Selective Separation and Complexation of Trivalent Actinide and Lanthanide by a Tetradentate Soft–Hard Donor Ligand: Solvent Extraction, Spectroscopy, and DFT Calculations
|
journal
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March 2019 |
Soft-donor dipicolinamide derivatives for selective actinide( iii )/lanthanide( iii ) separation: the role of S- vs. O-donor sites
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journal
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January 2019 |
Exploring Soft Donor Character of the N -2-Pyrazinylmethyl Group by Coordinating Trivalent Actinides and Lanthanides Using Aminopolycarboxylates
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journal
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August 2019 |
The Separation of Americium and Curium from the Rare Earth Elements
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journal
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June 1950 |
An Ion-exchange Study of Possible Hybridized 5f Bonding in the Actinides 1
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journal
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March 1954 |
Comparison of Covalency in the Complexes of Trivalent Actinide and Lanthanide Cations
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journal
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August 2002 |
Sulfur donating extractants for the separation of trivalent actinides and lanthanides
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journal
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October 2020 |
Thermodynamic Considerations of Covalency in Trivalent Actinide-(poly)aminopolycarboxylate Interactions
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journal
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January 2016 |
On the Origin of Covalent Bonding in Heavy Actinides
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journal
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July 2017 |
Characterization of Actinide Bonding in Th(S 2 PMe 2 ) 4 by Synchrotron X-ray Diffraction
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journal
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September 1998 |
Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR 2 ) 2 ] 3 Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, i Pr, H)
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journal
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January 2008 |
A Complete Family of Terminal Uranium Chalcogenides, [U(E)(N{SiMe 3 } 2 ) 3 ] − (E = O, S, Se, Te)
|
journal
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September 2012 |
Synthesis and Spectroscopic and Computational Characterization of the Chalcogenido-Substituted Analogues of the Uranyl Ion, [OUE] 2+ (E = S, Se)
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journal
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March 2013 |
Dithio- and Diselenophosphinate Thorium(IV) and Uranium(IV) Complexes: Molecular and Electronic Structures, Spectroscopy, and Transmetalation Reactivity
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journal
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December 2015 |
Synthesis of Terminal Uranium(IV) Disulfido and Diselenido Compounds by Activation of Elemental Sulfur and Selenium
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journal
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October 2013 |
Uncovering f-element bonding differences and electronic structure in a series of 1 : 3 and 1 : 4 complexes with a diselenophosphinate ligand
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journal
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January 2013 |
Trivalent Uranium Phenylchalcogenide Complexes: Exploring the Bonding and Reactivity with CS 2 in the Tp* 2 UEPh Series (E = O, S, Se, Te)
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journal
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November 2014 |
Use of 77 Se and 125 Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(E n ){N(SiMe 3 ) 2 } 3 ] − (E = Se, Te; n = 1, 2) and Their Oxo-Uranium(VI) Congeners
|
journal
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January 2016 |
Molecular Thorium Compounds with Dichalcogenide Ligands: Synthesis, Structure, 77 Se NMR Study, and Thermolysis
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journal
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November 2018 |
Thorium Cubanes–Synthesis, Solid-State and Solution Structures, Thermolysis, and Chalcogen Exchange Reactions
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journal
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May 2018 |
Actinide-Pnictide (An−Pn) Bonds Spanning Non-Metal, Metalloid, and Metal Combinations (An=U, Th; Pn=P, As, Sb, Bi)
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journal
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December 2017 |
Systematic Investigation of Thorium(IV)– and Uranium(IV)–Ligand Bonding in Dithiophosphonate, Thioselenophosphinate, and Diselenophosphonate Complexes
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journal
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August 2013 |
Triamidoamine uranium(IV)–arsenic complexes containing one-, two- and threefold U–As bonding interactions
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journal
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June 2015 |
Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex
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journal
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October 2015 |
Insertion of t BuNC into thorium–phosphorus and thorium–arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry
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journal
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January 2016 |
Metal-Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes
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journal
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November 2017 |
Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
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journal
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March 2017 |
Cyaarside (CAs − ) and 1,3-Diarsaallendiide (AsCAs 2− ) Ligands Coordinated to Uranium and Generated via Activation of the Arsaethynolate Ligand (OCAs − )
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journal
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January 2019 |
As≡UF 3 Molecule with a Weak Triple Bond to Uranium
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journal
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June 2009 |
