skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Low-Valence Metal Single Atoms on Graphdiyne Promotes Electrochemical Nitrogen Reduction via M-to-N 2 π-Backdonation

Journal Article · · Advanced Functional Materials

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
~OTHER
DOE Contract Number:
SC0012704
OSTI ID:
1880659
Report Number(s):
BNL-223118-0001-JACI
Journal Information:
Advanced Functional Materials, Vol. 32, Issue 24
Publisher:
Wiley
Country of Publication:
United States
Language:
English

References (49)

Catalysts for nitrogen reduction to ammonia journal July 2018
How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully journal January 2019
Challenges in reduction of dinitrogen by proton and electron transfer journal January 2014
Heterogeneous electrocatalysts design for nitrogen reduction reaction under ambient conditions journal July 2019
A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements journal May 2019
The Difficulty of Proving Electrochemical Ammonia Synthesis journal October 2019
Regulating kinetics and thermodynamics of electrochemical nitrogen reduction with metal single-atom catalysts in a pressurized electrolyser journal November 2020
Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia journal March 2019
Scalable synthesis of nanoporous boron for high efficiency ammonia electrosynthesis journal September 2020
Au Sub-Nanoclusters on TiO 2 toward Highly Efficient and Selective Electrocatalyst for N 2 Conversion to NH 3 at Ambient Conditions journal February 2017
Greatly Improving Electrochemical N 2 Reduction over TiO 2 Nanoparticles by Iron Doping journal October 2019
Corrosion-Induced Cl-Doped Ultrathin Graphdiyne toward Electrocatalytic Nitrogen Reduction at Ambient Conditions journal October 2019
Ammonia Electrosynthesis with High Selectivity under Ambient Conditions via a Li + Incorporation Strategy journal July 2017
High-performance artificial nitrogen fixation at ambient conditions using a metal-free electrocatalyst journal August 2018
Atomically dispersed Au1 catalyst towards efficient electrochemical synthesis of ammonia journal October 2018
Electrocatalytically Active Fe‐(O‐C 2 ) 4 Single‐Atom Sites for Efficient Reduction of Nitrogen to Ammonia journal May 2020
Atomically Dispersed Molybdenum Catalysts for Efficient Ambient Nitrogen Fixation journal January 2019
Nitrogenase-Inspired Atomically Dispersed Fe–S–C Linkages for Improved Electrochemical Reduction of Dinitrogen to Ammonia journal January 2022
Building Up a Picture of the Electrocatalytic Nitrogen Reduction Activity of Transition Metal Single-Atom Catalysts journal April 2019
Single Mo Atom Supported on Defective Boron Nitride Monolayer as an Efficient Electrocatalyst for Nitrogen Fixation: A Computational Study journal August 2017
Dinitrogen Functionalization Affording Chromium Hydrazido Complex journal February 2019
Atomically dispersed Fe 3+ sites catalyze efficient CO 2 electroreduction to CO journal June 2019
Anchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution journal April 2018
Highly Efficient and Selective Generation of Ammonia and Hydrogen on a Graphdiyne-Based Catalyst journal May 2019
Graphdiyne-Supported Single-Atom-Sized Fe Catalysts for the Oxygen Reduction Reaction: DFT Predictions and Experimental Validations journal October 2018
Few-layer graphdiyne doped with sp-hybridized nitrogen atoms at acetylenic sites for oxygen reduction electrocatalysis journal August 2018
An XPS study of the UV reduction and photochromism of MoO 3 and WO 3 journal January 1982
Photoelectron diffraction on clean W(110) surface and bulk 4 f core levels journal May 1988
Electronic structure of rhenium oxides journal January 1981
Photoelectron-spectroscopic study of nickel, manganese and cobalt selenides journal January 1984
XPS spectra of some transition metal and alkaline earth monochalcogenides journal August 1976
Proton-filtering covalent organic frameworks with superior nitrogen penetration flux promote ambient ammonia synthesis journal April 2021
Graphyne and Its Family: Recent Theoretical Advances journal April 2018
Graphdiyne and graphyne: from theoretical predictions to practical construction journal January 2014
Double transition metal atoms anchored on Graphdiyne as promising catalyst for electrochemical nitrogen reduction reaction journal June 2021
Transition Metal‐dinitrogen Complex Embedded Graphene for Nitrogen Reduction Reaction journal May 2019
A General Two‐Step Strategy–Based High‐Throughput Screening of Single Atom Catalysts for Nitrogen Fixation journal December 2018
Theoretical Evaluation of Possible 2D Boron Monolayer in N 2 Electrochemical Conversion into Ammonia journal October 2018
A theoretical evaluation of possible transition metal electro-catalysts for N 2 reduction journal January 2012
Screening a Suitable Mo Form Supported on Graphdiyne for Effectively Electrocatalytic N 2 Reduction Reaction: From Atomic Catalyst to Cluster Catalyst journal September 2020
Atomically embedded asymmetrical dual-metal dimers on N-doped graphene for ultra-efficient nitrogen reduction reaction journal August 2020
Coordination tunes the activity and selectivity of the nitrogen reduction reaction on single-atom iron catalysts: a computational study journal January 2021
Computational Evaluation of Electrocatalytic Nitrogen Reduction on TM Single-, Double-, and Triple-Atom Catalysts (TM = Mn, Fe, Co, Ni) Based on Graphdiyne Monolayers journal July 2019
Graphdiyne coordinated transition metals as single-atom catalysts for nitrogen fixation journal January 2020
Theoretical Investigation of Single and Double Transition Metals Anchored on Graphyne Monolayer for Nitrogen Reduction Reaction journal June 2020
Impact of H-termination on the nitrogen reduction reaction of molybdenum carbide as an electrochemical catalyst journal January 2018
Advances in Electrocatalytic N 2 Reduction—Strategies to Tackle the Selectivity Challenge journal October 2018
Electrochemical Ammonia Synthesis—The Selectivity Challenge journal December 2016
Exploration of iron borides as electrochemical catalysts for the nitrogen reduction reaction journal January 2019