Aqueous phase hydrodechlorination of trichloroethylene using Pd supported on swellable organically m

Ailawar, Saurabh; Hunoor, Anagha; Basu, Dishari; Rudzinski, Benjamin; Burel, Laurence; Millet, Jean-Marc M.; Miller, Jeffrey T.; Edmiston, Paul L.; Ozkan, Umit S.

doi:10.1016/j.jcat.2022.04.031

Title: Aqueous phase hydrodechlorination of trichloroethylene using Pd supported on swellable organically m

Journal Article · 01 July 2022 · J. Catal.

DOI:https://doi.org/10.1016/j.jcat.2022.04.031· OSTI ID:1879735

Ailawar, Saurabh; Hunoor, Anagha; Basu, Dishari; Rudzinski, Benjamin; Burel, Laurence; Millet, Jean-Marc M.; Miller, Jeffrey T.; Edmiston, Paul L.; Ozkan, Umit S.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: DOE - Office Of Science; National Science Foundation (NSF)

OSTI ID:: 1879735

Journal Information:: J. Catal., Vol. 411

Country of Publication:: United States

Language:: ENGLISH

References (73)

Bridged Polysilsesquioxanes. Molecular-Engineered Hybrid Organic−Inorganic Materials Shea, K. J.; Loy, D. A. Chemistry of Materials, Vol. 13, Issue 10 https://doi.org/10.1021/cm011074s	journal	October 2001
Arylsilsesquioxane gels and related materials. New hybrids of organic and inorganic networks Shea, K. J.; Loy, D. A.; Webster, O. Journal of the American Chemical Society, Vol. 114, Issue 17 https://doi.org/10.1021/ja00043a014	journal	August 1992
Bridged Polysilsesquioxanes. Highly Porous Hybrid Organic-Inorganic Materials Loy, Douglas A.; Shea, Kenneth J. Chemical Reviews, Vol. 95, Issue 5 https://doi.org/10.1021/cr00037a013	journal	July 1995
Hybrid materials and silica: drastic control of surfaces and porosity of xerogels via ageing temperature, and influence of drying step on polycondensation at silicon Cerveau, Genevi??ve; Corriu, Robert J. P.; Framery, Eric Journal of Materials Chemistry, Vol. 12, Issue 10 https://doi.org/10.1039/b205648h	journal	August 2002
Organic–Inorganic Hybrid Materials that Rapidly Swell in Non-Polar Liquids: Nanoscale Morphology and Swelling Mechanism Burkett, Colleen M.; Underwood, Laura A.; Volzer, Rebecca S. Chemistry of Materials, Vol. 20, Issue 4 https://doi.org/10.1021/cm0716001	journal	February 2008
Highly swellable sol–gels prepared by chemical modification of silanol groups prior to drying Burkett, Colleen M.; Edmiston, Paul L. Journal of Non-Crystalline Solids, Vol. 351, Issue 40-42 https://doi.org/10.1016/j.jnoncrysol.2005.08.015	journal	October 2005
Reducing residual silanol interactions in reversed-phase liquid chromatography Sunseri, J. David; Cooper, William T.; Dorsey, John G. Journal of Chromatography A, Vol. 1011, Issue 1-2 https://doi.org/10.1016/S0021-9673(03)01070-7	journal	September 2003
Mechanism and Kinetics of Hexamethyldisilazane Reaction with a Fumed Silica Surface Gun'ko, V. M.; Vedamuthu, M. S.; Henderson, G. L. Journal of Colloid and Interface Science, Vol. 228, Issue 1 https://doi.org/10.1006/jcis.2000.6934	journal	August 2000
Chemical Modification of Crystalline Porous Silicon Surfaces Song, Jae Hee; Sailor, Michael J. Comments on Inorganic Chemistry, Vol. 21, Issue 1-3 https://doi.org/10.1080/02603599908020416	journal	April 1999
