Solvation Dynamics of Wet Ethaline: Water is the Magic Component

Alfurayj, Ibrahim; Fraenza, Carla Cecilia; Zhang, Yong; Pandian, Rathiesh; Spittle, Stephanie; Hansen, Bryce; Dean, William; Gurkan, Burcu; Savinell, Robert; Greenbaum, Steve; Maginn, Edward; Sangoro, Joshua; Burda, Clemens

doi:10.1021/acs.jpcb.1c04629

Solvation Dynamics of Wet Ethaline: Water is the Magic Component

Journal Article · 02 August 2021 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry

DOI:https://doi.org/10.1021/acs.jpcb.1c04629· OSTI ID:1853228

Alfurayj, Ibrahim ^[1]; Fraenza, Carla Cecilia ^[2]; ^[3]; Pandian, Rathiesh ^[1]; Spittle, Stephanie ^[4]; Hansen, Bryce ^[4]; Dean, William ^[5]; ^[5]; ^[5]; Greenbaum, Steve ^[2]; ^[3]; ^[4]; ^[1]

Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106, United States
Department of Physics and Astronomy, Hunter College, New York, New York 10065, United States
Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, United States
Department of Chemical and Biomolecular Engineering, University of Tennessee, Knoxville, Tennessee 37996, United States
Department of Chemical and Biomolecular Engineering, Case Western Reserve University, Cleveland, Ohio 44106, United States

Not provided.

Research Organization:: Case Western Reserve Univ., Cleveland, OH (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0019409

OSTI ID:: 1853228

Journal Information:: Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry, Vol. 125, Issue 31; ISSN 1520-6106

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (40)

