Pressure-induced high-spin/low-spin disproportionated state in the Mott insulator FeBO[subscript 3]

Xu, Weiming; Dong, Weiwei; Layek, Samar; Shulman, Mark; Glazyrin, Konstantin; Bykova, Elena; Bykov, Maxim; Hanfland, Michael; Pasternak, Moshe P.; Leonov, Ivan; Greenberg, Eran; Rozenberg, Gregory Kh.

doi:10.1038/s41598-022-13507-4

Title: Pressure-induced high-spin/low-spin disproportionated state in the Mott insulator FeBO[subscript 3]

Journal Article · 01 June 2022 · Sci. Rep.

DOI:https://doi.org/10.1038/s41598-022-13507-4· OSTI ID:1872585

Xu, Weiming; Dong, Weiwei; Layek, Samar; Shulman, Mark; Glazyrin, Konstantin; Bykova, Elena; Bykov, Maxim; Hanfland, Michael; Pasternak, Moshe P.; Leonov, Ivan; Greenberg, Eran; Rozenberg, Gregory Kh.

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: DOE - Office Of Science; FOREIGN

OSTI ID:: 1872585

Journal Information:: Sci. Rep., Vol. 12

Country of Publication:: United States

Language:: ENGLISH

References (37)

Metal-insulator transitions Imada, Masatoshi; Fujimori, Atsushi; Tokura, Yoshinori Reviews of Modern Physics, Vol. 70, Issue 4, p. 1039-1263 https://doi.org/10.1103/RevModPhys.70.1039	journal	October 1998
Strong Correlations and Magnetic Frustration in the High $T_{c}$ Iron Pnictides Si, Qimiao; Abrahams, Elihu Physical Review Letters, Vol. 101, Issue 7 https://doi.org/10.1103/PhysRevLett.101.076401	journal	August 2008
Very high pressure Mössbauer Spectroscopy using Diamond Anvil Cells Pasternak, M.; Taylor, R. D. Hyperfine Interactions, Vol. 47-48, Issue 1-4 https://doi.org/10.1007/BF02351621	journal	March 1989
Collapse of magnetic moment drives the Mott transition in MnO Kuneš, Jan; Lukoyanov, Alexey V.; Anisimov, Vladimir I. Nature Materials, Vol. 7, Issue 3 https://doi.org/10.1038/nmat2115	journal	February 2008
Another mechanism for the insulator-metal transition observed in Mott insulators Gavriliuk, Alexander G.; Struzhkin, Viktor V.; Lyubutin, Igor S. Physical Review B, Vol. 77, Issue 15 https://doi.org/10.1103/PhysRevB.77.155112	journal	April 2008
Mott transition in ${CaFe}_{2} O_{4}$ at around 50 GPa Greenberg, Eran; Rozenberg, Gregory Kh.; Xu, Weiming Physical Review B, Vol. 88, Issue 21 https://doi.org/10.1103/PhysRevB.88.214109	journal	December 2013
Spin-crossover-induced Mott transition and the other scenarios of metallization in $3 d^{n}$ metal compounds Lyubutin, I. S.; Ovchinnikov, S. G.; Gavriliuk, A. G. Physical Review B, Vol. 79, Issue 8 https://doi.org/10.1103/PhysRevB.79.085125	journal	February 2009
Research on phase transformations in 3d-metal oxides at high and ultrahigh pressure: state of the art Lyubutin, Igor S.; Gavriliuk, Aleksandr G. Physics-Uspekhi, Vol. 52, Issue 10 https://doi.org/10.3367/UFNe.0179.200910b.1047	journal	October 2009
Pressure-induced spin collapse of octahedrally coordinated ${Fe}^{3 +}$ in ${Ca}_{3} {Fe}_{2} {[SiO}_{4}]_{3}$ from experiment and theory Friedrich, Alexandra; Winkler, Björn; Morgenroth, Wolfgang Physical Review B, Vol. 90, Issue 9 https://doi.org/10.1103/PhysRevB.90.094105	journal	September 2014
Suppression of magnetism under pressure in FeS: A DFT+DMFT study Ushakov, A. V.; Shorikov, A. O.; Anisimov, V. I. Physical Review B, Vol. 95, Issue 20 https://doi.org/10.1103/PhysRevB.95.205116	journal	May 2017
Magnetic collapse and the behavior of transition metal oxides at high pressure Leonov, I.; Pourovskii, L.; Georges, A. Physical Review B, Vol. 94, Issue 15 https://doi.org/10.1103/PhysRevB.94.155135	journal	October 2016