Silylation of mesoporous silica MCM-41 with the mixture of Cl(CH2)3SiCl3 and CH3SiCl3: combination of adjustable grafting density and improved hydrothermal stability Yang, Hengquan; Zhang, Gaoyong; Hong, Xinlin Microporous and Mesoporous Materials, Vol. 68, Issue 1-3 https://doi.org/10.1016/j.micromeso.2003.12.014	journal	March 2004
Silica: backbone material of liquid chromatographic column packings Berthod, Alain Journal of Chromatography A, Vol. 549 https://doi.org/10.1016/S0021-9673(00)91415-8	journal	January 1991
Silylation of a Co/SiO ₂ Catalyst. Characterization and Exploitation of the CO Hydrogenation Reaction Ojeda, Manuel; Pérez-Alonso, Francisco José; Terreros, Pilar Langmuir, Vol. 22, Issue 7 https://doi.org/10.1021/la052980c	journal	March 2006
Changes in the surface hydrophobicity degree of a MCM-41 used as iron support: a pathway to improve the activity and the olefins production in the Fischer–Tropsch synthesis Fellenz, N. A.; Bengoa, J. F.; Cagnoli, M. V. Journal of Porous Materials, Vol. 24, Issue 4 https://doi.org/10.1007/s10934-016-0342-5	journal	December 2016
Silylated Co3O4-m-SiO2 catalysts for Fischer–Tropsch synthesis Xie, Rongyong; Li, Debao; Hou, Bo Catalysis Communications, Vol. 12, Issue 7 https://doi.org/10.1016/j.catcom.2010.12.013	journal	March 2011
Effect of High Temperature on Swellable Organically Modified Silica (SOMS) and Its Application for Preferential CO Oxidation in H ₂ Rich Environment Basu, Dishari; Ailawar, Saurabh; Celik, Gokhan ChemCatChem, Vol. 12, Issue 14 https://doi.org/10.1002/cctc.202000397	journal	May 2020
Enhancement in the reducibility of cobalt oxides on a mesoporous silica supported cobalt catalyst Kim, Dae Jung; Dunn, Brian C.; Cole, Paul Chemical Communications, Issue 11 https://doi.org/10.1039/b417536k	journal	January 2005
Effect of Silylation of SBA-15 on Its Supported Cobalt Catalysts for Fischer-Tropsch Synthesis Shan, Yuanyuan; Liew, Kongyong; Li, Jinlin Chinese Journal of Catalysis, Vol. 30, Issue 11 https://doi.org/10.1016/S1872-2067(08)60141-2	journal	November 2009
Adsorption of Gas Phase Organic Compounds by Swellable Organically Modified Silica Edmiston, Paul L.; West, Laura J.; Chin, Alison Industrial & Engineering Chemistry Research, Vol. 55, Issue 46 https://doi.org/10.1021/acs.iecr.6b02403	journal	November 2016
Absorption of dissolved organic species from water using organically modified silica that swells Edmiston, Paul L.; Underwood, Laura A. Separation and Purification Technology, Vol. 66, Issue 3 https://doi.org/10.1016/j.seppur.2009.02.001	journal	May 2009
Absorption of short-chain to long-chain perfluoroalkyl substances using swellable organically modified silica Stebel, Eva K.; Pike, Kyndal A.; Nguyen, Huan Environmental Science: Water Research & Technology, Vol. 5, Issue 11 https://doi.org/10.1039/C9EW00364A	journal	January 2019
Effect of high-temperature on the swellable organically-modified silica (SOMS) and its application to gas-phase hydrodechlorination of trichloroethylene Sohn, Hyuntae; Celik, Gokhan; Gunduz, Seval Applied Catalysis B: Environmental, Vol. 209 https://doi.org/10.1016/j.apcatb.2017.02.056	journal	July 2017
Hydrodechlorination of trichloroethylene over Pd supported on swellable organically-modified silica (SOMS) Sohn, Hyuntae; Celik, Gokhan; Gunduz, Seval Applied Catalysis B: Environmental, Vol. 203 https://doi.org/10.1016/j.apcatb.2016.10.032	journal	April 2017
