skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Aqueous phase hydrodechlorination of trichloroethylene using Pd supported on swellable organically m

Journal Article · · J. Catal.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; National Science Foundation (NSF)
OSTI ID:
1878364
Journal Information:
J. Catal., Vol. 411
Country of Publication:
United States
Language:
ENGLISH

References (73)

Bridged Polysilsesquioxanes. Molecular-Engineered Hybrid Organic−Inorganic Materials journal October 2001
Arylsilsesquioxane gels and related materials. New hybrids of organic and inorganic networks journal August 1992
Bridged Polysilsesquioxanes. Highly Porous Hybrid Organic-Inorganic Materials journal July 1995
Hybrid materials and silica: drastic control of surfaces and porosity of xerogels via ageing temperature, and influence of drying step on polycondensation at silicon journal August 2002
Organic–Inorganic Hybrid Materials that Rapidly Swell in Non-Polar Liquids: Nanoscale Morphology and Swelling Mechanism journal February 2008
Highly swellable sol–gels prepared by chemical modification of silanol groups prior to drying journal October 2005
Reducing residual silanol interactions in reversed-phase liquid chromatography journal September 2003
Mechanism and Kinetics of Hexamethyldisilazane Reaction with a Fumed Silica Surface journal August 2000
Chemical Modification of Crystalline Porous Silicon Surfaces journal April 1999
Silylation of mesoporous silica MCM-41 with the mixture of Cl(CH2)3SiCl3 and CH3SiCl3: combination of adjustable grafting density and improved hydrothermal stability journal March 2004
Silica: backbone material of liquid chromatographic column packings journal January 1991
Silylation of a Co/SiO 2 Catalyst. Characterization and Exploitation of the CO Hydrogenation Reaction journal March 2006
Changes in the surface hydrophobicity degree of a MCM-41 used as iron support: a pathway to improve the activity and the olefins production in the Fischer–Tropsch synthesis journal December 2016
Silylated Co3O4-m-SiO2 catalysts for Fischer–Tropsch synthesis journal March 2011
Effect of High Temperature on Swellable Organically Modified Silica (SOMS) and Its Application for Preferential CO Oxidation in H 2 Rich Environment journal May 2020
Enhancement in the reducibility of cobalt oxides on a mesoporous silica supported cobalt catalyst journal January 2005
Effect of Silylation of SBA-15 on Its Supported Cobalt Catalysts for Fischer-Tropsch Synthesis journal November 2009
Adsorption of Gas Phase Organic Compounds by Swellable Organically Modified Silica journal November 2016
Absorption of dissolved organic species from water using organically modified silica that swells journal May 2009
Absorption of short-chain to long-chain perfluoroalkyl substances using swellable organically modified silica journal January 2019
Effect of high-temperature on the swellable organically-modified silica (SOMS) and its application to gas-phase hydrodechlorination of trichloroethylene journal July 2017
Hydrodechlorination of trichloroethylene over Pd supported on swellable organically-modified silica (SOMS) journal April 2017
Aqueous-phase hydrodechlorination of trichloroethylene over Pd-based swellable organically-modified silica (SOMS): Catalyst deactivation due to chloride anions journal December 2018
Aqueous-Phase Hydrodechlorination of Trichloroethylene over Pd-Based Swellable Organically Modified Silica: Catalyst Deactivation Due to Sulfur Species journal February 2019
Formation of carbonaceous deposits on Pd-based hydrodechlorination catalysts: Vibrational spectroscopy investigations over Pd/Al2O3 and Pd/SOMS journal February 2019
Swellable Organically Modified Silica (SOMS) as a Catalyst Scaffold for Catalytic Treatment of Water Contaminated with Trichloroethylene journal June 2018
On the dual role of the reactant during aqueous phase hydrodechlorination of trichloroethylene (HDC of TCE) using Pd supported on swellable organically modified silica (SOMS) journal August 2021
Elucidating the role of ethanol in aqueous phase hydrodechlorination of trichloroethylene over Pd catalysts supported on swellable organically modified silica (SOMS) journal May 2021
Hydrodehalogenation of 1- to 3-Carbon Halogenated Organic Compounds in Water Using a Palladium Catalyst and Hydrogen Gas journal June 1999
Pd-Catalyzed TCE Dechlorination in Groundwater:  Solute Effects, Biological Control, and Oxidative Catalyst Regeneration journal August 2000
Pd-Catalyzed TCE Dechlorination in Water:  Effect of [H 2 ](aq) and H 2 -Utilizing Competitive Solutes on the TCE Dechlorination Rate and Product Distribution journal February 2001
Critical Review of Pd-Based Catalytic Treatment of Priority Contaminants in Water journal March 2012
Supported Transition Metal Catalysts for Hydrodechlorination Reactions journal April 2011
