skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Fundamental understanding of the synthesis of well-defined supported non-noble metal intermetallic c

Journal Article · · Catal. Sci. Technol.
DOI:https://doi.org/10.1039/D2CY00183G· OSTI ID:1873545

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; National Science Foundation (NSF)
OSTI ID:
1873545
Journal Information:
Catal. Sci. Technol., Vol. 12, Issue (11)
Country of Publication:
United States
Language:
ENGLISH

References (166)

Hydrogenation of 1,3-butadiene on Pd(111) and PdSn/Pd(111) surface alloys under UHV conditions journal October 2007
Characterization and catalytic properties of Ni–Sn intermetallic compounds in acetylene hydrogenation journal January 2000
Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol journal March 2014
Adsorption and reaction of 1,3-butadiene on Pt(111) and Sn/Pt(111) surface alloys journal November 2004
Intermetallic compounds of Ni and Ga as catalysts for the synthesis of methanol journal December 2014
Through‐Space Electrostatic Effects of Positively Charged Substituents on the Hydrogen Evolution Reaction journal February 2022
A Pd@Zeolite Catalyst for Nitroarene Hydrogenation with High Product Selectivity by Sterically Controlled Adsorption in the Zeolite Micropores journal May 2017
Colloidal Platinum–Copper Nanocrystal Alloy Catalysts Surpass Platinum in Low-Temperature Propene Combustion journal January 2022
Structural changes in noble metal nanoparticles during CO oxidation and their impact on catalyst activity journal May 2020
Surface science under reaction conditions: CO oxidation on Pt and Pd model catalysts journal January 2017
The Role of Oxides in Catalytic CO Oxidation over Rhodium and Palladium journal April 2018
High-Pressure CO Oxidation on Pt(111) Monitored with Infrared−Visible Sum Frequency Generation (SFG) journal April 1997
Noble-Metal Nanoframes and Their Catalytic Applications journal December 2020
Catalytic activity of noble metals promoting hydrogen uptake journal April 2006
Trend in the CC and CO bond hydrogenation of acrolein on Pt–M (M=Ni, Co, Cu) bimetallic surfaces journal December 2009
Enhancement of oxygen reduction reaction on PtAu nanoparticles via CO induced surface Pt enrichment journal January 2013
Maximum Noble-Metal Efficiency in Catalytic Materials: Atomically Dispersed Surface Platinum journal June 2014
Identification of Non-Precious Metal Alloy Catalysts for Selective Hydrogenation of Acetylene journal June 2008
Electrochemical Energy Conversion on Intermetallic Compounds: A Review journal January 2019
Properties of Si-modified Pd catalyst for selective hydrogenation of acetylene journal September 1998
Pd−Ga Intermetallic Compounds as Highly Selective Semihydrogenation Catalysts journal October 2010
Adsorption and reaction of acetaldehyde on Pt( 111 ) and Sn/Pt( 111 ) surface alloys journal July 2003
Ru-Sn catalysts for selective hydrogenation of crotonaldehyde: Effect of the Sn/(Ru+Sn) ratio journal February 2007
Tandem Dehydrogenation of Ammonia Borane and Hydrogenation of Nitro/Nitrile Compounds Catalyzed by Graphene-Supported NiPd Alloy Nanoparticles journal April 2014
Design and Characterization by EXAFS, FTIR, and TEM of Rh-Sn/SiO2 Catalysts Active for NO-H2 Reaction journal September 1994
Trends in the Surface and Catalytic Chemistry of Transition-Metal Ceramics in the Deoxygenation of a Woody Biomass Pyrolysis Model Compound journal April 2017
Selective and Stable Non-Noble-Metal Intermetallic Compound Catalyst for the Direct Dehydrogenation of Propane to Propylene journal October 2018
Controlling the surface chemistry towards unsaturated carbon-carbon bonds over non-oxide transition metal ceramics: Trends in adsorption and distortion energies and adsorbate “activation” journal August 2019
The Origin of the Special Surface and Catalytic Chemistry of Ga-Rich Ni 3 Ga in the Direct Dehydrogenation of Ethane journal September 2019
Control of surface reactivity towards unsaturated C C bonds and H over Ni-based intermetallic compounds in semi-hydrogenation of acetylene journal April 2019
Controlling Selectivity and Stability in the Hydrocarbon Wet-Reforming Reaction Using Well-Defined Ni + Ga Intermetallic Compound Catalysts journal July 2020
