Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Site Densities, Rates, and Mechanism of Stable Ni/UiO-66 Ethylene Oligomerization Catalysts

Journal Article · · J. Am. Chem. Soc.
DOI:https://doi.org/10.1021/jacs.1c09320· OSTI ID:1855476

Research Organization:
Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Organization:
DOE - Office Of Science; DOE - BASIC ENERGY SCIENCES
OSTI ID:
1855476
Journal Information:
J. Am. Chem. Soc., Journal Name: J. Am. Chem. Soc. Journal Issue: (48) Vol. 143
Country of Publication:
United States
Language:
ENGLISH

References (36)

Ethene oligomerization on nickel microporous and mesoporous-supported catalysts: Investigation of the active sites journal January 2018
Computationally Guided Discovery of a Catalytic Cobalt-Decorated Metal–Organic Framework for Ethylene Dimerization journal October 2016
Ethene Oligomerization in Ni-Containing Zeolites: Theoretical Discrimination of Reaction Mechanisms journal January 2016
Vanadium-Node-Functionalized UiO-66: A Thermally Stable MOF-Supported Catalyst for the Gas-Phase Oxidative Dehydrogenation of Cyclohexene journal June 2014
Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000 journal October 2014
A Method for Assessing Catalyst Deactivation: A Case Study on Methanol-to-Hydrocarbons Conversion journal June 2019
Oligomerization of Ethylene to α-Olefins: Discovery and Development of the Shell Higher Olefin Process (SHOP) journal October 2013
Beyond the Active Site: Tuning the Activity and Selectivity of a Metal–Organic Framework-Supported Ni Catalyst for Ethylene Dimerization journal August 2018
Evidence for the Coordination–Insertion Mechanism of Ethene Dimerization at Nickel Cations Exchanged onto Beta Molecular Sieves journal October 2018
Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires journal July 2017
Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst journal February 2016
Oligomerization of Monoolefins by Homogeneous Catalysts journal September 2009
Influence of ethylene and acetylene on the rate and reversibility of methane dehydroaromatization on Mo/H-ZSM-5 catalysts journal January 2020
Stabilization of active, selective, and regenerable Ni-based dimerization catalysts by condensation of ethene withinordered mesopores journal August 2017
Thermodynamics of Environment-Dependent Oxygen Chemisorption on Pt(111) journal June 2008
Metal–Organic Framework Supported Single Site Chromium(III) Catalyst for Ethylene Oligomerization at Low Pressure and Temperature journal December 2018
Ethene Dimerization on Zeolite-Hosted Ni Ions: Reversible Mobilization of the Active Site journal May 2019
Industrial applications of olefin metathesis journal April 2004
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953
journal October 2008
Single Ni atoms and Ni4 clusters have similar catalytic activity for ethylene dimerization journal October 2017
A facile synthesis of UiO-66, UiO-67 and their derivatives journal January 2013
Definitive Molecular Level Characterization of Defects in UiO-66 Crystals journal August 2015
Surface oxides of the oxygen–copper system: Precursors to the bulk oxide phase? journal December 2007
Dimerization of Linear Butenes on Zeolite-Supported Ni 2+ journal November 2018
Oligomerization of .alpha.-olefins to higher oligomers journal June 1991
Selective Dimerization of Propylene with Ni-MFU-4 l journal April 2017
Tuned to Perfection: Ironing Out the Defects in Metal–Organic Framework UiO-66 journal July 2014
Selective Propene Oligomerization with Nickel(II)-Based Metal–Organic Frameworks journal January 2014
Late-Metal Catalysts for Ethylene Homo- and Copolymerization journal April 2000
Computational screening of MOF-supported transition metal catalysts for activity and selectivity in ethylene dimerization journal April 2018
Nature of Active Nickel Sites and Initiation Mechanism for Ethylene Oligomerization on Heterogeneous Ni-beta Catalysts journal March 2018
Catalysis in a Cage: Condition-Dependent Speciation and Dynamics of Exchanged Cu Cations in SSZ-13 Zeolites journal April 2016
Highly Active and Stable Single-Atom Cu Catalysts Supported by a Metal–Organic Framework journal March 2019
Mechanism of Single-Site Molecule-Like Catalytic Ethylene Dimerization in Ni-MFU-4 l journal January 2017
Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol journal June 2015
A General Strategy for the Synthesis of Functionalised UiO-66 Frameworks: Characterisation, Stability and CO 2 Adsorption Properties journal February 2013

Similar Records

Site Densities, Rates, and Mechanism of Stable Ni/UiO-66 Ethylene Oligomerization Catalysts
Journal Article · 2022 · J. Am. Chem. Soc. · OSTI ID:1854194

Validation of the Cossee–Arlman mechanism for propylene oligomerization on Ni/UiO-66
Journal Article · 2023 · Catalysis Science and Technology · OSTI ID:2000728

Related Subjects