Hematite-goethite ratios at pH 2?13 and 25?170 ?C: A time-resolved synchrotron X-ray diffraction stu

Chen, Si Athena; Heaney, Peter J.; Post, Jeffrey E.; Eng, Peter J.; Stubbs, Joanne E.

doi:10.1016/j.chemgeo.2022.120995

Hematite-goethite ratios at pH 2?13 and 25?170 ?C: A time-resolved synchrotron X-ray diffraction stu

Journal Article · 01 September 2022 · Chem. Geol.

DOI:https://doi.org/10.1016/j.chemgeo.2022.120995· OSTI ID:1875164

Chen, Si Athena; Heaney, Peter J.; Post, Jeffrey E.; Eng, Peter J.; Stubbs, Joanne E.

Research Organization:: Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)

Sponsoring Organization:: DOE - Office Of Science; NSF

OSTI ID:: 1875164

Journal Information:: Chem. Geol., Journal Name: Chem. Geol. Vol. 606

Country of Publication:: United States

Language:: ENGLISH

References (54)

A detailed study of the transformation of ferrihydrite to hematite in an aqueous medium at 92°C Johnston, J. H.; Lewis, D. G. Geochimica et Cosmochimica Acta, Vol. 47, Issue 11 https://doi.org/10.1016/0016-7037(83)90200-4	journal	November 1983
Mineralogy of the clay fraction of alfisols in two slope curvatures: IV - spatial correlation with physical properties Camargo, Livia Arantes; Marques Júnior, José; Pereira, Gener Tadeu Revista Brasileira de Ciência do Solo, Vol. 37, Issue 2 https://doi.org/10.1590/S0100-06832013000200002	journal	April 2013
Transformation of ferrihydrite to hematite: an in situ investigation on the kinetics and mechanisms Vu, H. P.; Shaw, S.; Benning, L. G. Mineralogical Magazine, Vol. 72, Issue 1 https://doi.org/10.1180/minmag.2008.072.1.217	journal	February 2008
High resolution hematite and goethite records from ODP 1143, South China Sea: Co-evolution of monsoonal precipitation and El Niño over the past 600,000 years Zhang, Yi Ge; Ji, Junfeng; Balsam, William L. Earth and Planetary Science Letters, Vol. 264, Issue 1-2 https://doi.org/10.1016/j.epsl.2007.09.022	journal	December 2007
Hematite reconstruction of Late Triassic hydroclimate over the Colorado Plateau Lepre, Christopher J.; Olsen, Paul E. Proceedings of the National Academy of Sciences, Vol. 118, Issue 7 https://doi.org/10.1073/pnas.2004343118	journal	February 2021
Transformation of Two-Line Ferrihydrite to Goethite and Hematite as a Function of pH and Temperature Das, Soumya; Hendry, M. Jim; Essilfie-Dughan, Joseph Environmental Science & Technology, Vol. 45, Issue 1 https://doi.org/10.1021/es101903y	journal	January 2011
Two-Step Growth of Goethite from Ferrihydrite Burleson, David J.; Penn, R. Lee Langmuir, Vol. 22, Issue 1 https://doi.org/10.1021/la051883g	journal	January 2006
The structure of six-line ferrihydrite Jansen, E.; Kyek, A.; Sch�fer, W. Applied Physics A: Materials Science & Processing, Vol. 74, Issue 0 https://doi.org/10.1007/s003390101175	journal	December 2002
Effect of pH on the Formation of Goethite and Hematite from Ferrihydrite Schwertmann, U. Clays and Clay Minerals, Vol. 31, Issue 4 https://doi.org/10.1346/CCMN.1983.0310405	journal	January 1983
Crystallization of Hematite (α-Fe ₂ O ₃ ) under Alkaline Condition: The Effects of Pb Vu, Hong P.; Shaw, Samuel; Brinza, Loredana Crystal Growth & Design, Vol. 10, Issue 4 https://doi.org/10.1021/cg900782g	journal	April 2010
Long-term in vitro transformation of 2-line ferrihydrite to goethite/hematite at 4, 10, 15 and 25°C Schwertmann, U.; Stanjek, H.; Becher, H. -H. Clay Minerals, Vol. 39, Issue 4 https://doi.org/10.1180/0009855043940145	journal	December 2004