Catalytic hydrodechlorination of groundwater contaminants in water and in the gas phase using Pd/γ-Al2O3 journal August 2003
Groundwater diffuse pollution in functional urban areas: The need to define anthropogenic diffuse pollution background levels journal March 2019
Reproductive and developmental health effects of prenatal exposure to tetrachloroethylene-contaminated drinking water journal January 2020
Carcinogenicity of trichloroethylene, tetrachloroethylene, some other chlorinated solvents, and their metabolites journal December 2012
Trichloroethylene: Mechanistic, epidemiologic and other supporting evidence of carcinogenic hazard journal January 2014
Chlorinated Solvents in Groundwater of the United States journal January 2007
Catalytic hydrodehalogenation of chlorinated ethylenes using palladium and hydrogen for the treatment of contaminated water journal September 1995
Deactivation of a Pd/Al2O3 catalyst used in hydrodechlorination reactions: Influence of the nature of organochlorinated compound and hydrogen chloride journal January 2006
Protection of palladium catalysts for hydrodechlorination of chlorinated organic compounds in wastewaters journal May 2012
Efforts for long-term protection of palladium hydrodechlorination catalysts journal June 2016
Designing Pd-on-Au Bimetallic Nanoparticle Catalysts for Trichloroethene Hydrodechlorination journal March 2005
Improved Pd-on-Au bimetallic nanoparticle catalysts for aqueous-phase trichloroethene hydrodechlorination journal December 2006
Hydrodechlorination of Trichloroethylene to Hydrocarbons Using Bimetallic Nickel−Iron Nanoparticles journal December 2002
Liquid phase hydrodechlorination of chlorophenols over Pd/C and Pd/Al2O3: a consideration of HCl/catalyst interactions and solution pH effects journal October 2004
Role of base addition in the liquid-phase hydrodechlorination of 2,4-dichlorophenol over Pd/Al2O3 and Pd/C journal July 2004
The Effect of NaOH on the Liquid-Phase Hydrodechlorination of Dioxins over Pd/γ-Al 2 O 3 journal September 2008
Adsorption of Gases in Multimolecular Layers journal February 1938
The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms journal January 1951
NIH Image to ImageJ: 25 years of image analysis journal June 2012
The New MRCAT (Sector 10) Bending Magnet Beamline at the Advanced Photon Source
  • Kropf, A. J.; Katsoudas, J.; Chattopadhyay, S.
  • SRI 2009, 10TH INTERNATIONAL CONFERENCE ON RADIATION INSTRUMENTATION, AIP Conference Proceedings https://doi.org/10.1063/1.3463194
conference January 2010
Attachment of 3-(Aminopropyl)triethoxysilane on Silicon Oxide Surfaces: Dependence on Solution Temperature journal October 2008
Incorporation of phenoxy groups in self-assembled monolayers of trichlorosilane derivatives. Effects on film thickness, wettability, and molecular orientation journal August 1988
Synthesis, Characterization and Microstructure of New Liquid Poly(methylhydrosiloxanes) Containing Branching Units SiO4/2 journal April 2018
Reaction of chloromethylsilanes with silica: a low-frequency infrared study journal May 1991
Infrared spectra-structure correlations for organosilicon compounds journal January 1960
Thermal polydimethylsiloxane degradation. Part 2. The degradation mechanisms journal March 2002
Spectroscopic Techniques for Identification of Organosilicon Compounds journal July 1959
Silicalite characterization. 2. IR spectroscopy of the interaction of carbon monoxide with internal and external hydroxyl groups journal June 1992
Infrared and gravimetric study of an aerosil and a precipitated silica using chemical and hydrogen/deuterium exchange probes journal August 1991
Structural Studies on Semiconducting Hydrogenated Amorphous Silicon Oxide Films journal January 2002
Chemical Bonding Structure of Low Dielectric Constant Si:O:C:H Films Characterized by Solid-State NMR journal January 2005
IR spectroscopic investigation of SiO2 film structure journal June 1992
Morphology and Surface Properties of Titania−Silica Hydrophobic Xerogels journal October 2000
Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) journal October 2015
Sol—Gel preparation of supported metal catalysts journal March 1997
The effect of gold particle size on AuAu bond length and reactivity toward oxygen in supported catalysts journal June 2006
An in situ XAS study of the activation of precursor-dependent Pd nanoparticles journal January 2018
Observing Metal-Catalyzed Chemical Reactions in Situ Using Surface-Enhanced Raman Spectroscopy on Pd−Au Nanoshells journal December 2008
Pd-catalyzed hydrodehalogenation of chlorinated olefins: Theoretical insights to the reaction mechanism journal June 2012
The graphene-supported palladium and palladium–yttrium nanoparticles for the oxygen reduction and ethanol oxidation reactions: Experimental measurement and computational validation journal January 2013