Aqueous-phase hydrodechlorination of trichloroethylene over Pd-based swellable organically-modified silica (SOMS): Catalyst deactivation due to chloride anions Celik, Gokhan; Ailawar, Saurabh A.; Gunduz, Seval Applied Catalysis B: Environmental, Vol. 239 https://doi.org/10.1016/j.apcatb.2018.08.065	journal	December 2018
Aqueous-Phase Hydrodechlorination of Trichloroethylene over Pd-Based Swellable Organically Modified Silica: Catalyst Deactivation Due to Sulfur Species Celik, Gokhan; Ailawar, Saurabh A.; Gunduz, Seval Industrial & Engineering Chemistry Research, Vol. 58, Issue 10 https://doi.org/10.1021/acs.iecr.8b05979	journal	February 2019
Formation of carbonaceous deposits on Pd-based hydrodechlorination catalysts: Vibrational spectroscopy investigations over Pd/Al2O3 and Pd/SOMS Celik, Gokhan; Ailawar, Saurabh A.; Gunduz, Seval Catalysis Today, Vol. 323 https://doi.org/10.1016/j.cattod.2018.05.001	journal	February 2019
Swellable Organically Modified Silica (SOMS) as a Catalyst Scaffold for Catalytic Treatment of Water Contaminated with Trichloroethylene Celik, Gokhan; Ailawar, Saurabh A.; Sohn, Hyuntae ACS Catalysis, Vol. 8, Issue 8 https://doi.org/10.1021/acscatal.8b01700	journal	June 2018
On the dual role of the reactant during aqueous phase hydrodechlorination of trichloroethylene (HDC of TCE) using Pd supported on swellable organically modified silica (SOMS) Ailawar, Saurabh; Hunoor, Anagha; Rudzinski, Benjamin Applied Catalysis B: Environmental, Vol. 291 https://doi.org/10.1016/j.apcatb.2021.120060	journal	August 2021
Elucidating the role of ethanol in aqueous phase hydrodechlorination of trichloroethylene over Pd catalysts supported on swellable organically modified silica (SOMS) Ailawar, Saurabh; Hunoor, Anagha; Khalifa, Yehia Applied Catalysis B: Environmental, Vol. 285 https://doi.org/10.1016/j.apcatb.2020.119819	journal	May 2021
Hydrodehalogenation of 1- to 3-Carbon Halogenated Organic Compounds in Water Using a Palladium Catalyst and Hydrogen Gas Lowry, Gregory V.; Reinhard, Martin Environmental Science & Technology, Vol. 33, Issue 11 https://doi.org/10.1021/es980963m	journal	June 1999
Pd-Catalyzed TCE Dechlorination in Groundwater: Solute Effects, Biological Control, and Oxidative Catalyst Regeneration Lowry, Gregory V.; Reinhard, Martin Environmental Science & Technology, Vol. 34, Issue 15 https://doi.org/10.1021/es991416j	journal	August 2000
Pd-Catalyzed TCE Dechlorination in Water: Effect of [H ₂ ](aq) and H ₂ -Utilizing Competitive Solutes on the TCE Dechlorination Rate and Product Distribution Lowry, Gregory V.; Reinhard, Martin Environmental Science & Technology, Vol. 35, Issue 4 https://doi.org/10.1021/es001623f	journal	February 2001
Critical Review of Pd-Based Catalytic Treatment of Priority Contaminants in Water Chaplin, Brian P.; Reinhard, Martin; Schneider, William F. Environmental Science & Technology, Vol. 46, Issue 7 https://doi.org/10.1021/es204087q	journal	March 2012
Supported Transition Metal Catalysts for Hydrodechlorination Reactions Keane, Mark A. ChemCatChem, Vol. 3, Issue 5 https://doi.org/10.1002/cctc.201000432	journal	April 2011
Catalytic hydrodechlorination of groundwater contaminants in water and in the gas phase using Pd/γ-Al2O3 Kopinke, Frank-Dieter; Mackenzie, Katrin; Köhler, Robert Applied Catalysis B: Environmental, Vol. 44, Issue 1 https://doi.org/10.1016/S0926-3373(03)00006-7	journal	August 2003