The Growth Mechanism of α-Fe2O3 Ellipsoidal Particles in Solution Ocaña, Manuel; Morales, Maria P.; Serna, Carlos J. Journal of Colloid and Interface Science, Vol. 171, Issue 1 https://doi.org/10.1006/jcis.1995.1153	journal	April 1995
Oxygen isotope fractionation in ferric oxide-water systems: low temperature synthesis Bao, Huiming; Koch, Paul L. Geochimica et Cosmochimica Acta, Vol. 63, Issue 5 https://doi.org/10.1016/S0016-7037(99)00005-8	journal	March 1999
In situ study of the goethite-hematite phase transformation by real time synchrotron powder diffraction Gualtieri, Alessandro F.; Venturelli, Paolo American Mineralogist, Vol. 84, Issue 5-6 https://doi.org/10.2138/am-1999-5-624	journal	June 1999
Climatic thresholds for pedogenic iron oxides under aerobic conditions: Processes and their significance in paleoclimate reconstruction Long, Xiaoyong; Ji, Junfeng; Barrón, Vidal Quaternary Science Reviews, Vol. 150 https://doi.org/10.1016/j.quascirev.2016.08.031	journal	October 2016
Ferrihydrite: A review of structure, properties and occurrence in relation to soils Childs, Cyril W. Zeitschrift für Pflanzenernährung und Bodenkunde, Vol. 155, Issue 5 https://doi.org/10.1002/jpln.19921550515	journal	January 1992
A kinetic analysis of the transformation from akaganeite to hematite: An in situ time-resolved X-ray diffraction study Peterson, Kristina M.; Heaney, Peter J.; Post, Jeffrey E. Chemical Geology, Vol. 444 https://doi.org/10.1016/j.chemgeo.2016.09.017	journal	December 2016
High resolution hematite/goethite records from Chinese loess sequences for the last glacial-interglacial cycle: Rapid climatic response of the East Asian Monsoon to the tropical Pacific Ji, Junfeng Geophysical Research Letters, Vol. 31, Issue 3 https://doi.org/10.1029/2003GL018975	journal	January 2004
The Structure of Ferrihydrite, a Nanocrystalline Material Michel, F. M.; Ehm, L.; Antao, S. M. Science, Vol. 316, Issue 5832 https://doi.org/10.1126/science.1142525	journal	June 2007
U. Schwertmann and R. M. Cornell Iron Oxides in the Laboratory. Weinheim, New York, Basel and Cambridge (VCH), 1991. xiv + 137 pp. Price £45.00 Bowles, J. F. W. Mineralogical Magazine, Vol. 56, Issue 383 https://doi.org/10.1180/minmag.1992.056.383.20	journal	June 1992
Effect of Mo and V on the Hydrothermal Crystallization of Hematite from Ferrihydrite: An in Situ Energy Dispersive X-ray Diffraction and X-ray Absorption Spectroscopy Study Brinza, Loredana; Vu, Hong P.; Shaw, Samuel Crystal Growth & Design, Vol. 15, Issue 10 https://doi.org/10.1021/acs.cgd.5b00173	journal	August 2015
The kinetics and mechanisms of goethite and hematite crystallization under alkaline conditions, and in the presence of phosphate Shaw, S. American Mineralogist, Vol. 90, Issue 11-12 https://doi.org/10.2138/am.2005.1757	journal	November 2005
Spatial variability of iron oxides in soils from Brazilian sandstone and basalt Silva, Laércio Santos; Marques Júnior, José; Barrón, Vidal CATENA, Vol. 185 https://doi.org/10.1016/j.catena.2019.104258	journal	February 2020
Water determination in iron oxyhydroxides and iron ores by Karl Fischer titration da Cunha, Camila C. R. F.; da Costa, Geraldo M. Physics and Chemistry of Minerals, Vol. 43, Issue 10 https://doi.org/10.1007/s00269-016-0830-9	journal	August 2016
The magnetism of micro-sized hematite explained Liu, Qingsong; Barrón, Vidal; Torrent, José Physics of the Earth and Planetary Interiors, Vol. 183, Issue 3-4 https://doi.org/10.1016/j.pepi.2010.08.008	journal	December 2010
