Nanoporous Pd-Cu thin films as highly active and durable catalysts for oxygen reduction in alkaline media

Xie, Yunxiang; Li, Can; Castillo, Ezer; Fang, Jiye; Dimitrov, Nikolay

doi:10.1016/j.electacta.2021.138306

Nanoporous Pd-Cu thin films as highly active and durable catalysts for oxygen reduction in alkaline media

Journal Article · 01 July 2021 · Electrochimica Acta

DOI:https://doi.org/10.1016/j.electacta.2021.138306· OSTI ID:1853271

; ; Castillo, Ezer; Fang, Jiye;

Not provided.

Research Organization:: Cornell Univ., Ithaca, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0019445

OSTI ID:: 1853271

Journal Information:: Electrochimica Acta, Vol. 385, Issue C; ISSN 0013-4686

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

References (43)

Electrochemistry and the Future of the Automobile Wagner, Frederick T.; Lakshmanan, Balasubramanian; Mathias, Mark F. The Journal of Physical Chemistry Letters, Vol. 1, Issue 14 https://doi.org/10.1021/jz100553m	journal	June 2010
Anion exchange membrane fuel cells: Current status and remaining challenges Gottesfeld, Shimshon; Dekel, Dario R.; Page, Miles Journal of Power Sources, Vol. 375 https://doi.org/10.1016/j.jpowsour.2017.08.010	journal	January 2018
Beyond catalysis and membranes: visualizing and solving the challenge of electrode water accumulation and flooding in AEMFCs Omasta, Travis J.; Park, Andrew M.; LaManna, Jacob M. Energy & Environmental Science, Vol. 11, Issue 3 https://doi.org/10.1039/C8EE00122G	journal	January 2018
Electrocatalysis of oxygen reduction on heteroatom-doped nanocarbons and transition metal–nitrogen–carbon catalysts for alkaline membrane fuel cells Sarapuu, Ave; Kibena-Põldsepp, Elo; Borghei, Maryam Journal of Materials Chemistry A, Vol. 6, Issue 3 https://doi.org/10.1039/C7TA08690C	journal	January 2018
Electrocatalyst approaches and challenges for automotive fuel cells Debe, Mark K. Nature, Vol. 486, Issue 7401 https://doi.org/10.1038/nature11115	journal	June 2012
Oxygen Reduction in Alkaline Media: From Mechanisms to Recent Advances of Catalysts Ge, Xiaoming; Sumboja, Afriyanti; Wuu, Delvin ACS Catalysis, Vol. 5, Issue 8 https://doi.org/10.1021/acscatal.5b00524	journal	July 2015
Oxygen reduction reaction activity of Pd-based bimetallic electrocatalysts in alkaline medium Bampos, Georgios; Sygellou, Labrini; Bebelis, Symeon Catalysis Today, Vol. 355 https://doi.org/10.1016/j.cattod.2019.06.010	journal	September 2020
Electrochemical reduction of oxygen in alkaline solution on Pd/C catalysts prepared by electrodeposition on various carbon nanomaterials Lüsi, Madis; Erikson, Heiki; Merisalu, Maido Journal of Electroanalytical Chemistry, Vol. 834 https://doi.org/10.1016/j.jelechem.2018.12.061	journal	February 2019
Highly active and durable Pd-Cu catalysts for oxygen reduction in alkaline exchange membrane fuel cells Peng, Xiong; Omasta, Travis J.; Roller, Justin M. Frontiers in Energy, Vol. 11, Issue 3 https://doi.org/10.1007/s11708-017-0495-1	journal	September 2017
Recent progress in oxygen reduction electrocatalysis on Pd-based catalysts Erikson, Heiki; Sarapuu, Ave; Solla-Gullón, Jose Journal of Electroanalytical Chemistry, Vol. 780 https://doi.org/10.1016/j.jelechem.2016.09.034	journal	November 2016
Revised Pourbaix Diagrams for Copper at 25 to 300°C Beverskog, B. Journal of The Electrochemical Society, Vol. 144, Issue 10 https://doi.org/10.1149/1.1838036	journal	January 1997
Oxygen reduction on Nafion-coated thin-film palladium electrodes Erikson, Heiki; Kasikov, Aarne; Johans, Christoffer Journal of Electroanalytical Chemistry, Vol. 652, Issue 1-2 https://doi.org/10.1016/j.jelechem.2010.12.021	journal	March 2011