Insights into Elevated-Temperature Photocatalytic Reduction of CO 2 by H 2 O journal March 2018
Control of Selectivity through a New Hydrogen-Transfer Mechanism in Photocatalytic Reduction Reactions: Electronically Relaxed Neutral H and the Role of Electron–Phonon Coupling journal July 2019
Density functional theory in surface chemistry and catalysis journal January 2011
Selective Activation of CH and CC Bonds on Metal Carbides: A Comparison of Reactions of n-Butane and 1,3-Butadiene on Vanadium Carbide Films on V(110) journal June 1995
Effect of carbon modification on a vanadium(110) surface: observation of surface reactivities characteristics of platinum-group metals journal September 1993
Tungsten carbides as selective deoxygenation catalysts: experimental and computational studies of converting C3 oxygenates to propene journal January 2014
Similarities in the decomposition and dehydrogenation of cyclohexene on (4 × 4)-CMo(110) and Pt(111) journal December 1996
Reactivity of Hydrogen on and in Nanostructured Molybdenum Nitride: Crotonaldehyde Hydrogenation journal August 2016
Catalytic properties of early transition metal nitrides and carbides: n-butane hydrogenolysis, dehydrogenation and isomerization journal July 1999
Identifying trends and descriptors for selective CO 2 conversion to CO over transition metal carbides journal January 2015
The catalytic activity of nickel and nickel boride for formic acid decomposition journal October 1967
Hydrogenation of various ketones on nickel boride catalyst journal September 1968
Dehydrogenation activity of nickel-tin-silica catalyst journal June 1975
Dehydrogenation of cyclohexene on ordered Sn/Pt(111) surface alloys journal March 1994
Multicomponent catalysts for the oxidation of propylene to acrolein: Fe2(MoO4)3 doped with Bi or Te journal July 1982
Partial Hydrogenation of Acetylenes on Modified Nickel Boride Catalysts journal November 1981
Comparison of the activity and lifetime of Raney nickel and nickel boride in the hydrogenation of various functional groups journal March 1981
Alumina-supported bimetallics of palladium alloyed with germanium, tin, lead, or antimony from organometallic precursors I. Preparation and characterization journal September 1989
The adsorption of benzene on Pd(111) and ordered Sn/Pd(111) surface alloys journal August 2004
Hydrogenation of Crotonaldehyde over Sn/Pt(111) Alloy Model Catalysts journal January 2002
Selective Hydrogenation of Biomass-derived Furfural over Supported Ni3Sn2 Alloy: Role of Supports journal March 2016
Nickel-Gallium Intermetallic Nanocrystal Catalysts in the Semihydrogenation of Phenylacetylene journal February 2014
Controlling Acetylene Adsorption and Reactions on Pt–Sn Catalytic Surfaces journal April 2013
Isolated Single-Atom Pd Sites in Intermetallic Nanostructures: High Catalytic Selectivity for Semihydrogenation of Alkynes journal May 2017
Etching of the intermetallic compounds PdGa and Pd3Ga7: An effective way to increase catalytic activity? journal June 2009
Preparation and catalytic properties of uniform particles of Ni3Ge intermetallic compound formed inside the mesopores of MCM-41 journal October 2008
Selective hydrogenation of acetylene on SiO2 supported Ni-In bimetallic catalysts: Promotional effect of In journal November 2016
Sn-modified Ni catalysts for aqueous-phase reforming: Characterization and deactivation studies journal April 2005
PdIn intermetallic nanoparticles for the Hydrogenation of CO2 to Methanol journal January 2018
Aromatization of butane on Pt–Ge intermetallic compounds supported on HZSM-5 journal March 2000
Steering the Catalytic Properties of Intermetallic Compounds and Alloys in Reforming Reactions by Controlled in Situ Decomposition and Self-Activation journal April 2021
Rational design of intermetallic compound catalysts for propane dehydrogenation from a descriptor-based microkinetic analysis journal December 2021
The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds journal November 2005
Characterizations and catalytic properties of fine particles of Ni–Sn intermetallic compounds supported on SiO2 journal January 2004
