High-Rate Lithium Cycling and Structure Evolution in Mo[subscript 4]O[subscript 11]

Vincent, Rebecca C.; Luo, Yunkai; Andrews, Jessica L.; Zohar, Arava; Zhou, Yucheng; Yan, Qizhang; Mozur, Eve M.; Preefer, Molleigh B.; Weker, Johanna Nelson; Cheetham, Anthony K.; Luo, Jian; Pilon, Laurent; Melot, Brent C.; Dunn, Bruce; Seshadri, Ram

doi:10.1021/acs.chemmater.2c00420

High-Rate Lithium Cycling and Structure Evolution in Mo[subscript 4]O[subscript 11]

Journal Article · 01 April 2022 · Chem. Mater.

DOI:https://doi.org/10.1021/acs.chemmater.2c00420· OSTI ID:1872588

Vincent, Rebecca C.; Luo, Yunkai; Andrews, Jessica L.; Zohar, Arava; Zhou, Yucheng; Yan, Qizhang; Mozur, Eve M.; Preefer, Molleigh B.; Weker, Johanna Nelson; Cheetham, Anthony K.; Luo, Jian; Pilon, Laurent; Melot, Brent C.; Dunn, Bruce; Seshadri, Ram

Research Organization:: Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)

Sponsoring Organization:: DOE - Office Of Science; DOE - BASIC ENERGY SCIENCES

OSTI ID:: 1872588

Journal Information:: Chem. Mater., Journal Name: Chem. Mater. Journal Issue: (9) Vol. 34

Country of Publication:: United States

Language:: ENGLISH

References (66)

