Photoreversible Order?Disorder Transitions in Block Copolymer/Ionic Liquid Solutions

Seitzinger, Claire L.; Hall, Cecilia C.; Lodge, Timothy P.

doi:10.1021/acs.macromol.2c00397

Title: Photoreversible Order?Disorder Transitions in Block Copolymer/Ionic Liquid Solutions

Journal Article · 01 May 2022 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.2c00397· OSTI ID:1878365

Seitzinger, Claire L.; Hall, Cecilia C.; Lodge, Timothy P.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: DOE - Office Of Science; National Science Foundation (NSF)

OSTI ID:: 1878365

Journal Information:: Macromolecules, Vol. 55, Issue (10)

Country of Publication:: United States

Language:: ENGLISH

References (55)

Correlations between Salt-Induced Crystallization, Morphology, Segmental Dynamics, and Conductivity in Amorphous Block Copolymer Electrolytes Thelen, Jacob L.; Wang, Andrew A.; Chen, X. Chelsea Macromolecules, Vol. 51, Issue 5 https://doi.org/10.1021/acs.macromol.7b02415	journal	February 2018
Three-Dimensional Bicontinuous Nanocomposite from a Self-Assembled Block Copolymer for a High-Capacity All-Solid-State Lithium Battery Cathode Wakayama, Hiroaki; Yonekura, Hirotaka; Kawai, Yasuaki Chemistry of Materials, Vol. 28, Issue 12 https://doi.org/10.1021/acs.chemmater.6b01665	journal	June 2016
Ionic-Liquid-Based Proton Conducting Membranes for Anhydrous H ₂ /Cl ₂ Fuel-Cell Applications Liu, Sa; Zhou, Li; Wang, Pengjie ACS Applied Materials & Interfaces, Vol. 6, Issue 5 https://doi.org/10.1021/am404645c	journal	February 2014
Polymer electrolytes integrated with ionic liquids for future electrochemical devices Park, Moon Jeong; Choi, Ilyoung; Hong, Jaewan Journal of Applied Polymer Science, Vol. 129, Issue 5 https://doi.org/10.1002/app.39064	journal	February 2013
Hierarchically Porous Polymer Monoliths by Combining Controlled Macro- and Microphase Separation Saba, Stacey A.; Mousavi, Maral P. S.; Bühlmann, Philippe Journal of the American Chemical Society, Vol. 137, Issue 28 https://doi.org/10.1021/jacs.5b04992	journal	July 2015
Robust Nanoporous Membranes Templated by a Doubly Reactive Block Copolymer Chen, Liang; Phillip, William A.; Cussler, E. L. Journal of the American Chemical Society, Vol. 129, Issue 45 https://doi.org/10.1021/ja0753041	journal	November 2007
ABAC Tetrablock Terpolymers for Tough Nanoporous Filtration Membranes Jackson, Elizabeth A.; Lee, Youngmin; Hillmyer, Marc A. Macromolecules, Vol. 46, Issue 4 https://doi.org/10.1021/ma302414w	journal	February 2013
Diffusion and Flow Across Nanoporous Polydicyclopentadiene-Based Membranes Phillip, William A.; Amendt, Mark; O’Neill, Brandon ACS Applied Materials & Interfaces, Vol. 1, Issue 2 https://doi.org/10.1021/am8001428	journal	January 2009
Recent developments in stimuli-responsive polymer nanogels for drug delivery and diagnostics: A review Preman, Namitha K.; Barki, Rashmi R.; Vijayan, Anjali European Journal of Pharmaceutics and Biopharmaceutics, Vol. 157 https://doi.org/10.1016/j.ejpb.2020.10.009	journal	December 2020
Stimuli-Responsive Polymers for Sensing and Reacting to Environmental Conditions Zhang, Qiang; Zhang, Yingnan; Wan, Yu Progress in Polymer Science, Vol. 116 https://doi.org/10.1016/j.progpolymsci.2021.101386	journal	May 2021
Reversible Adhesion Switching Using Spiropyran Photoisomerization in a High Glass Transition Temperature Polymer Gately, Thomas J.; Li, Wangxiang; Mostafavi, Seyed Hossein Macromolecules, Vol. 54, Issue 20 https://doi.org/10.1021/acs.macromol.1c01262	journal	October 2021