Rapid Room-Temperature Synthesis of a Metastable Ordered Intermetallic Electrocatalyst Wang, Yunfei; Sun, Du; Chowdhury, Tomojit Journal of the American Chemical Society, Vol. 141, Issue 6 https://doi.org/10.1021/jacs.8b09919	journal	January 2019
Enhancing the Electrocatalytic Activity of Pd/M (M = Ni, Mn) Nanoparticles for the Oxygen Reduction Reaction in Alkaline Media through Electrochemical Dealloying Lu, Xinyao; Ahmadi, Mahdi; DiSalvo, Francis J. ACS Catalysis, Vol. 10, Issue 10 https://doi.org/10.1021/acscatal.9b05499	journal	April 2020
Enhanced ORR Kinetics on Au-Doped Pt–Cu Porous Films in Alkaline Media Xie, Yunxiang; Yang, Yao; Muller, David A. ACS Catalysis, Vol. 10, Issue 17 https://doi.org/10.1021/acscatal.0c02690	journal	August 2020
Ultralow Pt loading nanoporous Au-Cu-Pt thin film as highly active and durable catalyst for formic acid oxidation Xie, Yunxiang; Dimitrov, Nikolay Applied Catalysis B: Environmental, Vol. 263 https://doi.org/10.1016/j.apcatb.2019.118366	journal	April 2020
Improved catalysis of room temperature synthesized Pd-Cu alloy nanoparticles for anodic oxidation of ethanol in alkaline media Mukherjee, Parthasarathi; Roy, Partha Sarathi; Mandal, Kaustab Electrochimica Acta, Vol. 154 https://doi.org/10.1016/j.electacta.2014.12.054	journal	February 2015
Oxygen Electroreduction in Alkaline Solution on Pd Coatings Prepared by Galvanic Exchange of Copper Lüsi, Madis; Erikson, Heiki; Merisalu, Maido Electrocatalysis, Vol. 9, Issue 3 https://doi.org/10.1007/s12678-017-0445-z	journal	December 2017
Atomic origins of the high catalytic activity of nanoporous gold Fujita, Takeshi; Guan, Pengfei; McKenna, Keith Nature Materials, Vol. 11, Issue 9 https://doi.org/10.1038/nmat3391	journal	August 2012
Fabrication, microstructure and electrocatalytic property of novel nanoporous palladium composites Wang, Xiaoguang; Wang, Weimin; Qi, Zhen Journal of Alloys and Compounds, Vol. 508, Issue 2 https://doi.org/10.1016/j.jallcom.2010.08.094	journal	October 2010
Pd–M/C (M = Pd, Cu, Pt) Electrocatalysts for Oxygen Reduction Reaction in Alkaline Medium: Correlating the Electronic Structure with Activity Castegnaro, Marcus V.; Paschoalino, Waldemir J.; Fernandes, Mauro R. Langmuir, Vol. 33, Issue 11 https://doi.org/10.1021/acs.langmuir.7b00098	journal	March 2017
Theoretical means for searching bimetallic alloys as anode electrocatalysts for direct liquid-feed fuel cells Demirci, Umit B. Journal of Power Sources, Vol. 173, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.04.069	journal	November 2007
Active surface area determination of Pd-Si alloys by H-adsorption Correia, A. N.; Mascaro, L. H.; Machado, S. A. S. Electrochimica Acta, Vol. 42, Issue 3 https://doi.org/10.1016/S0013-4686(96)00232-0	journal	January 1997
Electrochemical reduction of NOx species at the interface of nanostructured Pd and PdCu catalysts in alkaline conditions Soto-Hernández, J.; Santiago-Ramirez, C. R.; Ramirez-Meneses, E. Applied Catalysis B: Environmental, Vol. 259 https://doi.org/10.1016/j.apcatb.2019.118048	journal	December 2019
Enhanced Catalytic Activities of NiPt Truncated Octahedral Nanoparticles toward Ethylene Glycol Oxidation and Oxygen Reduction in Alkaline Electrolyte Xia, Tianyu; Liu, Jialong; Wang, Shouguo ACS Applied Materials & Interfaces, Vol. 8, Issue 17 https://doi.org/10.1021/acsami.6b01115	journal	April 2016
The electrodeposition and electrocatalytic properties of copper–palladium alloys Milhano, Clelia; Pletcher, Derek Journal of Electroanalytical Chemistry, Vol. 614, Issue 1-2 https://doi.org/10.1016/j.jelechem.2007.11.001	journal	March 2008
Evolution of nanoporosity in dealloying Erlebacher, Jonah; Aziz, Michael J.; Karma, Alain Nature, Vol. 410, Issue 6827, p. 450-453 https://doi.org/10.1038/35068529	journal	March 2001