Palladium–gallium intermetallic compounds for the selective hydrogenation of acetylenePart I: Preparation and structural investigation under reaction conditions journal August 2008
Spontaneous activation behavior of Ni3Sn, an intermetallic catalyst, for hydrogen production via methanol decomposition journal October 2015
Preparation of CoAl intermetallic compound by combustion synthesis in self-propagating mode journal February 2005
Ignition and reaction mechanism of Co–Al and Nb–Al intermetallic compounds prepared by combustion synthesis journal September 2006
The standard enthalpies of formation of binary intermetallic compounds of some late 4d and 5d transition metals by high temperature direct synthesis calorimetry journal March 2010
Investigations of the formation mechanism of nanostructured NbAl3 via MASHS reaction journal April 2002
Preparation of Highly Pure MnBi Intermetallic Compounds by Arc-Melting journal January 1999
Synthesis of WSi2 and W2B intermetallic compound by in-situ self propagating high-temperature synthesis reaction journal January 2014
The influence of modifying admixtures on the catalytic properties of the Ni3Al intermetallic compound in the conversion of methane with carbon dioxide journal January 2009
Properties of Bulk In‐Pt Intermetallic Compounds in Methanol Steam Reforming journal March 2022
Surface dynamics of the intermetallic catalyst Pd2Ga, Part II – Reactivity and stability in liquid-phase hydrogenation of phenylacetylene journal January 2014
Surface dynamics of the intermetallic catalyst Pd2Ga, Part I – Structural stability in UHV and different gas atmospheres journal January 2014
Alloys in catalysis: phase separation and surface segregation phenomena in response to the reactive environment journal January 2012
Electromagnetic properties of FeNi alloy nanoparticles prepared by hydrogen-thermal reduction method journal August 2008
High-Performance Pd 3 Pb Intermetallic Catalyst for Electrochemical Oxygen Reduction journal March 2016
Ag–Pt Compositional Intermetallics Made from Alloy Nanoparticles journal September 2016
Selective hydrogenation of acetylene over TiO 2 -supported PdAg cluster: carbon species effect journal January 2016
Converting nanocrystalline metals into alloys and intermetallic compounds for applications in catalysis journal January 2008
Nickel–Silicon Intermetallics with Enhanced Selectivity in Hydrogenation Reactions of Cinnamaldehyde and Phenylacetylene journal February 2012
Solution Synthesis of Nanocrystalline M−Zn (M = Pd, Au, Cu) Intermetallic Compounds via Chemical Conversion of Metal Nanoparticle Precursors journal August 2007
Low-Temperature Solution Synthesis of Nanocrystalline Binary Intermetallic Compounds Using the Polyol Process journal December 2005
Synthesis of Atomically Ordered AuCu and AuCu 3 Nanocrystals from Bimetallic Nanoparticle Precursors journal June 2004
Metallurgy in a Beaker:  Nanoparticle Toolkit for the Rapid Low-Temperature Solution Synthesis of Functional Multimetallic Solid-State Materials journal March 2005
Intermetallic Compounds: Liquid‐Phase Synthesis and Electrocatalytic Applications journal September 2021
Well-structured bimetallic surface capable of molecular recognition for chemoselective nitroarene hydrogenation journal January 2016
EXAFS Studies of Supported Rh–Sn Catalysts for Citral Hydrogenation journal February 1999
Ni–In Intermetallic Nanocrystals as Efficient Catalysts toward Unsaturated Aldehydes Hydrogenation journal September 2013
Revealing the Synergy between Oxide and Alloy Phases on the Performance of Bimetallic In–Pd Catalysts for CO 2 Hydrogenation to Methanol journal March 2019
Preparation of alumina-supported intermetallic compounds journal January 2013
Ga‐Pd/Ga 2 O 3 Catalysts: The Role of Gallia Polymorphs, Intermetallic Compounds, and Pretreatment Conditions on Selectivity and Stability in Different Reactions journal August 2012
Pt–Sn catalysts supported on highly-dispersed ceria on carbon journal May 2007
Spectroscopic and catalytic characterization of Pd–In and Pt–In supported on Al2O3 and SiO2, active catalysts for nitrate hydrogenation journal September 2008
Influence of Metallic Precursors on the Preparation of Silica-Supported Ptsn Alloy: Characterization and Reactivity in the Catalytic Activation of CO2 journal September 1995