Unusual Aggregation Behavior of a Novel Tertiary Amine Methacrylate-Based Diblock Copolymer: Formation of Micelles and Reverse Micelles in Aqueous Solution Bütün, V.; Billingham, N. C.; Armes, S. P. Journal of the American Chemical Society, Vol. 120, Issue 45 https://doi.org/10.1021/ja982295a	journal	November 1998
The effect of light penetration depth on the LCST phase behavior of a thermo‐ and photoresponsive statistical copolymer in an ionic liquid Hall, Cecilia C.; Rivera, Cecelia A.; Lodge, Timothy P. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 57, Issue 3 https://doi.org/10.1002/pola.29075	journal	August 2018
Photoreversible Gelation of a Triblock Copolymer in an Ionic Liquid Ueki, Takeshi; Nakamura, Yutaro; Usui, Ryoji Angewandte Chemie International Edition, Vol. 54, Issue 10 https://doi.org/10.1002/anie.201411526	journal	January 2015
Unusual Lower Critical Solution Temperature Phase Behavior of Poly(ethylene oxide) in Ionic Liquids Lee, Hau-Nan; Newell, Nakisha; Bai, Zhifeng Macromolecules, Vol. 45, Issue 8 https://doi.org/10.1021/ma300335p	journal	April 2012
Evidence for Lower Critical Solution Behavior in Ionic Liquid Solutions Lachwa, Joanna; Szydlowski, Jerzy; Najdanovic-Visak, Vesna Journal of the American Chemical Society, Vol. 127, Issue 18 https://doi.org/10.1021/ja0510257	journal	April 2005
Explanation for the Unusual Phase Behavior of Polystyrene- b -poly( n -alkyl methacrylate) Diblock Copolymers: Specific Interactions Dudowicz, Jacek; Freed, Karl F. Macromolecules, Vol. 33, Issue 14 https://doi.org/10.1021/ma000232i	journal	July 2000
A lower critical ordering transition in a diblock copolymer melt Russell, T. P.; Karis, T. E.; Gallot, Y. Nature, Vol. 368, Issue 6473 https://doi.org/10.1038/368729a0	journal	April 1994
Closed-loop phase behaviour in block copolymers Yeol Ryu, Du; Jeong, Unyong; Kon Kim, Jin Nature Materials, Vol. 1, Issue 2 https://doi.org/10.1038/nmat724	journal	September 2002
Phase Behavior of Diblock Copolymers between Styrene and n -Alkyl Methacrylates Ruzette, A. -V. G.; Banerjee, P.; Mayes, A. M. Macromolecules, Vol. 31, Issue 24 https://doi.org/10.1021/ma981055c	journal	November 1998
Stimuli-responsive polymers in ionic liquids Ueki, Takeshi Polymer Journal, Vol. 46, Issue 10 https://doi.org/10.1038/pj.2014.37	journal	May 2014
Poly( N -isopropylacrylamide) Phase Diagrams: Fifty Years of Research Halperin, Avraham; Kröger, Martin; Winnik, Françoise M. Angewandte Chemie International Edition, Vol. 54, Issue 51 https://doi.org/10.1002/anie.201506663	journal	November 2015
Volumetric Studies of Aqueous Polymer Solutions Using Pressure Perturbation Calorimetry: A New Look at the Temperature-Induced Phase Transition of Poly( N -isopropylacrylamide) in Water and D ₂ O Kujawa, Piotr; Winnik, Françoise M. Macromolecules, Vol. 34, Issue 12 https://doi.org/10.1021/ma002082h	journal	May 2001
Solution Properties of Poly(N-isopropylacrylamide) Heskins, M.; Guillet, J. E. Journal of Macromolecular Science: Part A - Chemistry, Vol. 2, Issue 8 https://doi.org/10.1080/10601326808051910	journal	December 1968
Poly( n -butyl methacrylate) in Ionic Liquids with Tunable Lower Critical Solution Temperatures (LCST) Lee, Hau-Nan; Lodge, Timothy P. The Journal of Physical Chemistry B, Vol. 115, Issue 9 https://doi.org/10.1021/jp1106058	journal	March 2011
Lower Critical Solution Temperature Phase Behavior of Poly( n -butyl methacrylate) in Ionic Liquid Mixtures Hoarfrost, Megan L.; He, Yanpu; Lodge, Timothy P. Macromolecules, Vol. 46, Issue 23 https://doi.org/10.1021/ma401450w	journal	November 2013
Thermodynamic study on phase transitions of poly(benzyl methacrylate) in ionic liquid solvents Ueki, Takeshi; Arai, Asako Ayusawa; Kodama, Koichi Pure and Applied Chemistry, Vol. 81, Issue 10 https://doi.org/10.1351/PAC-CON-08-09-04	journal	September 2009
