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Title: Pore and grain chemistry during sintering of garnet-type Li[subscript 6.4]La[subscript 3]Zr[subscrip

Journal Article · · J. Mater. Chem. A
DOI:https://doi.org/10.1039/D1TA10338E· OSTI ID:1865432

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - Office Of Science; DOE - BASIC ENERGY SCIENCES
OSTI ID:
1865432
Journal Information:
J. Mater. Chem. A, Vol. 10, Issue (16)
Country of Publication:
United States
Language:
ENGLISH

References (63)

Thermal stability and flammability of electrolytes for lithium-ion batteries journal May 2011
Materials for lithium-ion battery safety journal June 2018
Progress in electrolytes for rechargeable Li-based batteries and beyond journal April 2016
Promises, Challenges, and Recent Progress of Inorganic Solid-State Electrolytes for All-Solid-State Lithium Batteries journal February 2018
Garnet-Type Solid-State Electrolytes: Materials, Interfaces, and Batteries journal April 2020
Review on solid electrolytes for all-solid-state lithium-ion batteries journal June 2018
Room temperature elastic moduli and Vickers hardness of hot-pressed LLZO cubic garnet journal July 2012
Li Penetration in Ceramic Solid Electrolytes: Operando Microscopy Analysis of Morphology, Propagation, and Reversibility journal April 2020
Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte journal January 2017
Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12 journal October 2007
Structure and dynamics of the fast lithium ion conductor “Li7La3Zr2O12” journal January 2011
Atmosphere Controlled Processing of Ga-Substituted Garnets for High Li-Ion Conductivity Ceramics journal June 2014
Synthesis and Crystal Chemistry of the Fast Li-Ion Conductor Li 7 La 3 Zr 2 O 12 Doped with Fe journal July 2013
Lithium metal electrode kinetics and ionic conductivity of the solid lithium ion conductors “Li7La3Zr2O12” and Li7−xLa3Zr2−xTaxO12 with garnet-type structure journal May 2012
High lithium ionic conductivity in the garnet-type oxide Li7−XLa3(Zr2−X, NbX)O12 (X=0–2) journal March 2011
Structure and Li+ dynamics of Sb-doped Li7La3Zr2O12 fast lithium ion conductors journal January 2013
Synthesis, Crystal Structure, and Stability of Cubic Li 7– x La 3 Zr 2– x Bi x O 12 journal November 2016
High lithium ionic conductivity in the garnet-type oxide Li 7−2 x La 3 Zr 2− x Mo x O 12 ( x =0-0.3) ceramics by sol-gel method journal February 2017
W-Doped Li7La3Zr2O12 Ceramic Electrolytes for Solid State Li-ion Batteries journal October 2015
Improving the Li-ion conductivity and air stability of cubic Li7La3Zr2O12 by the co-doping of Nb, Y on the Zr site journal April 2018
Effect of Rb and Ta Doping on the Ionic Conductivity and Stability of the Garnet Li 7+2 xy (La 3– x Rb x )(Zr 2– y Ta y )O 12 (0 ≤ x ≤ 0.375, 0 ≤ y ≤ 1) Superionic Conductor: A First Principles Investigation journal July 2013
Synthesis of Ta and Ca doped Li7La3Zr2O12 solid-state electrolyte via simple solution method and its application in suppressing shuttle effect of Li-S battery journal May 2018
Tailor-Made Development of Fast Li Ion Conducting Garnet-Like Solid Electrolytes journal January 2010
All solid state lithium batteries based on lamellar garnet-type ceramic electrolytes journal December 2015
Garnet-type Li6.4La3Zr1.4Ta0.6O12 thin sheet: Fabrication and application in lithium–hydrogen peroxide semi-fuel cell journal November 2014
Low-temperature synthesis of cubic phase Li7La3Zr2O12 via sol-gel and ball milling induced phase transition journal February 2019
Key parameters governing the densification of cubic-Li7La3Zr2O12 Li+ conductors journal June 2017
Synthesis of nano-scale fast ion conducting cubic Li 7 La 3 Zr 2 O 12 journal September 2013
Reactive flash sintering of powders of four constituents into a single phase of a complex oxide in a few seconds below 700°C journal May 2019