Vapor phase deoxygenation of heptanoic acid over silica-supported palladium and palladium-tin catalysts journal December 2016
Synthesis of Co–Sn intermetallic nanocatalysts toward selective hydrogenation of citral journal January 2016
Aqueous-phase reforming of oxygenated hydrocarbons over Sn-modified Ni catalysts journal February 2004
NiAl and CoAl materials derived from takovite-like LDHs and related structures as efficient chemoselective hydrogenation catalysts journal January 2014
Catalytic activity of atomized Ni3Al powder for hydrogen generation by methane steam reforming journal November 2006
Nickel-Aluminum Intermetallic Compounds as Highly Selective and Stable Catalysts for the Hydrogenation of Naphthalene to Tetralin journal February 2015
Angle-resolved X-ray photoelectron spectroscopy of the surface of imidazolium ionic liquids journal January 2008
Oxygen accumulation on metal surfaces investigated by XPS, AES and LEIS, an issue for sputter depth profiling under UHV conditions journal July 2017
Surface structure and composition of flat titanium thin films as a function of film thickness and evaporation rate journal August 2005
Surface Composition Control of the Binary Au–Ag Catalyst for Enhanced Oxidant-Free Dehydrogenation journal September 2016
Controlling Reaction Selectivity through the Surface Termination of Perovskite Catalysts journal July 2017
Shape Effect Undermined by Surface Reconstruction: Ethanol Dehydrogenation over Shape-Controlled SrTiO 3 Nanocrystals journal December 2017
Molecular Oxygen Reduction in PEM Fuel Cell Conditions:  ToF-SIMS Analysis of Co-Based Electrocatalysts journal September 2005
Time-of-flight secondary ion mass spectrometry (TOF-SIMS):—versatility in chemical and imaging surface analysis journal January 2004
Multivariate Analysis of ToF-SIMS Data from Multicomponent Systems: The Why, When, and How journal December 2012
A concise tutorial review of TOF-SIMS based molecular and cellular imaging journal January 2019
Fundamental Bulk/Surface Structure–Photoactivity Relationships of Supported (Rh 2– y Cr y O 3 )/GaN Photocatalysts journal October 2013
Anatomy of a Visible Light Activated Photocatalyst for Water Splitting journal June 2018
Acid–Base Reactivity of Perovskite Catalysts Probed via Conversion of 2-Propanol over Titanates and Zirconates journal June 2017
Surface chemistry of La 0.6 Sr 0.4 CoO 3−δ thin films and its impact on the oxygen surface exchange resistance journal January 2015
Dry reforming of methane over Ni/La2O3 nanorod catalysts with stabilized Ni nanoparticles journal March 2017
Surface termination and subsurface restructuring of perovskite-based solid oxide electrode materials journal January 2014
Ammonia decomposition over Ru and Ni catalysts supported on fumed SiO2, MCM-41, and SBA-15 journal December 2005
NH 3 Decomposition for H 2 Generation: Effects of Cheap Metals and Supports on Plasma–Catalyst Synergy journal June 2015
High-efficiency oxygen reduction to hydrogen peroxide catalysed by oxidized carbon materials journal January 2018
Effect of surface oxygen functionalization of carbon support on the activity and durability of Pt/C catalysts for the oxygen reduction reaction journal May 2016
Origin and Abatement of Heterogeneity at the Support Granule Scale of Silver on Silica Catalysts journal November 2017
The Structure and Activity of Silica-Supported Palladium-Cobalt Alloys I. Alloy Homogeneity, Surface Composition, and Activity for Neopentane Conversion journal August 1993
Reforming of methane with carbon dioxide over Ni/Al2O3 catalysts: Effect of nickel precursor journal May 1998
Effect of metal precursor and pretreatment conditions on the catalytic activity of Ni/C in the aqueous phase hydrodechlorination of 1,1,2-trichloroethene journal February 2017
Strong Chemical Interactions Between Au and Off-Stoichiometric Defects on TiO 2 as a Possible Source of Chemical Activity of Nanosized Au Supported on the Oxide journal March 2009
Geometric and electronic characteristics of active sites on TiO2-supported Au nano-catalysts: insights from first principles journal January 2009