Groundwater diffuse pollution in functional urban areas: The need to define anthropogenic diffuse pollution background levels Azzellino, Arianna; Colombo, Loris; Lombi, Silvia Science of The Total Environment, Vol. 656 https://doi.org/10.1016/j.scitotenv.2018.11.416	journal	March 2019
Reproductive and developmental health effects of prenatal exposure to tetrachloroethylene-contaminated drinking water Aschengrau, Ann; Winter, Michael R.; Gallagher, Lisa G. Environmental Science: Processes & Impacts, Vol. 22, Issue 3 https://doi.org/10.1039/C9EM00590K	journal	January 2020
Carcinogenicity of trichloroethylene, tetrachloroethylene, some other chlorinated solvents, and their metabolites Guha, Neela; Loomis, Dana; Grosse, Yann The Lancet Oncology, Vol. 13, Issue 12 https://doi.org/10.1016/S1470-2045(12)70485-0	journal	December 2012
Trichloroethylene: Mechanistic, epidemiologic and other supporting evidence of carcinogenic hazard Rusyn, Ivan; Chiu, Weihsueh A.; Lash, Lawrence H. Pharmacology & Therapeutics, Vol. 141, Issue 1 https://doi.org/10.1016/j.pharmthera.2013.08.004	journal	January 2014
Chlorinated Solvents in Groundwater of the United States Moran, Michael J.; Zogorski, John S.; Squillace, Paul J. Environmental Science & Technology, Vol. 41, Issue 1 https://doi.org/10.1021/es061553y	journal	January 2007
Catalytic hydrodehalogenation of chlorinated ethylenes using palladium and hydrogen for the treatment of contaminated water Schreier, Cindy G.; Reinhard, Martin Chemosphere, Vol. 31, Issue 6 https://doi.org/10.1016/0045-6535(95)00200-R	journal	September 1995
Deactivation of a Pd/Al2O3 catalyst used in hydrodechlorination reactions: Influence of the nature of organochlorinated compound and hydrogen chloride Lopez, E.; Ordonez, S.; Diez, F. Applied Catalysis B: Environmental, Vol. 62, Issue 1-2 https://doi.org/10.1016/j.apcatb.2005.06.014	journal	January 2006
Protection of palladium catalysts for hydrodechlorination of chlorinated organic compounds in wastewaters Navon, Rotem; Eldad, Shay; Mackenzie, Katrin Applied Catalysis B: Environmental, Vol. 119-120 https://doi.org/10.1016/j.apcatb.2012.03.002	journal	May 2012
Efforts for long-term protection of palladium hydrodechlorination catalysts Comandella, Daniele; Woszidlo, Silke; Georgi, Anett Applied Catalysis B: Environmental, Vol. 186 https://doi.org/10.1016/j.apcatb.2015.12.043	journal	June 2016
Designing Pd-on-Au Bimetallic Nanoparticle Catalysts for Trichloroethene Hydrodechlorination Nutt, Michael O.; Hughes, Joseph B.; Wong, Michael S. Environmental Science & Technology, Vol. 39, Issue 5 https://doi.org/10.1021/es048560b	journal	March 2005
Improved Pd-on-Au bimetallic nanoparticle catalysts for aqueous-phase trichloroethene hydrodechlorination Nutt, Michael O.; Heck, Kimberly N.; Alvarez, Pedro Applied Catalysis B: Environmental, Vol. 69, Issue 1-2 https://doi.org/10.1016/j.apcatb.2006.06.005	journal	December 2006
Hydrodechlorination of Trichloroethylene to Hydrocarbons Using Bimetallic Nickel−Iron Nanoparticles Schrick, Bettina; Blough, Jennifer L.; Jones, A. Daniel Chemistry of Materials, Vol. 14, Issue 12 https://doi.org/10.1021/cm020737i	journal	December 2002
