranes for Gas and Vapor Separation: A Review and Prospective Opportunities Galizia, Michele; Chi, Won Seok; Smith, Zachary P. Macromolecules, Vol. 50, Issue 20 https://doi.org/10.1021/acs.macromol.7b01718	journal	October 2017
Performance study of multistage membrane and hybrid distillation processes for propylene/propane separation Park, Jaedeuk; Kim, Kiwoong; Shin, Jae-Wook The Canadian Journal of Chemical Engineering, Vol. 95, Issue 12 https://doi.org/10.1002/cjce.22914	journal	July 2017
Dynamics and control of vapor recompression distillation Jogwar, Sujit S.; Daoutidis, Prodromos Journal of Process Control, Vol. 19, Issue 10 https://doi.org/10.1016/j.jprocont.2009.07.001	journal	December 2009
Grain size control of ZIF-8 membranes by seeding-free aqueous synthesis and their performances in propylene/propane separation Tanaka, Shunsuke; Okubo, Kenta; Kida, Koji Journal of Membrane Science, Vol. 544 https://doi.org/10.1016/j.memsci.2017.09.037	journal	December 2017
Numerical simulation of fixed-bed catalytic reactor for isopropyl alcohol synthesis Kim, Dong-Kwon; Lee, Soo-Bok; Yoon, Poong Korean Journal of Chemical Engineering, Vol. 6, Issue 2 https://doi.org/10.1007/BF02697486	journal	April 1989
Effect of Temperature on Synthesis of ZIF-8 Membranes for Propylene/propane Separation by Counter Diffusion Method Hara, Nobuo; Yoshimune, Miki; Negishi, Hideyuki Journal of the Japan Petroleum Institute, Vol. 58, Issue 4 https://doi.org/10.1627/jpi.58.237	journal	January 2015
Gas transport properties and propylene/propane separation characteristics of ZIF-8 membranes Liu, Defei; Ma, Xiaoli; Xi, Hongxia Journal of Membrane Science, Vol. 451 https://doi.org/10.1016/j.memsci.2013.09.029	journal	February 2014
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks Park, K. S.; Ni, Z.; Cote, A. P. Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191 https://doi.org/10.1073/pnas.0602439103	journal	June 2006
Modeling of the Separation of Propene/Propane Mixtures by Permeation through Membranes in a Polymerization System Castoldi, Marcelo T.; Pinto, José C.; Melo, Príamo A. Industrial & Engineering Chemistry Research, Vol. 46, Issue 4 https://doi.org/10.1021/ie060333q	journal	February 2007
Membrane Retrofit Option for Paraffin/Olefin Separation—A Technoeconomic Evaluation Motelica, Anatolie; Bruinsma, Odolphus S. L.; Kreiter, Robert Industrial & Engineering Chemistry Research, Vol. 51, Issue 19 https://doi.org/10.1021/ie300587u	journal	May 2012

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