Deep Eutectic Solvents Formed between Choline Chloride and Carboxylic Acids: Versatile Alternatives to Ionic Liquids No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja048266j		July 2004
A Sustainable Redox-Flow Battery with an Aluminum-Based, Deep-Eutectic-Solvent Anolyte No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201703399		May 2017
Deep Eutectic Solvents Based on N -Methylacetamide and a Lithium Salt as Electrolytes at Elevated Temperature for Activated Carbon-Based Supercapacitors No authors listed The Journal of Physical Chemistry C https://doi.org/10.1021/jp412552v		February 2014
Controlled electrodeposition of Cu–Ga from a deep eutectic solvent for low cost fabrication of CuGaSe2 thin film solar cells No authors listed Physical Chemistry Chemical Physics https://doi.org/10.1039/c0cp01408g		January 2011
Dye-Sensitized Solar Cells that use an Aqueous Choline Chloride-Based Deep Eutectic Solvent as Effective Electrolyte Solution No authors listed Energy Technology https://doi.org/10.1002/ente.201600420		January 2017
Phosphate-Functionalized Carbon Monoliths from Deep Eutectic Solvents and their Use as Monolithic Electrodes in Supercapacitors No authors listed ChemSusChem https://doi.org/10.1002/cssc.201200136		July 2012
Deep Eutectic Solvents (DESs) and Their Applications No authors listed Chemical Reviews https://doi.org/10.1021/cr300162p		October 2014
Natural Deep Eutectic Solvents – Solvents for the 21st Century No authors listed ACS Sustainable Chemistry & Engineering https://doi.org/10.1021/sc500096j		March 2014
Deep eutectic solvents: syntheses, properties and applications No authors listed Chemical Society Reviews https://doi.org/10.1039/c2cs35178a		January 2012
Deep Eutectic Solvents: Physicochemical Properties and Gas Separation Applications No authors listed Energy & Fuels https://doi.org/10.1021/ef5028873		March 2015
Deep Eutectic Solvents: Sustainable Media for Nanoscale and Functional Materials No authors listed Accounts of Chemical Research https://doi.org/10.1021/ar5000488		June 2014
Effect of water presence on choline chloride-2urea ionic liquid and coating platings from the hydrated ionic liquid No authors listed Scientific Reports https://doi.org/10.1038/srep29225		July 2016
Are There Magic Compositions in Deep Eutectic Solvents? Effects of Composition and Water Content in Choline Chloride/Ethylene Glycol from Ab Initio Molecular Dynamics No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/acs.jpcb.0c04844		July 2020
Shape-Controlled Synthesis of Gold Nanoparticles in Deep Eutectic Solvents for Studies of Structure-Functionality Relationships in Electrocatalysis No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.200803202		November 2008
Formation of type III Deep Eutectic Solvents and effect of water on their intermolecular interactions No authors listed Fluid Phase Equilibria https://doi.org/10.1016/j.fluid.2017.01.022		June 2017
Interfacial Properties of Deep Eutectic Solvents Regarding to CO ₂ Capture No authors listed The Journal of Physical Chemistry C https://doi.org/10.1021/acs.jpcc.5b04585		September 2015
Effect of Water on Solubility of Carbon Dioxide in (Aminomethanamide + 2-Hydroxy- N , N , N -trimethylethanaminium Chloride) No authors listed Journal of Chemical & Engineering Data https://doi.org/10.1021/je900078k		April 2009
Protein Phase Behavior in Aqueous Solutions: Crystallization, Liquid-Liquid Phase Separation, Gels, and Aggregates No authors listed Biophysical Journal https://doi.org/10.1529/biophysj.107.116152		January 2008
Molecular and ionic diffusion in aqueous – deep eutectic solvent mixtures: probing inter-molecular interactions using PFG NMR No authors listed Physical Chemistry Chemical Physics https://doi.org/10.1039/C5CP01493J		January 2015
Mesoscopic Structuring and Dynamics of Alcohol/Water Solutions Probed by Terahertz Time-Domain Spectroscopy and Pulsed Field Gradient Nuclear Magnetic Resonance No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/jp502799x		August 2014
Translational and Rotational Diffusion of Glycerol by Means of Field Cycling ¹ H NMR Relaxometry No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/jp110514r		February 2011
NMR Relaxometry: The Canonical Case Glycerol No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/acs.jpcb.9b11770		January 2020
Viscosity of aqueous ionic liquids analogues as a function of water content and temperature No authors listed Chinese Journal of Chemical Engineering https://doi.org/10.1016/j.cjche.2017.09.008		December 2017
Anodic Dissolution of Refractory Metals in Choline Chloride Based Binary Mixtures No authors listed ECS Transactions https://doi.org/10.1149/1.3566089		October 2010
Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis No authors listed Journal of Molecular Liquids https://doi.org/10.1016/j.molliq.2018.03.076		June 2018
Computational perspectives on structure, dynamics, gas sorption, and bio-interactions in deep eutectic solvents No authors listed Fluid Phase Equilibria https://doi.org/10.1016/j.fluid.2017.04.018		September 2017
Dynamic Solvent Effect on Betaine-30 Electron-Transfer Kinetics in Alcohols No authors listed The Journal of Physical Chemistry https://doi.org/10.1021/j100011a024		March 1995
Polarity of ionic liquids determined empirically by means of solvatochromic pyridinium N-phenolate betaine dyes No authors listed Green Chemistry https://doi.org/10.1039/b500106b		January 2005
Determination of a Solvent Hydrogen-Bond Acidity Scale by Means of the Solvatochromism of Pyridinium- N -phenolate Betaine Dye 30 and PCM-TD-DFT Calculations No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/jp501534n		April 2014
How polar are choline chloride-based deep eutectic solvents? No authors listed Phys. Chem. Chem. Phys. https://doi.org/10.1039/C3CP53456A		January 2014
Ultrafast electron transfer of betaine-30 No authors listed Journal of Luminescence https://doi.org/10.1016/S0022-2313(97)00226-3		February 1998
Subpicosecond Measurements of Polar Solvation Dynamics: Coumarin 153 Revisited No authors listed The Journal of Physical Chemistry https://doi.org/10.1021/j100048a004		November 1995
Reliable Viscosity Calculation from Equilibrium Molecular Dynamics Simulations: A Time Decomposition Method No authors listed Journal of Chemical Theory and Computation https://doi.org/10.1021/acs.jctc.5b00351		July 2015
Evaluation and Refinement of the General AMBER Force Field for Nineteen Pure Organic Electrolyte Solvents No authors listed Journal of Chemical & Engineering Data https://doi.org/10.1021/acs.jced.8b00382		August 2018
System-Size Dependence of Diffusion Coefficients and Viscosities from Molecular Dynamics Simulations with Periodic Boundary Conditions No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/jp0477147		October 2004
System-size corrections for self-diffusion coefficients calculated from molecular dynamics simulations: The case of CO2, n-alkanes, and poly(ethylene glycol) dimethyl ethers No authors listed The Journal of Chemical Physics https://doi.org/10.1063/1.4960776		August 2016
Liquid Structure and Transport Properties of the Deep Eutectic Solvent Ethaline No authors listed The Journal of Physical Chemistry B https://doi.org/10.1021/acs.jpcb.0c04058		May 2020
Comproportionation Reaction of Cu(II)/Cu(0) in Ethaline-Water Mixed Solvents No authors listed Journal of The Electrochemical Society https://doi.org/10.1149/2.1331802jes		January 2018
Chemical and electrochemical properties of a hydrophobic deep eutectic solvent No authors listed Electrochimica Acta https://doi.org/10.1016/j.electacta.2018.10.086		February 2019
Differential Microscopic Mobility of Components within a Deep Eutectic Solvent No authors listed The Journal of Physical Chemistry Letters https://doi.org/10.1021/acs.jpclett.5b01192		July 2015

Similar Records

Solvation Dynamics of Wet Ethaline: Water is the Magic Component

Journal Article · 2021 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry · OSTI ID:1865396

Alfurayj, Ibrahim; Fraenza, Carla Cecilia; Zhang, Yong; +10 more

Solvation dynamics of choline fluoride in ethylene glycol – Water mixtures

Journal Article · 2023 · Journal of Molecular Liquids · OSTI ID:2368985

Alfurayj, Ibrahim; Cecilia Fraenza, Carla; Pandian, Rathiesh; +2 more

Feasibility of TEMPO-functionalized imidazolium, ammonium and pyridinium salts as redox-active carriers in ethaline deep eutectic solvent for energy storage

Journal Article · 2020 · Molecular Systems Design & Engineering · OSTI ID:1803807

Chen, Brian; Mitchell, Sarah; Sinclair, Nicholas; +3 more

Related Subjects

Chemistry

Solvation Dynamics of Wet Ethaline: Water is the Magic Component

Citation Formats

References (40)

Similar Records

Related Subjects