Liquid phase hydrodechlorination of chlorophenols over Pd/C and Pd/Al2O3: a consideration of HCl/catalyst interactions and solution pH effects Yuan, Guang; Keane, Mark A. Applied Catalysis B: Environmental, Vol. 52, Issue 4 https://doi.org/10.1016/j.apcatb.2004.04.015	journal	October 2004
Role of base addition in the liquid-phase hydrodechlorination of 2,4-dichlorophenol over Pd/Al2O3 and Pd/C Yuan, G. Journal of Catalysis, Vol. 225, Issue 2 https://doi.org/10.1016/j.jcat.2004.05.003	journal	July 2004
The Effect of NaOH on the Liquid-Phase Hydrodechlorination of Dioxins over Pd/γ-Al ₂ O ₃ Cobo, Martha I.; Conesa, Juan A.; Montes de Correa, Consuelo The Journal of Physical Chemistry A, Vol. 112, Issue 37 https://doi.org/10.1021/jp802570t	journal	September 2008
Adsorption of Gases in Multimolecular Layers Brunauer, Stephen; Emmett, P. H.; Teller, Edward Journal of the American Chemical Society, Vol. 60, Issue 2, p. 309-319 https://doi.org/10.1021/ja01269a023	journal	February 1938
The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms Barrett, Elliott P.; Joyner, Leslie G.; Halenda, Paul P. Journal of the American Chemical Society, Vol. 73, Issue 1 https://doi.org/10.1021/ja01145a126	journal	January 1951
NIH Image to ImageJ: 25 years of image analysis Schneider, Caroline A.; Rasband, Wayne S.; Eliceiri, Kevin W. Nature Methods, Vol. 9, Issue 7 https://doi.org/10.1038/nmeth.2089	journal	June 2012
The New MRCAT (Sector 10) Bending Magnet Beamline at the Advanced Photon Source Kropf, A. J.; Katsoudas, J.; Chattopadhyay, S. SRI 2009, 10TH INTERNATIONAL CONFERENCE ON RADIATION INSTRUMENTATION, AIP Conference Proceedings https://doi.org/10.1063/1.3463194	conference	January 2010
Attachment of 3-(Aminopropyl)triethoxysilane on Silicon Oxide Surfaces: Dependence on Solution Temperature Pasternack, Robert M.; Rivillon Amy, Sandrine; Chabal, Yves J. Langmuir, Vol. 24, Issue 22 https://doi.org/10.1021/la8024827	journal	October 2008
Incorporation of phenoxy groups in self-assembled monolayers of trichlorosilane derivatives. Effects on film thickness, wettability, and molecular orientation Tillman, Nolan.; Ulman, Abraham.; Schildkraut, Jay S. Journal of the American Chemical Society, Vol. 110, Issue 18 https://doi.org/10.1021/ja00226a031	journal	August 1988
Synthesis, Characterization and Microstructure of New Liquid Poly(methylhydrosiloxanes) Containing Branching Units SiO4/2 Chruściel, Jerzy; Fejdyś, Marzena; Fortuniak, Witold Polymers, Vol. 10, Issue 5 https://doi.org/10.3390/polym10050484	journal	April 2018
Reaction of chloromethylsilanes with silica: a low-frequency infrared study Tripp, C. P.; Hair, M. L. Langmuir, Vol. 7, Issue 5 https://doi.org/10.1021/la00053a019	journal	May 1991
Infrared spectra-structure correlations for organosilicon compounds Smith, A. Lee Spectrochimica Acta, Vol. 16, Issue 1-2 https://doi.org/10.1016/0371-1951(60)80074-4	journal	January 1960
Thermal polydimethylsiloxane degradation. Part 2. The degradation mechanisms Camino, G.; Lomakin, S. M.; Lageard, M. Polymer, Vol. 43, Issue 7 https://doi.org/10.1016/S0032-3861(01)00785-6	journal	March 2002
Spectroscopic Techniques for Identification of Organosilicon Compounds Smith, A. L.; McHard, J. A. Analytical Chemistry, Vol. 31, Issue 7 https://doi.org/10.1021/ac60151a029	journal	July 1959