Hydrogen oxidation kinetics on model Pd/C electrodes: Electrochemical impedance spectroscopy and rotating disk electrode study Pronkin, Sergey N.; Bonnefont, Antoine; Ruvinskiy, Pavel S. Electrochimica Acta, Vol. 55, Issue 9 https://doi.org/10.1016/j.electacta.2010.01.060	journal	March 2010
Unique Electrochemical Adsorption Properties of Pt-Skin Surfaces van der Vliet, Dennis F.; Wang, Chao; Li, Dongguo Angewandte Chemie, Vol. 124, Issue 13 https://doi.org/10.1002/ange.201107668	journal	February 2012
DFT Study on Intermetallic Pd–Cu Alloy with Cover Layer Pd as Efficient Catalyst for Oxygen Reduction Reaction Liu, Ji; Fan, Xiaofeng; Sun, Chang Materials, Vol. 11, Issue 1 https://doi.org/10.3390/ma11010033	journal	December 2017
Probing the Limits of d-Band Center Theory: Electronic and Electrocatalytic Properties of Pd-Shell–Pt-Core Nanoparticles Gorzkowski, Maciej T.; Lewera, Adam The Journal of Physical Chemistry C, Vol. 119, Issue 32 https://doi.org/10.1021/acs.jpcc.5b05302	journal	July 2015
Surface electrochemistry of CO on Pt(): anion effects Marković, N. M.; Lucas, C. A.; Rodes, A. Surface Science, Vol. 499, Issue 2-3 https://doi.org/10.1016/S0039-6028(01)01821-0	journal	March 2002
Electrooxidation of adsorbed CO on Pt(111) and Pt(111)/Ru in alkaline media and comparison with results from acidic media Spendelow, J. S.; Lu, G. Q.; Kenis, P. J. A. Journal of Electroanalytical Chemistry, Vol. 568 https://doi.org/10.1016/j.jelechem.2004.01.018	journal	July 2004
Combinatorial Studies of Palladium-Based Oxygen Reduction Electrocatalysts for Alkaline Fuel Cells Yang, Yao; Chen, Guanyu; Zeng, Rui Journal of the American Chemical Society, Vol. 142, Issue 8 https://doi.org/10.1021/jacs.9b13400	journal	February 2020
Experimental Protocol for HOR and ORR in Alkaline Electrochemical Measurements Campos-Roldán, C. A.; González-Huerta, R. G.; Alonso-Vante, N. Journal of The Electrochemical Society, Vol. 165, Issue 15 https://doi.org/10.1149/2.0011815jes	journal	January 2018
Catalytic Activity of Pd/Cu Random Alloy Nanoparticles for Oxygen Reduction Tang, Wenjie; Zhang, Liang; Henkelman, Graeme The Journal of Physical Chemistry Letters, Vol. 2, Issue 11 https://doi.org/10.1021/jz2004717	journal	May 2011
Elementary Mechanisms in Electrocatalysis: Revisiting the ORR Tafel Slope Holewinski, Adam; Linic, Suljo Journal of The Electrochemical Society, Vol. 159, Issue 11 https://doi.org/10.1149/2.022211jes	journal	January 2012
Tafel slopes from first principles Fletcher, Stephen Journal of Solid State Electrochemistry, Vol. 13, Issue 4 https://doi.org/10.1007/s10008-008-0670-8	journal	October 2008
The effect of alloying of transition metals (M = Fe, Co, Ni) with palladium catalysts on the electrocatalytic activity for the oxygen reduction reaction in alkaline media Gunji, Takao; Wakabayashi, Ryo H.; Noh, Seung Hyo Electrochimica Acta, Vol. 283 https://doi.org/10.1016/j.electacta.2018.06.051	journal	September 2018
Charge redistribution in core-shell nanoparticles to promote oxygen reduction Tang, Wenjie; Henkelman, Graeme The Journal of Chemical Physics, Vol. 130, Issue 19 https://doi.org/10.1063/1.3134684	journal	May 2009
Carbon supported Pd-based bimetallic and trimetallic catalyst for formic acid electrochemical oxidation Hu, Shuozhen; Munoz, Fabian; Noborikawa, Jennifer Applied Catalysis B: Environmental, Vol. 180 https://doi.org/10.1016/j.apcatb.2015.07.023	journal	January 2016
Electronic factors determining the reactivity of metal surfaces Hammer, B.; Nørskov, J. K. Surface Science, Vol. 343, Issue 3 https://doi.org/10.1016/0039-6028(96)80007-0	journal	December 1995
Effect of Strain on the Reactivity of Metal Surfaces Mavrikakis, M.; Hammer, B.; Nørskov, J. K. Physical Review Letters, Vol. 81, Issue 13 https://doi.org/10.1103/PhysRevLett.81.2819	journal	September 1998

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