Lithium Intercalation Cells Without Metallic Lithium Auborn, J. J. Journal of The Electrochemical Society, Vol. 134, Issue 3 https://doi.org/10.1149/1.2100521	journal	January 1987
Far-infrared and Raman studies of orthorhombic MoO3 single crystal Nazri, G. Solid State Ionics, Vol. 53-56 https://doi.org/10.1016/0167-2738(92)90403-C	journal	July 1992
A Raman and XPS investigation of supported molybdenum oxide thin films. 1. Calcination and reduction studies Spevack, Perry A.; McIntyre, N. S. The Journal of Physical Chemistry, Vol. 97, Issue 42 https://doi.org/10.1021/j100144a020	journal	October 1993
Lithiated MoO3 Nanobelts with Greatly Improved Performance for Lithium Batteries Mai, L. Q.; Hu, B.; Chen, W. Advanced Materials, Vol. 19, Issue 21 https://doi.org/10.1002/adma.200700883	journal	November 2007
Energy storage mechanisms in vacancy-ordered Wadsley–Roth layered niobates McColl, Kit; Griffith, Kent J.; Dally, Rebecca L. Journal of Materials Chemistry A, Vol. 9, Issue 35 https://doi.org/10.1039/D1TA02992D	journal	January 2021
Thermodynamic modeling and first-principles calculations of the Mo–O system Zhang, C.; Gao, M. C.; Yang, Y. Calphad, Vol. 45 https://doi.org/10.1016/j.calphad.2013.12.006	journal	June 2014
Reversible Capacity of Conductive Carbon Additives at Low Potentials: Caveats for Testing Alternative Anode Materials for Li-Ion Batteries See, Kimberly A.; Lumley, Margaret A.; Stucky, Galen D. Journal of The Electrochemical Society, Vol. 164, Issue 2 https://doi.org/10.1149/2.0971702jes	journal	December 2016
On the relation between molybdenum trioxide and rhenium trioxide type crystal structures Bursill, L. A. Acta Crystallographica Section A, Vol. 29, Issue 1 https://doi.org/10.1107/S0567739473000069	journal	January 1973
Substitutional effects on the electrical properties of the purple bronze Li0.9Mo6O17 Ramanujachary, K. Solid State Ionics, Vol. 22, Issue 1 https://doi.org/10.1016/0167-2738(86)90064-0	journal	December 1986
The Cathodic Behavior of CuS, MoO[sub 3], and MnO[sub 2] in Lithium Cells Dampier, Fred W. Journal of The Electrochemical Society, Vol. 121, Issue 5 https://doi.org/10.1149/1.2401880	journal	January 1974
VESTA : a three-dimensional visualization system for electronic and structural analysis Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 41, Issue 3 https://doi.org/10.1107/S0021889808012016	journal	May 2008
Molybdenum, Molybdenum Oxides, and their Electrochemistry Saji, Viswanathan S.; Lee, Chi‐Woo ChemSusChem, Vol. 5, Issue 7 https://doi.org/10.1002/cssc.201100660	journal	June 2012
Electrochemical lithium insertion in two polymorphs of a reduced molybdenum oxide (? and ??- Mo 4 O 11 ) S�nchez, Roberto Herrera; Trevi�o, Leopoldo; Fuentes, Antonio F. Journal of Solid State Electrochemistry, Vol. 4, Issue 4 https://doi.org/10.1007/s100080050197	journal	March 2000
TOPAS and TOPAS-Academic : an optimization program integrating computer algebra and crystallographic objects written in C++ Coelho, Alan A. Journal of Applied Crystallography, Vol. 51, Issue 1 https://doi.org/10.1107/S1600576718000183	journal	February 2018
Interlayer gap widened α-phase molybdenum trioxide as high-rate anodes for dual-ion-intercalation energy storage devices Yu, Minghao; Shao, Hui; Wang, Gang Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15216-w	journal	March 2020
Superionic Lithium Intercalation through 2 × 2 nm ² Columns in the Crystallographic Shear Phase Nb ₁₈ W ₈ O ₆₉ Griffith, Kent J.; Grey, Clare P. Chemistry of Materials, Vol. 32, Issue 9 https://doi.org/10.1021/acs.chemmater.9b05403	journal	April 2020
MoO[sub 3]: A New Electrode Material for Nonaqueous Secondary Battery Applications Campanella, Luigi; Pistoia, Gianfranco Journal of The Electrochemical Society, Vol. 118, Issue 12 https://doi.org/10.1149/1.2407864	journal	January 1971
Studies on Molybdenum Oxides. Kihlborg, Lars; Sundholm, Anita; Magnéli, Arne Acta Chemica Scandinavica, Vol. 13 https://doi.org/10.3891/acta.chem.scand.13-0954	journal	January 1959