Structural aspects of the LCST phase behavior of poly(benzyl methacrylate) in room-temperature ionic liquid Fujii, Kenta; Ueki, Takeshi; Niitsuma, Kazuyuki Polymer, Vol. 52, Issue 7 https://doi.org/10.1016/j.polymer.2011.01.037	journal	March 2011
Thermosensitive Phase Separation Behavior of Poly(benzyl methacrylate)/Solvate Ionic Liquid Solutions Kobayashi, Yumi; Kitazawa, Yuzo; Hashimoto, Kei Langmuir, Vol. 33, Issue 49 https://doi.org/10.1021/acs.langmuir.7b03378	journal	December 2017
Microscopic Structure of Solvated Poly(benzyl methacrylate) in an Imidazolium-Based Ionic Liquid: High-Energy X-ray Total Scattering and All-Atom MD Simulation Study Fujii, Kenta; Ueki, Takeshi; Hashimoto, Kei Macromolecules, Vol. 50, Issue 12 https://doi.org/10.1021/acs.macromol.7b00840	journal	June 2017
SANS study on the solvated structure and molecular interactions of a thermo-responsive polymer in a room temperature ionic liquid Hirosawa, Kazu; Fujii, Kenta; Ueki, Takeshi Physical Chemistry Chemical Physics, Vol. 18, Issue 27 https://doi.org/10.1039/C6CP02254E	journal	January 2016
Photoisomerization-Induced Tunable LCST Phase Separation of Azobenzene-Containing Polymers in an Ionic Liquid Ueki, Takeshi; Yamaguchi, Ayuko; Ito, Naoki Langmuir, Vol. 25, Issue 16 https://doi.org/10.1021/la901159r	journal	August 2009
Thermally Reversible Ion Gels with Photohealing Properties Based on Triblock Copolymer Self-Assembly Ueki, Takeshi; Usui, Ryoji; Kitazawa, Yuzo Macromolecules, Vol. 48, Issue 16 https://doi.org/10.1021/acs.macromol.5b01366	journal	August 2015
Unlocking of interlocked heteropolymer gel by light: photoinduced volume phase transition in an ionic liquid from a metastable state to an equilibrium phase Ueki, Takeshi; Yamaguchi, Ayuko; Watanabe, Masayoshi Chemical Communications, Vol. 48, Issue 42 https://doi.org/10.1039/c2cc30830d	journal	January 2012
Photoinduced Reversible Worm-to-Vesicle Transformation of Azo-Containing Block Copolymer Assemblies Prepared by Polymerization-Induced Self-Assembly Ye, Qiquan; Huo, Meng; Zeng, Min Macromolecules, Vol. 51, Issue 9 https://doi.org/10.1021/acs.macromol.8b00340	journal	April 2018
Exchange Kinetics for a Single Block Copolymer in Micelles of Two Different Sizes Zhao, Dan; Ma, Yuanchi; Lodge, Timothy P. Macromolecules, Vol. 51, Issue 6 https://doi.org/10.1021/acs.macromol.7b02550	journal	March 2018
From Macromolecular to Small-Molecular Triggers: Facile Method toward Photoinduced LCST Phase Behavior of Thermoresponsive Polymers in Mixed Ionic Liquids Containing an Azobenzene Moiety Wang, Caihong; Ma, Xiaofeng; Kitazawa, Yuzo Macromolecular Rapid Communications, Vol. 37, Issue 23 https://doi.org/10.1002/marc.201600360	journal	September 2016
Reversible Ion-Conducting Switch by Azobenzene Molecule with Light-Controlled Sol–Gel Transitions of the PNIPAm Ion Gel Wang, Caihong; Dong, Weibin; Li, Peiqi ACS Applied Materials & Interfaces, Vol. 12, Issue 37 https://doi.org/10.1021/acsami.0c12910	journal	August 2020
Self-Assembly of Diblock Copolymers Containing Thermo- and Photoresponsive Lower Critical Solution Temperature Phase Behavior Polymer with Tunable Assembly Temperature in an Ionic Liquid Mixture Lan, Xiaoyu; Ma, Xiaofeng; Wang, Lei ACS Omega, Vol. 4, Issue 6 https://doi.org/10.1021/acsomega.9b01287	journal	June 2019
The Cis-form of Azobenzene Hartley, G. S. Nature, Vol. 140, Issue 3537 https://doi.org/10.1038/140281a0	journal	August 1937