Emergence of quantum critical charge and spin-state fluctuations near the pressure-induced Mott transition in MnO, FeO, CoO, and NiO Leonov, I.; Shorikov, A. O.; Anisimov, V. I. Physical Review B, Vol. 101, Issue 24 https://doi.org/10.1103/PhysRevB.101.245144	journal	June 2020
The ⁵⁷ Fe Synchrotron Mössbauer Source at the ESRF Potapkin, Vasily; Chumakov, Aleksandr I.; Smirnov, Gennadii V. Journal of Synchrotron Radiation, Vol. 19, Issue 4 https://doi.org/10.1107/S0909049512015579	journal	May 2012
Room‐Temperature Ferromagnetic Materials Transparent in the Visible Wolfe, R.; Kurtzig, A. J.; LeCraw, R. C. Journal of Applied Physics, Vol. 41, Issue 3 https://doi.org/10.1063/1.1658881	journal	March 1970
Transport and optical properties of iron borate FeBO3 under high pressures Troyan, I. A.; Eremets, M. I.; Gavrilyuk, A. G. Journal of Experimental and Theoretical Physics Letters, Vol. 78, Issue 1 https://doi.org/10.1134/1.1609568	journal	July 2003
Equation of state and structural phase transition in FeBO3 at high pressure Gavriliuk, A. G.; Trojan, I. A.; Boehler, R. Journal of Experimental and Theoretical Physics Letters, Vol. 75, Issue 1 https://doi.org/10.1134/1.1463109	journal	January 2002
High-Pressure Magnetic Properties and P–T Phase Diagram of Iron Borate Gavriliuk, A. G. Journal of Experimental and Theoretical Physics, Vol. 100, Issue 4 https://doi.org/10.1134/1.1926429	journal	January 2005
Intriguing sequence of GaFeO $_{3}$ structures and electronic states to 70 GPa Arielly, R.; Xu, W. M.; Greenberg, E. Physical Review B, Vol. 84, Issue 9 https://doi.org/10.1103/PhysRevB.84.094109	journal	September 2011
Charge disproportionation and site-selective local magnetic moments in the post-perovskite-type Fe2O3 under ultra-high pressures Leonov, Ivan; Rozenberg, Gregory Kh.; Abrikosov, Igor A. npj Computational Materials, Vol. 5, Issue 1 https://doi.org/10.1038/s41524-019-0225-9	journal	September 2019
Elasticity, shear strength, and equation of state of molybdenum and gold from x-ray diffraction under nonhydrostatic compression to 24 GPa Duffy, Thomas S.; Shen, Guoyin; Shu, Jinfu Journal of Applied Physics, Vol. 86, Issue 12 https://doi.org/10.1063/1.371723	journal	December 1999
Effects of temperature and composition on the bulk modulus of (Mg,Fe)O Fei, Yingwei American Mineralogist, Vol. 84, Issue 3 https://doi.org/10.2138/am-1999-0308	journal	March 1999
Deviatoric stress: a nuisance or a gold mine? Bassett, W. A. Journal of Physics: Condensed Matter, Vol. 18, Issue 25 https://doi.org/10.1088/0953-8984/18/25/S01	journal	June 2006
The effect of crystallite size and stress condition on the equation of state of nanocrystalline MgO Marquardt, H.; Speziale, S.; Marquardt, K. Journal of Applied Physics, Vol. 110, Issue 11 https://doi.org/10.1063/1.3662491	journal	December 2011
Compression of a multiphase mantle assemblage: Effects of undesirable stress and stress annealing on the iron spin state crossover in ferropericlase: Stresses and HS-LS Crossover in (Mg,Fe)O Glazyrin, Konstantin; Miyajima, Nobuyoshi; Smith, Jesse S. Journal of Geophysical Research: Solid Earth, Vol. 121, Issue 5 https://doi.org/10.1002/2015JB012321	journal	May 2016