Shear Pleasure: The Structure, Formation, and Thermodynamics of Crystallographic Shear Phases Voskanyan, Albert A.; Navrotsky, Alexandra Annual Review of Materials Research, Vol. 51, Issue 1 https://doi.org/10.1146/annurev-matsci-070720-013445	journal	July 2021
New Anode Framework for Rechargeable Lithium Batteries Han, Jian-Tao; Huang, Yun-Hui; Goodenough, John B. Chemistry of Materials, Vol. 23, Issue 8, p. 2027-2029 https://doi.org/10.1021/cm200441h	journal	April 2011
Niobium tungsten oxides for high-rate lithium-ion energy storage Griffith, Kent J.; Wiaderek, Kamila M.; Cibin, Giannantonio Nature, Vol. 559, Issue 7715 https://doi.org/10.1038/s41586-018-0347-0	journal	July 2018
Crystal structure of lithium molybdenum purple bronze Li0.9Mo6O17 Onoda, M.; Toriumi, K.; Matsuda, Y. Journal of Solid State Chemistry, Vol. 66, Issue 1 https://doi.org/10.1016/0022-4596(87)90231-3	journal	January 1987
Potentiometric entropy and operando calorimetric measurements reveal fast charging mechanisms in PNb 9 O25 Baek, Sun Woong; Preefer, Molleigh B.; Saber, Muna Journal of Power Sources, Vol. 520 https://doi.org/10.1016/j.jpowsour.2021.230776	journal	February 2022
The Crystal Structure of Mo4O11 (gamma-Molybdenum Oxide). Magnéli, Arne; Barfod, Bent; Gjertsen, Poul Acta Chemica Scandinavica, Vol. 2 https://doi.org/10.3891/acta.chem.scand.02-0861	journal	January 1948
Low-temperature synthetic route based on the amorphous nature of giant species for preparation of lower valence oxides Eda, Kazuo; Kunotani, Fumiko; Uchiyama, Noriki Journal of Solid State Chemistry, Vol. 178, Issue 5 https://doi.org/10.1016/j.jssc.2005.02.020	journal	May 2005
The Crystal Structures of Mo9O26 (beta'-Molybdenum Oxide) and Mo8O23 (beta-molybdenum Oxide). Magnéli, Arne; Hofman-Bang, Niels; Gjertsen, Poul Acta Chemica Scandinavica, Vol. 2 https://doi.org/10.3891/acta.chem.scand.02-0501	journal	January 1948
Ordered Mesoporous Metallic MoO ₂ Materials with Highly Reversible Lithium Storage Capacity Shi, Yifeng; Guo, Bingkun; Corr, Serena A. Nano Letters, Vol. 9, Issue 12 https://doi.org/10.1021/nl902423a	journal	December 2009
Molybdenum Oxide Cathodes in Secondary Lithium Cells Christian, P. A.; Carides, J. N.; DiSalvo, F. J. Journal of The Electrochemical Society, Vol. 127, Issue 11 https://doi.org/10.1149/1.2129404	journal	November 1980
Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x Kim, Hyung-Seok; Cook, John B.; Lin, Hao Nature Materials, Vol. 16, Issue 4 https://doi.org/10.1038/nmat4810	journal	December 2016
New tools for calibrating diffraction setups Kieffer, J.; Valls, V.; Blanc, N. Journal of Synchrotron Radiation, Vol. 27, Issue 2 https://doi.org/10.1107/S1600577520000776	journal	February 2020
Synthesis and Electrochemical Insertion Properties of the Layered Li[sub x]MoO[sub 2] Phases (x = 0.74, 0.85, and 1.00) Barker, J.; Saidi, M. Y.; Swoyer, J. L. Electrochemical and Solid-State Letters, Vol. 6, Issue 12 https://doi.org/10.1149/1.1621288	journal	January 2003
Cycling-Induced Changes in the Entropy Profiles of Lithium Cobalt Oxide Electrodes Hudak, Nicholas S.; Davis, Lorie E.; Nagasubramanian, Ganesan Journal of The Electrochemical Society, Vol. 162, Issue 3 https://doi.org/10.1149/2.0071503jes	journal	December 2014
Interface layer formation in solid polymer electrolyte lithium batteries: an XPS study Xu, Chao; Sun, Bing; Gustafsson, Torbjörn J. Mater. Chem. A, Vol. 2, Issue 20 https://doi.org/10.1039/C4TA00214H	journal	January 2014
A Study of the Crystal Symmetry and Structure of Orthorhombic Mo4O11 by Least-squares Techniques. Åsbrink, Stig; Kihlborg, Lars; Jackman, Lloyd M. Acta Chemica Scandinavica, Vol. 18 https://doi.org/10.3891/acta.chem.scand.18-1571	journal	January 1964
Monophosphate Tungsten Bronzes. A New Family of Low-Dimensional, Charge-Density-Wave Oxides Greenblatt, Martha Accounts of Chemical Research, Vol. 29, Issue 5 https://doi.org/10.1021/ar950157	journal	January 1996