Silicalite characterization. 2. IR spectroscopy of the interaction of carbon monoxide with internal and external hydroxyl groups Zecchina, A.; Bordiga, S.; Spoto, G. The Journal of Physical Chemistry, Vol. 96, Issue 12 https://doi.org/10.1021/j100191a048	journal	June 1992
Infrared and gravimetric study of an aerosil and a precipitated silica using chemical and hydrogen/deuterium exchange probes Morrow, B. A.; McFarlan, A. J. Langmuir, Vol. 7, Issue 8 https://doi.org/10.1021/la00056a022	journal	August 1991
Structural Studies on Semiconducting Hydrogenated Amorphous Silicon Oxide Films Iftiquar, S. M. High Temperature Material Processes (An International Quarterly of High-Technology Plasma Processes), Vol. 6, Issue 1 https://doi.org/10.1615/HighTempMatProc.v6.i1.40	journal	January 2002
Chemical Bonding Structure of Low Dielectric Constant Si:O:C:H Films Characterized by Solid-State NMR Mabboux, Pierre-Yves; Gleason, Karen K. Journal of The Electrochemical Society, Vol. 152, Issue 1 https://doi.org/10.1149/1.1830353	journal	January 2005
IR spectroscopic investigation of SiO2 film structure Lisovskii, I. P.; Litovchenko, V. G.; Lozinskii, V. G. Thin Solid Films, Vol. 213, Issue 2 https://doi.org/10.1016/0040-6090(92)90278-J	journal	June 1992
Morphology and Surface Properties of Titania−Silica Hydrophobic Xerogels Mariscal, R.; López-Granados, M.; Fierro, J. L. G. Langmuir, Vol. 16, Issue 24 https://doi.org/10.1021/la000876j	journal	October 2000
Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) Thommes, Matthias; Kaneko, Katsumi; Neimark, Alexander V. Pure and Applied Chemistry, Vol. 87, Issue 9-10 https://doi.org/10.1515/pac-2014-1117	journal	October 2015
Sol—Gel preparation of supported metal catalysts Gonzalez, Richard D.; Lopez, Tessie; Gomez, Ricardo Catalysis Today, Vol. 35, Issue 3 https://doi.org/10.1016/S0920-5861(96)00162-9	journal	March 1997
The effect of gold particle size on AuAu bond length and reactivity toward oxygen in supported catalysts Miller, J. T.; Kropf, A. J.; Zha, Y. Journal of Catalysis, Vol. 240, Issue 2 https://doi.org/10.1016/j.jcat.2006.04.004	journal	June 2006
An in situ XAS study of the activation of precursor-dependent Pd nanoparticles Lopes, Christian W.; Cerrillo, Jose L.; Palomares, Antonio E. Physical Chemistry Chemical Physics, Vol. 20, Issue 18 https://doi.org/10.1039/C8CP00517F	journal	January 2018
Observing Metal-Catalyzed Chemical Reactions in Situ Using Surface-Enhanced Raman Spectroscopy on Pd−Au Nanoshells Heck, Kimberly N.; Janesko, Benjamin G.; Scuseria, Gustavo E. Journal of the American Chemical Society, Vol. 130, Issue 49 https://doi.org/10.1021/ja803556k	journal	December 2008
Pd-catalyzed hydrodehalogenation of chlorinated olefins: Theoretical insights to the reaction mechanism Andersin, Jenni; Parkkinen, Pauli; Honkala, Karoliina Journal of Catalysis, Vol. 290 https://doi.org/10.1016/j.jcat.2012.03.006	journal	June 2012
The graphene-supported palladium and palladium–yttrium nanoparticles for the oxygen reduction and ethanol oxidation reactions: Experimental measurement and computational validation Seo, Min Ho; Choi, Sung Mook; Seo, Joon Kyo Applied Catalysis B: Environmental, Vol. 129 https://doi.org/10.1016/j.apcatb.2012.09.005	journal	January 2013

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