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Title: Driving Barocaloric Effects in a Molecular Spin-Crossover Complex at Low Pressures

Journal Article · · J. Am. Chem. Soc.
DOI:https://doi.org/10.1021/jacs.2c01315· OSTI ID:1866438

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; National Science Foundation (NSF)
OSTI ID:
1866438
Journal Information:
J. Am. Chem. Soc., Vol. 144, Issue (14)
Country of Publication:
United States
Language:
ENGLISH

References (54)

Contribution of air conditioning adoption to future energy use under global warming journal April 2015
Limited options for low-global-warming-potential refrigerants journal February 2017
The large contribution of projected HFC emissions to future climate forcing journal June 2009
New refrigerants and system configurations for vapor-compression refrigeration journal November 2020
A review of the state of the art of solid-state caloric cooling processes at room-temperature before 2019 journal October 2019
Caloric materials for cooling and heating journal November 2020
Magnetocaloric Materials journal August 2000
Electrocaloric Materials journal August 2011
Electrocaloric Cooling Materials and Devices for Zero-Global-Warming-Potential, High-Efficiency Refrigeration journal May 2019
Torsional refrigeration by twisted, coiled, and supercoiled fibers journal October 2019
Materials with Giant Mechanocaloric Effects: Cooling by Strength journal December 2016
Novel mechanocaloric materials for solid-state cooling applications journal December 2019
Fantastic barocalorics and where to find them journal April 2021
Solid-state cooling by stress: A perspective journal February 2020
Colossal barocaloric effects in plastic crystals journal March 2019
Colossal barocaloric effects near room temperature in plastic crystals of neopentylglycol journal April 2019
Research Update: The mechanocaloric potential of spin crossover compounds journal November 2016
Spin Crossover—An Overall Perspective book January 2004
Thermal, pressure and light switchable spin-crossover materials journal January 2005
Pressure effect investigations on spin-crossover coordination compounds journal December 2018
A microscopic refrigeration process triggered through spin-crossover mechanism journal May 2017
The refrigerant capacity in spin-crossover materials: Application to [Fe(phen)2(NCS)2] journal November 2019
Large barocaloric effect in spin-crossover complex [CrI 2 (depe) 2 ] journal April 2020
Refrigeration through Barocaloric Effect Using the Spin Crossover Complex {Fe[H 2 B(pz) 2 ] 2 (bipy)} journal May 2021
Giant Barocaloric Effect at the Spin Crossover Transition of a Molecular Crystal journal March 2019
Giant and Reversible Barocaloric Effect in Trinuclear Spin‐Crossover Complex Fe 3 (bntrz) 6 (tcnset) 6 journal February 2021
Effects of Nitrogen Substitution in Poly(Pyrazolyl)Borato Ligands: From Orbital Energy Levels to C–H ⃛ O Hydrogen Bonding journal August 1996
Observation of a 331K (58°C) spin transition for bis[hydrotris(1,2,4-triazol-1-yl)borate]iron(II) by variable temperature infrared spectroscopy and magnetic susceptibility measurements journal December 2008
Heat Capacity and Thermal Damping Properties of Spin‐Crossover Molecules: A New Look at an Old Topic journal April 2020
Complete Set of Elastic Moduli of a Spin-Crossover Solid: Spin-State Dependence and Mechanical Actuation journal June 2018
Spatiotemporal dynamics of the spin transition in [ Fe ( HB ( tz ) 3 ) 2 ] single crystals journal October 2017
Vacuum deposition of high-quality thin films displaying spin transition near room temperature journal January 2017
Unprecedented switching endurance affords for high-resolution surface temperature mapping using a spin-crossover film journal July 2020
A review of elastocaloric cooling: Materials, cycles and system integrations journal April 2016
Vibrational Spectroscopy of Cyanide-Bridged, Iron(II) Spin-Crossover Coordination Polymers:  Estimation of Vibrational Contributions to the Entropy Change Associated with the Spin Transition journal September 2002
Caloric materials near ferroic phase transitions journal April 2014
Material-based figure of merit for caloric materials journal January 2018
Magnetic heat pumping near room temperature journal August 1976
Stirling‐cycle rotating magnetic refrigerators and heat engines for use near room temperature journal March 1978
General analysis of magnetic refrigeration and its optimization using a new concept: maximization of refrigerant capacity journal December 1985
A universal metric for ferroic energy materials
  • Brück, Ekkes; Yibole, Hargen; Zhang, Lian
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2074 https://doi.org/10.1098/rsta.2015.0303
journal August 2016
New developments in caloric materials for cooling applications journal June 2015
Too cool to work journal March 2015
Impact of hysteresis on caloric cooling performance journal January 2021
Thermal hysteresis and its impact on the efficiency of first-order caloric materials journal February 2020
Materials, physics and systems for multicaloric cooling journal March 2022
Fatigue-resistant high-performance elastocaloric materials made by additive manufacturing journal November 2019
Mastering hysteresis in magnetocaloric materials
  • Gutfleisch, O.; Gottschall, T.; Fries, M.
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2074 https://doi.org/10.1098/rsta.2015.0308
journal August 2016
Enhanced reversibility and unusual microstructure of a phase-transforming material journal October 2013
Triazole-Based One-Dimensional Spin-Crossover Coordination Polymers journal November 2012
Spin-Crossover Temperature Predictable from DFT Calculation for Iron(II) Complexes with 4-Substituted Pybox and Related Heteroaromatic Ligands journal June 2018
Relationship between the Molecular Structure and Switching Temperature in a Library of Spin-Crossover Molecular Materials journal July 2019
Deuterium isotope effect on the high-spin α low-spin transition in deuterated solvates of tris(2-picolylamine) iron(II) chloride journal September 1980
Deuterium isotope effect in the two-step spin-state transition of [FeII(5-NO2-sal-N(1,4,7,10))] investigated by Mössbauer spectroscopy and magnetic susceptibility journal September 1995