Eight coordinate 1,2-bis(dimethylarsino) and 1,2-bis(dimethylphosphino)-benzene complexes of uranium tetrachloride, UCl4[(1,2-Me2E)2C6H4]2 where E is As or P
|
journal
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September 2016 |
Bicyclisches As6 als komplexligand
|
journal
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December 1994 |
Importance of Energy Level Matching for Bonding in Th 3+ -Am 3+ Actinide Metallocene Amidinates, (C 5 Me 5 ) 2 [ i PrNC(Me)N i Pr]An
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journal
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November 2010 |
Energy-Degeneracy-Driven Covalency in Actinide Bonding
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journal
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December 2018 |
A computational investigation of orbital overlap versus energy degeneracy covalency in [UE 2 ] 2+ (E = O, S, Se, Te) complexes
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journal
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January 2020 |
The strength of actinide–element bonds from the quantum theory of atoms-in-molecules
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journal
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January 2015 |
A base-free terminal thorium phosphinidene metallocene and its reactivity toward selected organic molecules
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journal
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January 2019 |
Bicyclic P6 as Complex Ligand
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journal
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May 1991 |
Experimental and computational studies on a three-membered diphosphido thorium metallaheterocycle [η 5 -1,3-(Me 3 C) 2 C 5 H 3 ] 2 Th[η 2 -P 2 (2,4,6- i Pr 3 C 6 H 2 ) 2 ]
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journal
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January 2019 |
Formation of a Bridging Phosphinidene Thorium Complex
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journal
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November 2015 |
An Alkali-Metal Halide-Bridged Actinide Phosphinidiide Complex
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journal
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January 2019 |
Preparation of a potassium chloride bridged thorium phosphinidiide complex and its reactivity towards small organic molecules
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journal
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January 2019 |
Preparation of Actinide Phosphinidene Complexes: Steric Control of Reactivity
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journal
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January 1996 |
A Base-Free Terminal Actinide Phosphinidene Metallocene: Synthesis, Structure, Reactivity, and Computational Studies
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journal
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October 2018 |
A Lewis Base Supported Terminal Uranium Phosphinidene Metallocene
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journal
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September 2020 |
(η 5 -C 5 Me 5 ) 2 U(=P-2,4,6- t Bu 3 C 6 H 2 )(OPMe 3 ) Revisited—Its Intrinsic Reactivity toward Small Organic Molecules
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journal
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November 2020 |
Influence of the Lewis Base Ph 3 PO on the Reactivity of the Uranium Phosphinidene (η 5 -C 5 Me 5 ) 2 U(═P-2,4,6- i Pr 3 C 6 H 2 )(OPPh 3 )
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journal
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January 2021 |
Experimental and Computational Studies on a Base‐Free Terminal Uranium Phosphinidene Metallocene
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journal
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November 2020 |
Infrared spectra and density functional calculations of triplet pnictinidene N÷ThF3, P÷ThF3 and As÷ThF3 molecules
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journal
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January 2009 |
Thorium and Uranium Hydride Phosphorus and Arsenic Bearing Molecules with Single and Double Actinide-Pnictogen and Bridged Agostic Hydrogen Bonds
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journal
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February 2017 |
Dipnictogen f-Element Chemistry: A Diphosphorus Uranium Complex
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journal
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April 2021 |
Yttrium Complexes of Arsine, Arsenide, and Arsinidene Ligands
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journal
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February 2015 |
SYNTHESIS AND MOLECULAR STRUCTURE OF Mes(H)P-P(H)Mes (Mes = 2,4,6-Me 3 C 6 H 2 )
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journal
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October 1996 |
Phenylsilane as a safe, versatile alternative to hydrogen for the synthesis of actinide hydrides
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journal
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January 2015 |
Formation of Methane versus Benzene in the Reactions of (C 5 Me 5 ) 2 Th(CH 3 ) 2 with [CH 3 PPh 3 ]X (X=Cl, Br, I) Yielding Thorium-Carbene or Thorium-Ylide Complexes
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journal
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September 2017 |
Diamagnetic Corrections and Pascal's Constants
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journal
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April 2008 |
Toward reliable density functional methods without adjustable parameters: The PBE0 model
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journal
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April 1999 |
Assessment of the Perdew–Burke–Ernzerhof exchange-correlation functional
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journal
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March 1999 |
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy
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journal
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January 2005 |
Valence basis sets for relativistic energy-consistent small-core actinide pseudopotentials
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journal
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January 2003 |
Segmented contraction scheme for small-core actinide pseudopotential basis sets
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journal
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March 2004 |
