Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Driving Barocaloric Effects in a Molecular Spin-Crossover Complex at Low Pressures

Journal Article · · J. Am. Chem. Soc.
DOI:https://doi.org/10.1021/jacs.2c01315· OSTI ID:1866438

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; National Science Foundation (NSF)
OSTI ID:
1866438
Journal Information:
J. Am. Chem. Soc., Vol. 144, Issue (14)
Country of Publication:
United States
Language:
ENGLISH

References (54)

Contribution of air conditioning adoption to future energy use under global warming April 2015
Limited options for low-global-warming-potential refrigerants February 2017
The large contribution of projected HFC emissions to future climate forcing June 2009
New refrigerants and system configurations for vapor-compression refrigeration November 2020
A review of the state of the art of solid-state caloric cooling processes at room-temperature before 2019 October 2019
Caloric materials for cooling and heating November 2020
Magnetocaloric Materials August 2000
Electrocaloric Materials August 2011
Electrocaloric Cooling Materials and Devices for Zero-Global-Warming-Potential, High-Efficiency Refrigeration May 2019
Torsional refrigeration by twisted, coiled, and supercoiled fibers October 2019
Materials with Giant Mechanocaloric Effects: Cooling by Strength December 2016
Novel mechanocaloric materials for solid-state cooling applications December 2019
Fantastic barocalorics and where to find them April 2021
Solid-state cooling by stress: A perspective February 2020
Colossal barocaloric effects in plastic crystals March 2019
Colossal barocaloric effects near room temperature in plastic crystals of neopentylglycol April 2019
Research Update: The mechanocaloric potential of spin crossover compounds November 2016
Spin Crossover—An Overall Perspective January 2004
Thermal, pressure and light switchable spin-crossover materials January 2005
Pressure effect investigations on spin-crossover coordination compounds December 2018
A microscopic refrigeration process triggered through spin-crossover mechanism May 2017
The refrigerant capacity in spin-crossover materials: Application to [Fe(phen)2(NCS)2] November 2019
Large barocaloric effect in spin-crossover complex [CrI 2 (depe) 2 ] April 2020
Refrigeration through Barocaloric Effect Using the Spin Crossover Complex {Fe[H 2 B(pz) 2 ] 2 (bipy)} May 2021
Giant Barocaloric Effect at the Spin Crossover Transition of a Molecular Crystal March 2019
Giant and Reversible Barocaloric Effect in Trinuclear Spin‐Crossover Complex Fe 3 (bntrz) 6 (tcnset) 6 February 2021
Effects of Nitrogen Substitution in Poly(Pyrazolyl)Borato Ligands: From Orbital Energy Levels to C–H ⃛ O Hydrogen Bonding August 1996
Observation of a 331K (58°C) spin transition for bis[hydrotris(1,2,4-triazol-1-yl)borate]iron(II) by variable temperature infrared spectroscopy and magnetic susceptibility measurements December 2008
Heat Capacity and Thermal Damping Properties of Spin‐Crossover Molecules: A New Look at an Old Topic April 2020
Complete Set of Elastic Moduli of a Spin-Crossover Solid: Spin-State Dependence and Mechanical Actuation June 2018
Spatiotemporal dynamics of the spin transition in [ Fe ( HB ( tz ) 3 ) 2 ] single crystals October 2017
Vacuum deposition of high-quality thin films displaying spin transition near room temperature January 2017
Unprecedented switching endurance affords for high-resolution surface temperature mapping using a spin-crossover film July 2020
A review of elastocaloric cooling: Materials, cycles and system integrations April 2016
Vibrational Spectroscopy of Cyanide-Bridged, Iron(II) Spin-Crossover Coordination Polymers:  Estimation of Vibrational Contributions to the Entropy Change Associated with the Spin Transition September 2002
Caloric materials near ferroic phase transitions April 2014
Material-based figure of merit for caloric materials January 2018
Magnetic heat pumping near room temperature August 1976
Stirling‐cycle rotating magnetic refrigerators and heat engines for use near room temperature March 1978
General analysis of magnetic refrigeration and its optimization using a new concept: maximization of refrigerant capacity December 1985
A universal metric for ferroic energy materials August 2016
New developments in caloric materials for cooling applications June 2015
Too cool to work March 2015
Impact of hysteresis on caloric cooling performance January 2021
Thermal hysteresis and its impact on the efficiency of first-order caloric materials February 2020
Materials, physics and systems for multicaloric cooling March 2022
Fatigue-resistant high-performance elastocaloric materials made by additive manufacturing November 2019
Mastering hysteresis in magnetocaloric materials August 2016
Enhanced reversibility and unusual microstructure of a phase-transforming material October 2013
Triazole-Based One-Dimensional Spin-Crossover Coordination Polymers November 2012
Spin-Crossover Temperature Predictable from DFT Calculation for Iron(II) Complexes with 4-Substituted Pybox and Related Heteroaromatic Ligands June 2018
Relationship between the Molecular Structure and Switching Temperature in a Library of Spin-Crossover Molecular Materials July 2019
Deuterium isotope effect on the high-spin α low-spin transition in deuterated solvates of tris(2-picolylamine) iron(II) chloride September 1980
Deuterium isotope effect in the two-step spin-state transition of [FeII(5-NO2-sal-N(1,4,7,10))] investigated by Mössbauer spectroscopy and magnetic susceptibility September 1995