Non-stoichiometric molybdenum oxides as cathodes for lithium cells Cignini, P.; Icovi, M.; Panero, S. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 102, Issue 3 https://doi.org/10.1016/S0022-0728(79)80461-1	journal	October 1979
Operando calorimetry informs the origin of rapid rate performance in microwave-prepared TiNb 2 O 7 electrodes Baek, Sun Woong; Wyckoff, Kira E.; Butts, Danielle M. Journal of Power Sources, Vol. 490 https://doi.org/10.1016/j.jpowsour.2021.229537	journal	April 2021
Generalized molybdenum oxide surface chemical state XPS determination via informed amorphous sample model Baltrusaitis, Jonas; Mendoza-Sanchez, Beatriz; Fernandez, Vincent Applied Surface Science, Vol. 326 https://doi.org/10.1016/j.apsusc.2014.11.077	journal	January 2015
Cycle Performance and Molybdenum Dissolution into Electrolyte in MoO ₂ Anode for Lithium Secondary Batteries Takeuchi, Masanobu; Fujimoto, Hiroyuki; Kida, Yoshinori ECS Meeting Abstracts, Vol. MA2010-02, Issue 11 https://doi.org/10.1149/MA2010-02/11/1101	journal	July 2010
Some Defect Structures in Crystalline Solids Hyde, B. G.; Bagshaw, A. N.; Andersson, S. Annual Review of Materials Science, Vol. 4, Issue 1 https://doi.org/10.1146/annurev.ms.04.080174.000355	journal	August 1974
Insertion/extraction of lithium and sodium in transition metal oxides and chalcogenides Gopalakrishnan, J. Bulletin of Materials Science, Vol. 7, Issue 3-4 https://doi.org/10.1007/BF02747574	journal	October 1985
Elucidating the physical properties of the molybdenum oxide Mo ₄ O ₁₁ and its tantalum substituted variant Mo ₂ Ta ₂ O ₁₁ Zoller, Michael; Bubnova, Rimma; Biryukov, Yaroslav Zeitschrift für Kristallographie - Crystalline Materials, Vol. 235, Issue 4-5 https://doi.org/10.1515/zkri-2019-0073	journal	April 2020
Characteristics of molybdenum oxide and chromium oxide cathodes in primary and secondary organic electrolyte lithium batteries I. Morphology, structure and their changes during discharge and cycling Besenhard, J.; Heydecke, J.; Fritz, H. Solid State Ionics, Vol. 6, Issue 3 https://doi.org/10.1016/0167-2738(82)90042-X	journal	May 1982
High-Capacity Li ⁺ Storage through Multielectron Redox in the Fast-Charging Wadsley–Roth Phase (W _0.2 V _0.8 ) ₃ O ₇ Wyckoff, Kira E.; Robertson, Daniel D.; Preefer, Molleigh B. Chemistry of Materials, Vol. 32, Issue 21 https://doi.org/10.1021/acs.chemmater.0c03496	journal	October 2020
Thermodynamic Analysis and Interpretative Guide to Entropic Potential Measurements of Lithium-Ion Battery Electrodes Baek, Sun Woong; Saber, Muna; Van der Ven, Anton The Journal of Physical Chemistry C, Vol. 126, Issue 14 https://doi.org/10.1021/acs.jpcc.1c10414	journal	April 2022
Ordered mesoporous α-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors Brezesinski, Torsten; Wang, John; Tolbert, Sarah H. Nature Materials, Vol. 9, Issue 2 https://doi.org/10.1038/nmat2612	journal	January 2010
Rietveld refinement of the crystal structure of γ- Mo ₄ O ₁₁ Fun, Hoong-Kun; Yang, Ping; Sasaki, Minoru Powder Diffraction, Vol. 14, Issue 4 https://doi.org/10.1017/S0885715600010691	journal	December 1999
Quantifying structure dependent responses in Li-ion cells with excess Li spinel cathodes: matching voltage and entropy profiles through mean field models Schlueter, Steffen; Genieser, Ronny; Richards, Daniel Physical Chemistry Chemical Physics, Vol. 20, Issue 33 https://doi.org/10.1039/C8CP02989J	journal	January 2018
α-MoO ₃ Nanobelts: A High Performance Cathode Material for Lithium Ion Batteries Zhou, Liang; Yang, Lichun; Yuan, Pei The Journal of Physical Chemistry C, Vol. 114, Issue 49 https://doi.org/10.1021/jp108778v	journal	November 2010
Fast Synthesis of α-MoO ₃ Nanorods with Controlled Aspect Ratios and Their Enhanced Lithium Storage Capabilities Chen, Jun Song; Cheah, Yan Ling; Madhavi, Srinivasan The Journal of Physical Chemistry C, Vol. 114, Issue 18 https://doi.org/10.1021/jp1017482	journal	April 2010