Energy‐adjusted pseudopotentials for the actinides. Parameter sets and test calculations for thorium and thorium monoxide
|
journal
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May 1994 |
TURBOMOLE: Modular program suite for ab initio quantum-chemical and condensed-matter simulations
|
journal
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May 2020 |
Comparative Insertion Reactivity of CO, CO 2 , t BuCN, and t BuNC into Thorium– and Uranium–Phosphorus Bonds
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journal
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May 2020 |
Photolytic and Reductive Activations of 2‐Arsaethynolate in a Uranium–Triamidoamine Complex: Decarbonylative Arsenic‐Group Transfer Reactions and Trapping of a Highly Bent and Reduced Form
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journal
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October 2019 |
Syntheses and characterization of some solid-state actinide (Th, U, Np) compounds
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journal
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January 2010 |
X-Ray determination of the structure of Fe(CO) 4 (AsC 6 F 5 ) 2 , a complex containing “decafluoro-arsenobenzene”
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journal
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January 1971 |
Arsenic-Rich Polyarsenides Stabilized by Cp*Fe Fragments
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journal
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May 2017 |
Fixation and Release of Intact E 4 Tetrahedra (E=P, As)
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journal
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February 2015 |
Molecular Polyarsenides of the Rare-Earth Elements
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journal
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December 2015 |
Dicationic E 4 Chains (E=P, As, Sb, Bi) Embedded in the Coordination Sphere of Transition Metals
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journal
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February 2018 |
Synthesis and Reactivity of Nickel-Stabilised μ 2 :η 2 ,η 2 -P 2 , As 2 and PAs Units
|
journal
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December 2017 |
Structural Rearrangements in Triple-Decker-Like Complexes with Mixed Group 15/16 Ligands: Synthesis and Characterization of the Redox Couple [Cp2*Fe2As2Se2]/[Cp2*Fe2As2Se2]+ (Cp*=C5Me5)
|
journal
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March 2001 |
Metallaheteroborane chemistry. Part 9. Syntheses and spectroscopy of platinum and palladium phosphine complexes containing η 5 -{As 2 B 9 }-based cluster ligands. Crystal structures of [3,3-L 2 -closo-3,1,2-PtAs 2 B 9 H 9 ](L = PPh 3 or PMe 2 Ph) and [3-Cl-3,8-(PPh 3 ) 2 -closo-3,1,2-PdAs 2 B 9 H 8 ]
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journal
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January 1991 |
New chemistry of 1,2-closo-P2B10H10 and 1,2-closo-As2B10H10; in silico and gas electron diffraction structures, and new metalladiphospha- and metalladiarsaboranes
|
journal
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January 2011 |
Pentahapto-bonded gold heteroborane clusters [3-(R3P)-closo-2,1-AuTeB10H10]? and [3-(R3P)-closo-3,1,2-AuAs2B9H9]?
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journal
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January 2006 |
Conformational polymorphism and fluxional behaviour of M(PR 3 ) 2 units in closo-twelve-atom metallaheteroboranes with MX 2 B 9 (X = C or As) and MZB 10 cages (Z = S, Se or Te)
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journal
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January 1996 |
The synthesis and chemistry of icosahedral bis(phosphine)metalladiarsaboranes and -distibaboranes containing nickel and palladium. Crystal and molecular structures of closo-1,1-(Me2PPh)2-1,2,3-PdAs2B9H9, closo-1,6-Cl2-1,5-(Me2PPh)2-1,2,3-PdAs2B9H7.CH2Cl2, and closo-1,1-(Me2PPh)2-1,2,3-PdSb2B9H9
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journal
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July 1993 |
(3-tert-Butyl isocyanide)-3,8-bis(dimethylphenylphosphine)octahydro-1,2-diarsa-3-pallada-closo-dodecaboron(1+) Hexafluoroantimonate
|
journal
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August 1995 |
Reactions of low-coordinate transition-metal amides with secondary phosphanes and arsanes: synthesis, structural, and spectroscopic studies of [M{N(SiMe3)2}(.mu.-PMes2)]2 (M = manganese, iron), [Mn{N(SiMe3)2}(.mu.-AsMes2)]2 and Mes2AsAsMes2
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journal
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April 1991 |
Aryl-substituted triarsiranes: synthesis and reactivity
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journal
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January 2021 |
Agostic interactions in transition metal compounds
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journal
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April 2007 |
sp3 versus sp2 C–H bond activation chemistry of 2-picoline by Th(IV) and U(IV) metallocene complexes
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journal
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October 2007 |
A transient lanthanum phosphinidene complex
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journal
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January 2020 |
Double insertion of benzophenone into thorium-phosphorus bonds
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journal
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February 2018 |
Formation and reactivity of the early metal phosphides and phosphinidenes Cp*2Zr:PR, Cp*2Zr(PR)2, and Cp*2Zr(PR)3
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journal
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August 1993 |
Triphosphanato (R3P32−), primary phosphido (RPH−) and diphosphanato (diphosphene) (R2P22−) complexes of zirconium and hafnium metallocenes
|
journal
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January 1989 |
Trends in Covalency for d- and f-Element Metallocene Dichlorides Identified Using Chlorine K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory
|
journal
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September 2009 |
A selective route to aryl-triphosphiranes and their titanocene-induced fragmentation
|
journal
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January 2019 |
Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes
|
journal
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March 2014 |
Is the structure of selenoformamide similar to those of formamide and thioformamide?