From Fe(III) Ions to Ferrihydrite and then to Hematite Schwertmann, Udo; Friedl, Josef; Stanjek, Helge Journal of Colloid and Interface Science, Vol. 209, Issue 1 https://doi.org/10.1006/jcis.1998.5899	journal	January 1999
The thermodynamic consideration for Fe-H2O system at 25°C Misawa, T. Corrosion Science, Vol. 13, Issue 9 https://doi.org/10.1016/S0010-938X(73)80037-X	journal	January 1973
Effect of Solution and Solid-Phase Conditions on the Fe(II)-Accelerated Transformation of Ferrihydrite to Lepidocrocite and Goethite Boland, Daniel D.; Collins, Richard N.; Miller, Christopher J. Environmental Science & Technology, Vol. 48, Issue 10 https://doi.org/10.1021/es4043275	journal	April 2014
A refined monoclinic structure for a variety of "hydrohematite" Peterson, K. M.; Heaney, P. J.; Post, J. E. American Mineralogist, Vol. 100, Issue 2-3 https://doi.org/10.2138/am-2015-4807	journal	February 2015
Goethite and hematite in a climosequence in southern Brazil and their application in classification of kaolinitic soils Kämpf, N.; Schwertmann, U. Geoderma, Vol. 29, Issue 1 https://doi.org/10.1016/0016-7061(83)90028-9	journal	January 1983
A structural study of size-dependent lattice variation: In situ X-ray diffraction of the growth of goethite nanoparticles from 2-line ferrihydrite Heaney, Peter J.; Oxman, Matthew J.; Chen, Si Athena American Mineralogist, Vol. 105, Issue 5 https://doi.org/10.2138/am-2020-7217	journal	May 2020
Energetics of stable and metastable low-temperature iron oxides and oxyhydroxides Laberty, Christel; Navrotsky, Alexandra Geochimica et Cosmochimica Acta, Vol. 62, Issue 17 https://doi.org/10.1016/S0016-7037(98)00208-7	journal	September 1998
Heat capacity and thermodynamic properties of α-Fe2O3 in the region 300–1050 K. antiferromagnetic transition Grønvold, F.; Samuelsen, E. J. Journal of Physics and Chemistry of Solids, Vol. 36, Issue 4 https://doi.org/10.1016/0022-3697(75)90017-7	journal	April 1975
Occurrence and Constitution of Natural and Synthetic Ferrihydrite, a Widespread Iron Oxyhydroxide Jambor, John L.; Dutrizac, John E. Chemical Reviews, Vol. 98, Issue 7 https://doi.org/10.1021/cr970105t	journal	November 1998
Global mapping of Martian hematite mineral deposits: Remnants of water-driven processes on early Mars Christensen, P. R.; Morris, R. V.; Lane, M. D. Journal of Geophysical Research: Planets, Vol. 106, Issue E10 https://doi.org/10.1029/2000JE001415	journal	October 2001
Aggregation and disaggregation of iron oxide nanoparticles: Influence of particle concentration, pH and natural organic matter Baalousha, Mohammed Science of The Total Environment, Vol. 407, Issue 6 https://doi.org/10.1016/j.scitotenv.2008.11.022	journal	March 2009
Transformations from triclinic to hexagonal birnessite at circumneutral pH induced through pH control by common biological buffers Ling, Florence T.; Heaney, Peter J.; Post, Jeffrey E. Chemical Geology, Vol. 416 https://doi.org/10.1016/j.chemgeo.2015.10.007	journal	November 2015
EXPGUI , a graphical user interface for GSAS Toby, Brian H. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889801002242	journal	April 2001
Predicting pH buffering capacity of New Zealand soils from organic matter content and mineral characteristics Curtin, Denis; Trolove, Stephen Soil Research, Vol. 51, Issue 6 https://doi.org/10.1071/SR13137	journal	January 2013