Structural Stability from Crystallographic Shear in TiO ₂ –Nb ₂ O ₅ Phases: Cation Ordering and Lithiation Behavior of TiNb ₂₄ O ₆₂ Griffith, Kent J.; Senyshyn, Anatoliy; Grey, Clare P. Inorganic Chemistry, Vol. 56, Issue 7 https://doi.org/10.1021/acs.inorgchem.6b03154	journal	March 2017
The redetermination of the crystal structure of a sodium molybdenum oxide bronze: Na0.9Mo6O17 Gatehouse, B. M.; Lloyd, D. J. Journal of the Chemical Society D: Chemical Communications, Issue 1 https://doi.org/10.1039/c29710000013	journal	January 1971
Electronic properties of reduced molybdenum oxides Inzani, K.; Nematollahi, M.; Vullum-Bruer, F. Physical Chemistry Chemical Physics, Vol. 19, Issue 13 https://doi.org/10.1039/C7CP00644F	journal	January 2017
Carbon/MoO ₂ Composite Based on Porous Semi-Graphitized Nanorod Assemblies from In Situ Reaction of Tri-Block Polymers Ji, Xiulei; Herle, P. Subramanya; Rho, Youngho Chemistry of Materials, Vol. 19, Issue 3 https://doi.org/10.1021/cm060961y	journal	February 2007
Non-stoichiometric molybdenum oxides as cathodes for lithium cells Pistoia, G.; Temperoni, C.; Cignini, P. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 108, Issue 2 https://doi.org/10.1016/S0022-0728(80)80465-7	journal	March 1980
On the Crystal Structure of Molybdenum Trioxide. Andersson, Georg; Magnéli, Arne; Sillén, Lars Gunnar Acta Chemica Scandinavica, Vol. 4 https://doi.org/10.3891/acta.chem.scand.04-0793	journal	January 1950
Non-stoichiometric molybdenum oxides as cathodes for lithium cells. part v. thermodynamic, kinetic and structural aspects of the behaviour of Mo8O23 and Mo18O52 Pasquali, M.; Pistoia, G.; Rodante, F. Solid State Ionics, Vol. 6, Issue 4 https://doi.org/10.1016/0167-2738(82)90016-9	journal	July 1982
Raman spectroscopy of molybdenum oxides Dieterle, M.; Mestl, G. Physical Chemistry Chemical Physics, Vol. 4, Issue 5 https://doi.org/10.1039/b107046k	journal	February 2002
Multielectron Redox and Insulator-to-Metal Transition upon Lithium Insertion in the Fast-Charging, Wadsley-Roth Phase PNb ₉ O ₂₅ Preefer, Molleigh B.; Saber, Muna; Wei, Qiulong Chemistry of Materials, Vol. 32, Issue 11 https://doi.org/10.1021/acs.chemmater.0c00560	journal	May 2020
Challenges and opportunities towards fast-charging battery materials Liu, Yayuan; Zhu, Yangying; Cui, Yi Nature Energy, Vol. 4, Issue 7 https://doi.org/10.1038/s41560-019-0405-3	journal	June 2019
3-V Full Cell Performance of Anode Framework TiNb₂O₇/Spinel LiNi_0.5Mn_1.5O₄ Han, Jian-Tao; Goodenough, John B. Chemistry of Materials, Vol. 23, Issue 15, p. 3404-3407 https://doi.org/10.1021/cm201515g	journal	August 2011
Transition Metal Migration Can Facilitate Ionic Diffusion in Defect Garnet-Based Intercalation Electrodes Bashian, Nicholas H.; Abdel-Latif, Samantha; Zuba, Mateusz ACS Energy Letters, Vol. 5, Issue 5 https://doi.org/10.1021/acsenergylett.0c00376	journal	April 2020
XPS study of as-prepared and reduced molybdenum oxides Choi, J. -G.; Thompson, L. T. Applied Surface Science, Vol. 93, Issue 2 https://doi.org/10.1016/0169-4332(95)00317-7	journal	February 1996
Structure and electrochemistry of LixMoO2 Dahn, J.; Mckinnon, W. Solid State Ionics, Vol. 23, Issue 1-2 https://doi.org/10.1016/0167-2738(87)90074-9	journal	March 1987
Statistical mechanical modeling of the transition Stage II → Stage I of Li-ion storage in graphite. A priori vs induced heterogeneity Otero, M.; Sigal, A.; Perassi, E. M. Electrochimica Acta, Vol. 245 https://doi.org/10.1016/j.electacta.2017.05.128	journal	August 2017
Non-stoichiometric molybdenum oxides as cathodes for lithium cells Icovi, M.; Panero, S.; D'Agate, A. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 102, Issue 3 https://doi.org/10.1016/S0022-0728(79)80462-3	journal	October 1979

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