|
journal
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December 1992 |
Synthesis and characterization of bis(pentamethylcyclopentadienyl)uranium(IV) and -thorium(IV) compounds containing the bis(trimethylsilyl)phosphide ligand
|
journal
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March 1993 |
Influence of Substituents on the Electronic Structure of Mono- and Bis(phosphido) Thorium(IV) Complexes
|
journal
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June 2018 |
Formation of an α-Diimine from Isocyanide Coupling Using Thorium(IV) and Uranium(IV) Phosphido–Methyl Complexes
|
journal
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April 2019 |
Organoactinide phosphine/phosphite coordination chemistry. Facile hydride-induced dealkoxylation and the formation of actinide phosphinidene complexes
|
journal
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May 1984 |
Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
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journal
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September 2016 |
Density Functional Theory Investigation of the Redox Properties of Tricyclopentadienyl- and Phospholyluranium(IV) Chloride Complexes
|
journal
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June 2012 |
Activation of carbon dioxide by new mixed sandwich uranium( iii ) complexes incorporating cyclooctatetraenyl and pyrrolide, phospholide, or arsolide ligands
|
journal
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January 2015 |
Trends in Electronic Structure and Redox Energetics for Early-Actinide Pentamethylcyclopentadienyl Complexes
|
journal
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October 2004 |
Facile Access to Pentavalent Uranium Organometallics: One-Electron Oxidation of Uranium(IV) Imido Complexes with Copper(I) Salts
|
journal
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October 2007 |
Crystalline Diuranium Phosphinidiide and μ-Phosphido Complexes with Symmetric and Asymmetric UPU Cores
|
journal
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July 2017 |
Systematic Studies of Early Actinide Complexes: Uranium(IV) Fluoroketimides
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journal
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September 2007 |
Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with U IV –E–U IV cores (E = S, Se, Te): implications for determining the presence or absence of actinide–actinide magnetic exchange
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journal
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January 2017 |
Activation of Triphenylphosphine Oxide Mediated by Trivalent Organouranium Species
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journal
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March 2018 |
Synthesis and x-ray crystallographic characterization of an oxo-bridged bimetallic organosamarium complex, [(C5Me5)2Sm]2(.mu.-O)
|
journal
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January 1985 |
Chemistry of trivalent uranium metallocenes: electron-transfer reactions. Synthesis and characterization of [(MeC5H4)3U]2E (E = S, Se, Te) and the crystal structures of hexakis(methylcyclopentadienyl)sulfidodiuranium and tris(methylcyclopentadienyl)(triphenylphosphine oxide)uranium
|
journal
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May 1986 |
Reduction of phosphine oxides to phosphines
|
journal
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February 2019 |
Direct and Scalable Electroreduction of Triphenylphosphine Oxide to Triphenylphosphine
|
journal
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January 2020 |
Beyond CO 2 Reduction: Vistas on Electrochemical Reduction of Heavy Non-metal Oxides with Very Strong E—O Bonds (E = Si, P, S)
|
journal
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August 2020 |
Direct Electrochemical P(V) to P(III) Reduction of Phosphine Oxide Facilitated by Triaryl Borates
|
journal
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October 2018 |
Thorium Oxo and Sulfido Metallocenes: Synthesis, Structure, Reactivity, and Computational Studies
|
journal
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August 2011 |
Covalency in AnCl 3 (An = Th–No)
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journal
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January 2021 |
Functionalization of Carbon Monoxide and tert -Butyl Nitrile by Intramolecular Proton Transfer in a Bis(Phosphido) Thorium Complex
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journal
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November 2018 |