Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Transient Symmetry Controls Photo Dynamics near Conical Intersections

Journal Article · · Journal of Physical Chemistry Letters
 [1];  [2];  [2];  [3];  [4];  [2];  [5]
  1. Laboratorium Für Physikalische Chemie, ETH Zürich, Vladimir-Prelogs-Weg 2, 8093 Zürich, Switzerland
  2. Department of Chemistry, Brown University, Providence, Rhode Island 02912, United States of America
  3. Department of Chemistry and Biochemistry, Western Connecticut State University, Danbury, Connecticut 06810, United States of America
  4. Department of Chemistry, University of Florence, Via della Lastruccia 3-13, Sesto Fiorentino, Florence 50019, Italy
  5. College of Petroleum & Geosciences, King Fahd University of Petroleum & Minerals, Dharan 31261, Saudi Arabia

Not provided.

Research Organization:
Brown Univ., Providence, RI (United States); Univ. of Nebraska, Lincoln, NE (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0017995; SC0020276
OSTI ID:
1852462
Journal Information:
Journal of Physical Chemistry Letters, Vol. 12, Issue 38; ISSN 1948-7185
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (17)

Conical intersection dynamics of the primary photoisomerization event in vision journal September 2010
Characterization of a conical intersection between the ground and first excited state for a retinal analog journal July 2000
Mediation of ultrafast electron transfer in biological systems by conical intersections journal April 2001
Ultrafast Electron Transfer in Photosynthesis:  Reduced Pheophytin and Quinone Interaction Mediated by Conical Intersections journal November 2006
The Non-Ergodic Nature of Internal Conversion journal December 2013
Multimode Molecular Dynamics Beyond the Born-Oppenheimer Approximation book January 2007
Solvent tuning of photochemistry upon excited-state symmetry breaking journal April 2020
Electronic and vibrational relaxation dynamics of NH 3 Rydberg states probed by vacuum-ultraviolet time-resolved photoelectron imaging journal September 2019
Non-Born–Oppenheimer wavepacket dynamics in polyatomic molecules: vibrations at conical intersections in DABCO journal January 2011
Time-resolved x-ray absorption spectroscopy with a water window high-harmonic source journal January 2017
Symmetry controlled excited state dynamics journal January 2019
Characterization of a Conical Intersection in a Charge-Transfer Dimer with Two-Dimensional Time-Resolved Stimulated Raman Spectroscopy journal June 2014
Wavepacket dynamics study of Cr(CO) 5 after formation by photodissociation: relaxation through an (E ⊕ A) ⊗ e Jahn–Teller conical intersection journal March 2006
Coherence in nonradiative transitions: internal conversion in Rydberg-excited N-methyl and N-ethyl morpholine journal January 2017
Observation of Structural Wavepacket Motion: The Umbrella Mode in Rydberg-Excited N -Methyl Morpholine journal July 2017
Ultrafast X-ray scattering reveals vibrational coherence following Rydberg excitation journal July 2019
Energy Flow and Fragmentation Dynamics of N,N -Dimethylisopropylamine journal March 2006