Biogeochemical Properties of Bacteriogenic Iron Oxides Ferris, F. G. Geomicrobiology Journal, Vol. 22, Issue 3-4 https://doi.org/10.1080/01490450590945861	journal	April 2005
Kinetics of Fe ³⁺ mineral crystallization from ferrihydrite in the presence of Si at alkaline conditions and implications for nuclear waste disposal Francisco, Paul Clarence M.; Sato, Tsutomu; Otake, Tsubasa American Mineralogist, Vol. 101, Issue 9 https://doi.org/10.2138/am-2016-5589	journal	September 2016
Natural ferrihydrites in surface deposits from Finland and their association with silica Carlson, L.; Schwertmann, U. Geochimica et Cosmochimica Acta, Vol. 45, Issue 3 https://doi.org/10.1016/0016-7037(81)90250-7	journal	March 1981
Review on iron availability in soil: interaction of Fe minerals, plants, and microbes Colombo, Claudio; Palumbo, Giuseppe; He, Ji-Zheng Journal of Soils and Sediments, Vol. 14, Issue 3 https://doi.org/10.1007/s11368-013-0814-z	journal	November 2013
A hematite-bearing layer in Gale Crater, Mars: Mapping and implications for past aqueous conditions Fraeman, A. A.; Arvidson, R. E.; Catalano, J. G. Geology, Vol. 41, Issue 10 https://doi.org/10.1130/G34613.1	journal	July 2013
The Molecular Mechanism of Iron(III) Oxide Nucleation Scheck, Johanna; Wu, Baohu; Drechsler, Markus The Journal of Physical Chemistry Letters, Vol. 7, Issue 16 https://doi.org/10.1021/acs.jpclett.6b01237	journal	August 2016
The Magnetic and Color Reflectance Properties of Hematite: From Earth to Mars Jiang, Zhaoxia; Liu, Qingsong; Roberts, Andrew P. Reviews of Geophysics, Vol. 60, Issue 1 https://doi.org/10.1029/2020RG000698	journal	January 2022
The kinetics and reaction mechanism of the goethite to hematite transformation Goss, C. J. Mineralogical Magazine, Vol. 51, Issue 361 https://doi.org/10.1180/minmag.1987.051.361.11	journal	September 1987
The effect of [OH] on the goethite produced from ferrihydrite under alkaline conditions Lewis, D. G.; Schwertmann, U. Journal of Colloid and Interface Science, Vol. 78, Issue 2 https://doi.org/10.1016/0021-9797(80)90591-3	journal	December 1980
Superhydrous hematite and goethite: A potential water reservoir in the red dust of Mars? Chen, Si Athena; Heaney, Peter J.; Post, Jeffrey E. Geology, Vol. 49, Issue 11 https://doi.org/10.1130/G48929.1	journal	July 2021
Impact of structural features on pigment properties of α-Fe2O3 haematite Pailhé, N.; Wattiaux, A.; Gaudon, M. Journal of Solid State Chemistry, Vol. 181, Issue 10 https://doi.org/10.1016/j.jssc.2008.06.049	journal	October 2008
Composition, nucleation, and growth of iron oxide concretions Parry, W. T. Sedimentary Geology, Vol. 233, Issue 1-4 https://doi.org/10.1016/j.sedgeo.2010.10.009	journal	January 2011
Evolution in the structure of akaganeite and hematite during hydrothermal growth: an in situ synchrotron X-ray diffraction analysis Peterson, Kristina M.; Heaney, Peter J.; Post, Jeffrey E. Powder Diffraction, Vol. 33, Issue 4 https://doi.org/10.1017/S0885715618000623	journal	September 2018
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration Prescher, Clemens; Prakapenka, Vitali B. High Pressure Research, Vol. 35, Issue 3 https://doi.org/10.1080/08957959.2015.1059835	journal	May 2015
Transformation of 2-line ferrihydrite to 6-line ferrihydrite under oxic and anoxic conditions Kukkadapu, Ravi K.; Zachara, John M.; Fredrickson, James K. American Mineralogist, Vol. 88, Issue 11-12 https://doi.org/10.2138/am-2003-11-1233	journal	November 2003

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