989. Physical properties and chemical constitution. Part XLIII. The electric dipole moments of azobenzene, azopyridines, and azoquinolines Bullock, D. J. W.; Cumper, C. W. N.; Vogel, A. I. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9650005316	journal	January 1965
Photoreversible Order–Disorder Transition in an Ionic Liquid Solvated Block Polymer Hall, Cecilia C.; Lodge, Timothy P. ACS Macro Letters, Vol. 8, Issue 4 https://doi.org/10.1021/acsmacrolett.9b00153	journal	March 2019
Mechanistic Investigation of Smart Polymer−Protein Conjugates Shimoboji, Tsuyoshi; Ding, Zhongli; Stayton, Patrick S. Bioconjugate Chemistry, Vol. 12, Issue 2 https://doi.org/10.1021/bc000107b	journal	February 2001
Pressure and Temperature Dependence of Local Structure and Dynamics in an Ionic Liquid Lundin, Filippa; Hansen, Henriette Wase; Adrjanowicz, Karolina The Journal of Physical Chemistry B, Vol. 125, Issue 10 https://doi.org/10.1021/acs.jpcb.1c00147	journal	March 2021
Size exclusion chromatography with multiple detectors: Solution properties of linear chains of varying flexibility in tetrahydrofuran Jackson, Christian; Chen, Yuan-Ju; Mays, Jimmy W. Journal of Applied Polymer Science, Vol. 61, Issue 5 https://doi.org/10.1002/(SICI)1097-4628(19960801)61:5<865::AID-APP20>3.0.CO;2-V	journal	August 1996
Light Scattering, Size Exclusion Chromatography and Asymmetric Flow Field Flow Fractionation Podzimek, Stepan Wiley https://doi.org/10.1002/9780470877975	journal	February 2011
Determination of the composition of copolymers by differential refractometry in mixed solvents Tuzar, Zdeněk; Kratochvíl, Pavel Journal of Polymer Science Part B: Polymer Letters, Vol. 7, Issue 12 https://doi.org/10.1002/pol.1969.110071201	journal	December 1969
Lower Critical Solution Temperature Behavior of Linear Polymers in Ionic Liquids and the Corresponding Volume Phase Transition of Polymer Gels Ueki, Takeshi; Watanabe, Masayoshi Langmuir, Vol. 23, Issue 3 https://doi.org/10.1021/la062986h	journal	January 2007
Dilute Solution Properties of Poly(benzyl methacrylate) in Ionic Liquids Kharel, Aakriti; Hall, Cecilia; Černoch, Peter Macromolecules, Vol. 53, Issue 3 https://doi.org/10.1021/acs.macromol.9b02618	journal	January 2020
Unusual Lower Critical Solution Temperature Phase Behavior of Poly(benzyl methacrylate) in a Pyrrolidinium-Based Ionic Liquid Carrick, Brian R.; Seitzinger, Claire L.; Lodge, Timothy P. Molecules, Vol. 26, Issue 16 https://doi.org/10.3390/molecules26164850	journal	August 2021
Lower Critical Solution Temperature (LCST) Phase Behavior of Poly(ethylene oxide) in Ionic Liquids Lee, Hau-Nan; Lodge, Timothy P. The Journal of Physical Chemistry Letters, Vol. 1, Issue 13 https://doi.org/10.1021/jz100617t	journal	June 2010
Micelle/Inverse Micelle Self-Assembly of a PEO−PNIPAm Block Copolymer in Ionic Liquids with Double Thermoresponsivity Lee, Hau-Nan; Bai, Zhifeng; Newell, Nakisha Macromolecules, Vol. 43, Issue 22 https://doi.org/10.1021/ma1019279	journal	November 2010
Lower Critical Solution Temperature Phase Behavior of Linear Polymers in Imidazolium-Based Ionic Liquids: Effects of Structural Modifications Kodama, Koichi; Nanashima, Hideyuki; Ueki, Takeshi Langmuir, Vol. 25, Issue 6 https://doi.org/10.1021/la803945n	journal	March 2009
Phase Behavior of a Block Copolymer in Solvents of Varying Selectivity Hanley, Kenneth J.; Lodge, Timothy P.; Huang, Ching-I Macromolecules, Vol. 33, Issue 16 https://doi.org/10.1021/ma000318b	journal	August 2000
UCST Phase Transition of Azobenzene-Containing Random Copolymer in an Ionic Liquid Ueki, Takeshi; Nakamura, Yutaro; Yamaguchi, Ayuko Macromolecules, Vol. 44, Issue 17 https://doi.org/10.1021/ma2014244	journal	August 2011

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