Garnet related lithium ion conductor processed by spark plasma sintering for all solid state batteries journal March 2014
A general method to synthesize and sinter bulk ceramics in seconds journal April 2020
Controlling the lithium proton exchange of LLZO to enable reproducible processing and performance optimization journal January 2021
Exploring the relationship between solvent-assisted ball milling, particle size, and sintering temperature in garnet-type solid electrolytes journal February 2021
Flame made nanoparticles permit processing of dense, flexible, Li + conducting ceramic electrolyte thin films of cubic-Li 7 La 3 Zr 2 O 12 (c-LLZO) journal January 2016
Densification and ionic-conduction improvement of lithium garnet solid electrolytes by flowing oxygen sintering journal February 2014
A Simple and Highly Efficient Method toward High-Density Garnet-Type LLZTO Solid-State Electrolyte journal June 2020
In-situ small angle X-ray scattering (SAXS) – A versatile tool for clarifying the evolution of microporosity in polymer-derived ceramics journal September 2021
Tailoring grain growth and densification toward a high-performance solid-state electrolyte membrane journal January 2021
Two-step sintering strategy to prepare dense Li-Garnet electrolyte ceramics with high Li+ conductivity journal April 2018
Fiji: an open-source platform for biological-image analysis journal June 2012
Development of combined microstructure and structure characterization facility for in situ and operando studies at the Advanced Photon Source journal June 2018
Irena : tool suite for modeling and analysis of small-angle scattering journal February 2009
Nika : software for two-dimensional data reduction journal March 2012
Recent Advances in the Design of Novel β‐Titanium Alloys Using Integrated Theory, Computer Simulation, and Advanced Characterization journal April 2021
The use of Monte-Carlo simulations to calculate small-angle scattering patterns journal November 2002
Acid induced conversion towards a robust and lithiophilic interface for Li–Li 7 La 3 Zr 2 O 12 solid-state batteries journal January 2019
Small-Angle X-Ray-Scattering Investigation of Submicroscopic Porosity with Fractal Properties journal August 1984
Small angle scattering model for Pickering emulsions and raspberry particles journal March 2010
Approximations Leading to a Unified Exponential/Power-Law Approach to Small-Angle Scattering journal December 1995
Small-angle scattering of two-phase systems: determination and significance of systematic deviations from Porod's law journal February 1971
Effects of Li source on microstructure and ionic conductivity of Al-contained Li6.75La3Zr1.75Ta0.25O12 ceramics journal February 2015
Influence of the Total Porosity on the Properties of Sintered Materials—A Review journal April 2021
Oxygen Vacancies in Fast Lithium-Ion Conducting Garnets journal August 2017
Data mining of molecular dynamics data reveals Li diffusion characteristics in garnet Li7La3Zr2O12 journal January 2017
Origin of High Li + Conduction in Doped Li 7 La 3 Zr 2 O 12 Garnets journal August 2015
Biomimetic superelastic graphene-based cellular monoliths journal January 2012
Instability of the Lithium Garnet Li 7 La 3 Sn 2 O 12 : Li + /H + Exchange and Structural Study journal April 2011
The reaction of Li6.5La3Zr1.5Ta0.5O12 with water journal January 2015
Effect of Li+/H+ exchange in water treated Ta-doped Li7La3Zr2O12 journal September 2016
From order to disorder: The structure of lithium-conducting garnets Li7−xLa3TaxZr2−xO12 (x=0–2) journal January 2012
Annular dynamical disorder of the rare earth ions in a La2Zr2O7 pyrochlore via single crystal synchrotron X-ray diffraction journal January 2001
Influence of Li + and H + Distribution on the Crystal Structure of Li 7– x H x La 3 Zr 2 O 12 (0 ≤ x ≤ 5) Garnets journal January 2016
In situ atomic scale investigation of Li7La3Zr2O12-based Li+-conducting solid electrolyte during calcination growth journal May 2020