Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Method of producing thin layer of large area transition metal dichalcogenides MoS2 and others

Patent ·
OSTI ID:1859932

An ultra-thin film transition metal dichalcogenide (“TMD”) supported on a support. The TMD is formed from a metal grown by atomic layer deposition (“ALD”) on a substrate. The metal is sulphurized to produce a TMD ultra-thin layer.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
Assignee:
UChicago Argonne, LLC (Chicago, IL)
Patent Number(s):
11,142,824
Application Number:
16/391,876
OSTI ID:
1859932
Country of Publication:
United States
Language:
English

References (55)

A review of recent advances in solid film lubrication journal March 1987
Wafer-scale growth of MoS 2 thin films by atomic layer deposition journal January 2016
Transition Metal–MoS2 Reactions: Review and Thermodynamic Predictions journal August 2015
Area‐Selective Growth of HfS 2 Thin Films via Atomic Layer Deposition at Low Temperature journal October 2020
Oxidation Effect in Octahedral Hafnium Disulfide Thin Film journal December 2015
Emerging Photoluminescence in Monolayer MoS2 journal April 2010
Preparation of MoS2 thin films by chemical vapor deposition journal June 1994
Electric Field Effect in Atomically Thin Carbon Films journal October 2004
Photoluminescence from Chemically Exfoliated MoS2 journal December 2011
2D nanosheet molybdenum disulphide (MoS2) modified electrodes explored towards the hydrogen evolution reaction journal January 2015
Continuous ultra-thin MoS2 films grown by low-temperature physical vapor deposition journal June 2014
Atomic Layer Deposition of Crystalline MoS 2 Thin Films: New Molybdenum Precursor for Low-Temperature Film Growth journal March 2017
Preparation of High Concentration Dispersions of Exfoliated MoS 2 with Increased Flake Size journal June 2012
Selective Molybdenum Deposition by LPCVD journal January 1987
Advances in the Synthesis of Inorganic Nanotubes and Fullerene-Like Nanoparticles journal November 2003
Atomic layer deposition of tungsten disulphide solid lubricant thin films journal December 2004
Recent progress in atomic layer deposition of molybdenum disulfide: a mini review journal March 2019
Conducting MoS 2 Nanosheets as Catalysts for Hydrogen Evolution Reaction journal November 2013
Detailed photocurrent spectroscopy of the semiconducting group VIB transition metal dichalcogenides journal February 1982
Inkjet Printing of MoS 2 journal August 2014
Establishment of 2D Crystal Heterostructures by Sulfurization of Sequential Transition Metal Depositions: Preparation, Characterization, and Selective Growth journal October 2016
Atomic Layer Deposited MoS 2 as a Carbon and Binder Free Anode in Li-ion Battery journal November 2014
Crystal orientation and near-interface structure of chemically vapor deposited MoS2 films journal January 1995
Surface Oxidation of Molybdenum Disulfide journal September 1955
Synthesis of MoS2 Thin Film by Chemical Vapor Deposition Method and Discharge Characteristics as a Cathode of the Lithium Secondary Battery journal August 1992
Reaction mechanism of core–shell MoO 2 /MoS 2 nanoflakes via plasma-assisted sulfurization of MoO 3 journal May 2016
Atomic layer deposition of molybdenum disulfide films using MoF 6 and H 2 S
  • Mane, Anil U.; Letourneau, Steven; Mandia, David J.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 36, Issue 1 https://doi.org/10.1116/1.5003423
journal January 2018
Low temperature deposition of 2D WS2 layers from WF6 and H2S precursors: impact of reducing agents journal January 2015
Large-Area Vapor-Phase Growth and Characterization of MoS2 Atomic Layers on a SiO2 Substrate journal February 2012
Wafer-scale, conformal and direct growth of MoS2 thin films by atomic layer deposition journal March 2016
Bottom-up synthesis of vertically oriented two-dimensional materials journal October 2016
Controlled Scalable Synthesis of Uniform, High-Quality Monolayer and Few-layer MoS2 Films journal May 2013
Molybdenum Atomic Layer Deposition Using MoF 6 and Si 2 H 6 as the Reactants journal April 2011
Atomic-Scale Structure of Single-Layer MoS 2 Nanoclusters journal January 2000
Nucleation and growth during the atomic layer deposition of W on Al2O3 and Al2O3 on W journal November 2004
Atomic layer deposition of two dimensional MoS 2 on 150 mm substrates
  • Valdivia, Arturo; Tweet, Douglas J.; Conley, John F.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 34, Issue 2 https://doi.org/10.1116/1.4941245
journal March 2016
Ultralarge atomically flat template-stripped Au surfaces for scanning probe microscopy journal July 1993
Growth, structure, and tribological behavior of atomic layer-deposited tungsten disulphide solid lubricant coatings with applications to MEMS journal October 2006
Synthesis of Large-Area Highly Crystalline Monolayer Molybdenum Disulfide with Tunable Grain Size in a H 2 Atmosphere journal September 2015
In situ growth of double-layer MoO3/MoS2 film from MoS2 for hole-transport layers in organic solar cell journal January 2014
Atomic Layer Deposition: An Overview journal January 2010
1T-MoS 2 , a new metallic modification of molybdenum disulfide journal January 1992
Low-Temperature Atomic Layer Deposition of MoS 2 Films journal April 2017
Single-layer MoS2 journal April 1986
From Bulk to Monolayer MoS2: Evolution of Raman Scattering journal January 2012
Atomic layer deposition of a MoS 2 film journal January 2014
Novel chemical route for atomic layer deposition of MoS 2 thin film on SiO 2 /Si substrate journal January 2014
Review Article: Progress in fabrication of transition metal dichalcogenides heterostructure systems
  • Dong, Rui; Kuljanishvili, Irma
  • Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 35, Issue 3 https://doi.org/10.1116/1.4982736
journal May 2017
Single-layer MoS2 transistors journal January 2011
The Vapor Pressures of Sulphur between 100° and 550° with related Thermal Data journal December 1929
Viscous flow reactor with quartz crystal microbalance for thin film growth by atomic layer deposition journal August 2002
Atomic Layer Deposition of Emerging 2D Semiconductors, HfS2 and ZrS2, for Optoelectronics journal August 2019
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets journal April 2013
Fast detection and low power hydrogen sensor using edge-oriented vertically aligned 3-D network of MoS 2 flakes at room temperature journal August 2017
Atomic layer deposition of MoS 2 thin films journal February 2015