An egg-shell type Ni/Al2O3 catalyst derived from layered double hydroxides precursor for selective hydrogenation of pyrolysis gasoline journal November 2013
A novel nickel catalyst derived from layered double hydroxides (LDHs) supported on fluid catalytic cracking catalyst residue (FC3R) for rosin hydrogenation journal June 2015
High-loaded nickel–silica catalysts for hydrogenation, prepared by sol–gel journal June 2003
TPR Study on the Preparation of Impregnated Co/SiO2Catalysts journal September 1996
Characterization and Nitrile Group Hydrogenation Study of Supported and Unsupported Ru–Co Catalyst journal June 1996
Ru, Os and Ru–Os supported on mesoporous silica doped with zirconium as mild thio-tolerant catalysts in the hydrogenation and hydrogenolysis/hydrocracking of tetralin journal January 2005
Spillover in Heterogeneous Catalysis journal May 1995
Spillover sites on a 19% Ni/Al2O3 catalyst journal June 1989
Effect of nickel precursor on the catalytic performance of Ni/Al2O3 catalysts in the hydrodechlorination of 1,1,2-trichloroethane journal August 2006
Hydrogen Production via Glycerol Steam Reforming over Ni/Al 2 O 3 : Influence of Nickel Precursors journal June 2013
Radiation-induced synthesis of α-Al2O3 supported nickel clusters: Characterization and catalytic properties journal October 2005
Indium( iii ) hydration in aqueous solutions of perchlorate, nitrate and sulfate. Raman and infrared spectroscopic studies and ab-initio molecular orbital calculations of indium( iii )–water clusters journal January 2004
Field-activated combustion synthesis of Ta–Si intermetallic compounds journal February 2001
Ga-Ni (Gallium-Nickel) journal April 2008
The binary system Ni-In journal July 1997
SiO2 supported Ni-In intermetallic compounds: Efficient for selective hydrogenation of fatty acid methyl esters to fatty alcohols journal December 2020
Nano-size particles of palladium intermetallic compounds as catalysts for oxidative acetoxylation journal September 2003
Intermetallic: A Pseudoelement for Catalysis journal December 2017
Intermetallic Compound Cu 2 Sb Nanoparticles for Effective Electrocatalytic Oxidation of an Antibiotic Drug: Sulphadiazine journal November 2020
Fe-Sn nanocrystalline films for flexible magnetic sensors with high thermal stability journal March 2019
Lithium Storage Mechanism and Application of Micron‐Sized Lattice‐Reversible Binary Intermetallic Compounds as High‐Performance Flexible Lithium‐Ion Battery Anodes journal December 2021
Adsorbate-Induced Surface Segregation for Core-Shell Nanocatalysts journal April 2009
Influence of bulk composition of the intermetallic compound ZnPd on surface composition and methanol steam reforming properties journal January 2012
Dynamic restructuring drives catalytic activity on nanoporous gold–silver alloy catalysts journal December 2016
Surfaces of intermetallic compounds: An ab initio DFT study for B20-type AlPd journal January 2013
Alloy vs. intermetallic compounds: Effect of the ordering on the electrocatalytic activity for oxygen reduction and the stability of low temperature fuel cell catalysts journal November 2017
Intermetallic Compounds: Promising Inorganic Materials for Well-Structured and Electronically Modified Reaction Environments for Efficient Catalysis journal December 2016
Properties of intermetallic compounds suitable for hydrogen storage applications journal June 2002
Mechanism of formation of C2-oxygenated compounds from CO + H2 reaction over SiO2-supported Rh catalysts journal December 1984
Simple and high-yield method for synthesizing single-crystal GaN nanowires journal September 2000
Metal Particle Size in Ni/SiO 2 Materials Prepared by Deposition−Precipitation:  Influence of the Nature of the Ni(II) Phase and of Its Interaction with the Support journal July 1999
Reforming of methane with carbon dioxide over supported bimetallic catalysts containing Ni and noble metal journal March 2005
Structural and chemical stability of thin films of Pt–Ga intermetallic compounds of GaAs(001) journal October 1990
Surface Investigation of Intermetallic PdGa(1̅ 1̅ 1̅) journal April 2012
The surface energy of metals journal August 1998
Evolution of near-surface concentration profiles of Cr during annealing of Fe–15Cr polycrystalline alloy journal August 2005