Critical behavior of $M g_{1 - x} F e_{x} O$ at the pressure-induced iron spin-state crossover Glazyrin, K.; Sinmyo, R.; Bykova, E. Physical Review B, Vol. 95, Issue 21 https://doi.org/10.1103/PhysRevB.95.214412	journal	June 2017
Mössbauer Spectroscopy Greenwood, N. N.; Gibb, T. C. https://doi.org/10.1007/978-94-009-5697-1	book	January 1971
Superstructures at low spin–high spin transitions Khomskii, D. I.; Löw, U. Physical Review B, Vol. 69, Issue 18 https://doi.org/10.1103/PhysRevB.69.184401	journal	May 2004
Crystal structure of the thallium strontium cobaltite TlSr2CoO5 and its relationship to the electronic properties Doumerc, Jean-Pierre; Coutanceau, Martine; Demourgues, Alain Journal of Materials Chemistry, Vol. 11, Issue 1 https://doi.org/10.1039/b003198o	journal	January 2001
Fe3+ spin transition in CaFe2O4 at high pressure Merlini, M.; Hanfland, M.; Gemmi, M. American Mineralogist, Vol. 95, Issue 1 https://doi.org/10.2138/am.2010.3347	journal	December 2009
Pressure-Induced Hydrogen Bond Symmetrization in Iron Oxyhydroxide Xu, Weiming; Greenberg, Eran; Rozenberg, Gregory Kh. Physical Review Letters, Vol. 111, Issue 17 https://doi.org/10.1103/PhysRevLett.111.175501	journal	October 2013
Novel high pressure monoclinic Fe ₂ O ₃ polymorph revealed by single-crystal synchrotron X-ray diffraction studies Bykova, Elena; Bykov, Maxim; Prakapenka, Vitali High Pressure Research, Vol. 33, Issue 3 https://doi.org/10.1080/08957959.2013.833613	journal	August 2013
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Thermal Expansion Fei, Yingwei AGU Reference Shelf https://doi.org/10.1029/RF002p0029	book	January 1995
Disproportionation and Metallization at Low-Spin to High-Spin Transition in Multiorbital Mott Systems Kuneš, Jan; Křápek, Vlastimil Physical Review Letters, Vol. 106, Issue 25 https://doi.org/10.1103/PhysRevLett.106.256401	journal	June 2011
Metal-insulator transition and local-moment collapse in negative charge transfer ${CaFeO}_{3}$ under pressure Leonov, I. Physical Review B, Vol. 105, Issue 3 https://doi.org/10.1103/PhysRevB.105.035157	journal	January 2022
Growth and perfection of flux grown FeBO3 and 57FeBO3 crystals Kotrbová, M.; Kadečková, S.; Novák, J. Journal of Crystal Growth, Vol. 71, Issue 3 https://doi.org/10.1016/0022-0248(85)90368-9	journal	May 1985
Compression curves of transition metals in the Mbar range: Experiments and projector augmented-wave calculations Dewaele, Agnès; Torrent, Marc; Loubeyre, Paul Physical Review B, Vol. 78, Issue 10 https://doi.org/10.1103/PhysRevB.78.104102	journal	September 2008

Similar Records

Transition of iron ions from high-spin to low-spin state and pressure-induced insulator-metal transition in hematite Fe{sub 2}O{sub 3}

Journal Article · 2007 · Journal of Experimental and Theoretical Physics · OSTI ID:1872585

Kozhevnikov, A V; Lukoyanov, A V; Anisimov, V I

Distinct intermediate states in the isostructural R-3m phase of the topological insulator Bi[subscript 2]Se[subscript 3] at high pressure

Journal Article · 2020 · Phys. Rev. B · OSTI ID:1872585

Hong, Xinguo; Newville, Matt; Ding, Yang; +3 more

Honeycomb lattice

{Na}_{2} {IrO}_{3}

at high pressures: A robust spin-orbit Mott insulator

Journal Article · 2018 · Physical Review B · OSTI ID:1872585

Xi, Xiaoxiang; Bo, Xiangyan; Xu, X. S.; +7 more

Title: Pressure-induced high-spin/low-spin disproportionated state in the Mott insulator FeBO[subscript 3]

Citation Formats

References (37)

Similar Records

Related Subjects